Climate change affecting temperature and aridity zones: a case study in Eastern Inner Mongolia, China from 1960–2008

Recent climate change is substantially affecting the spatial pattern of geographical zones, and the temporal and spatial inconsistency of climatic warming and drying patterns contributes to the complexity of the shifting of temperature and aridity zones. Eastern Inner Mongolia, China, located in the interface region of different biomes and ecogeographic zones, has experienced dramatic drying and warming over the past several decades. In this study, the annual accumulated temperature above 10 °C (AAT10) and the aridity index, two key indicators in geographical regionalization, are used to assess warming and drying processes and track the movements of temperature and aridity zones from 1960 to 2008. The results show a significant warming at the regional level from 1960 to 2008 with an AAT10 increase rate of 7.89 °C·d/year (p?<?0.001) in Eastern Inner Mongolia, while the drying trend was not significant during this period. Spatial heterogeneity of warming and drying distributions was also evident. Analysis of warming and drying via piecewise regression revealed two separate, specific trends between the first 31 years (1960–1990) and the subsequent 18 years (1991–2008). Generally, mild warming and very slight wetting occurred prior to 1990, while after 1991 both warming and drying were significant and enhanced. Continuous warming drove a northward shift of temperature zones from the 1960s to 2000s, while aridity zones displayed enhanced temporal and spatial variability. Climate change effects on temperature and aridity zones imply that the patterns of cropping systems, macro-ecosystems, and human land use modes are potentially undergoing migration and modification due to climate change.     

Edge-to-Stem Variability in Wet-Canopy Evaporation From an Urban Tree Row

Evaporation from wet-canopy (\(E_\mathrm{C}\)) and stem (\(E_\mathrm{S}\)) surfaces during rainfall represents a significant portion of municipal-to-global scale hydrologic cycles. For urban ecosystems, \(E_\mathrm{C}\) and \(E_\mathrm{S}\) dynamics play valuable roles in stormwater management. Despite this, canopy-interception loss studies typically ignore crown-scale variability in \(E_\mathrm{C}\) and assume (with few indirect data) that \(E_\mathrm{S}\) is generally \({<}2\%\) of total wet-canopy evaporation. We test these common assumptions for the first time with a spatially-distributed network of in-canopy meteorological monitoring and 45 surface temperature sensors in an urban Pinus elliottii tree row to estimate \(E_\mathrm{C}\) and \(E_\mathrm{S}\) under the assumption that crown surfaces behave as “wet bulbs”. From December 2015 through July 2016, 33 saturated crown periods (195 h of 5-min observations) were isolated from storms for determination of 5-min evaporation rates ranging from negligible to 0.67 \(\hbox {mm h}^{-1}\). Mean \(E_\mathrm{S}\) (0.10 \(\hbox {mm h}^{-1}\)) was significantly lower (\(p < 0.01\)) than mean \(E_\mathrm{C}\) (0.16 \(\hbox {mm h}^{-1}\)). But, \(E_\mathrm{S}\) values often equalled \(E_\mathrm{C}\) and, when scaled to trunk area using terrestrial lidar, accounted for 8–13% (inter-quartile range) of total wet-crown evaporation (\(E_\mathrm{S}+E_\mathrm{C}\) scaled to surface area). \(E_\mathrm{S}\) contributions to total wet-crown evaporation maximized at 33%, showing a general underestimate (by 2–17 times) of this quantity in the literature. Moreover, results suggest wet-crown evaporation from urban tree rows can be adequately estimated by simply assuming saturated tree surfaces behave as wet bulbs, avoiding problematic assumptions associated with other physically-based methods.     

Variability of ozone in the marine boundary layer of the equatorial Pacific Ocean

This study examines the processes controlling the diurnal variability of ozone (O₃) in the marine boundary layer of the Kwajalein Atoll, Republic of the Marshall Islands (latitude 8° 43′ N, longitude 167° 44′ E), during July to September 1999. At the study site, situated in the equatorial Pacific Ocean, O₃ mixing ratios remained low, with an overall average of 9–10 parts per billion on a volume basis (ppbv) and a standard deviation of 2.5 ppbv. In the absence of convective storms, daily O₃ mixing ratios decreased after sunrise and reached minimum during the afternoon in response to photochemical reactions. The peak-to-peak amplitude of O₃ diurnal variation was approximately 1–3 ppbv. During the daytime, O₃ photolysis, hydroperoxyl radicals, hydroxyl radicals, and bromine atoms contributed to the destruction of O₃, which explained the observed minimum O₃ levels observed in the afternoon. The entrainment of O₃-richer air from the free troposphere to the local marine boundary layer provided a recovery mechanism of surface O₃ mixing ratio with a transport rate of 0.04 to 0.2 ppbv per hour during nighttime. In the presence of convection, downward transport of O₃-richer tropospheric air increased surface O₃ mixing ratios by 3–12 ppbv. The magnitude of O₃ increase due to moist convection was lower than that observed over the continent (as high as 20–30 ppbv). Differences were ascribed to the higher O₃ levels in the continental troposphere and weaker convection over the ocean. Present results suggest that moist convection plays a role in surface-level O₃ dynamics in the tropical marine boundary layer.     

Geochemistry of low-molecular weight hydrocarbons in hydrothermal fluids from Middle Valley, northern Juan de Fuca Ridge

Hydrothermal vent fluids from Middle Valley, a sediment-covered vent field located on the northern Juan de Fuca Ridge, were sampled in July, 2000. Eight different vents with exit temperatures of 186-281 °C were sampled from two areas of venting: the Dead Dog and ODP Mound fields. Fluids from the Dead Dog field are characterized by higher concentrations of ΣNH₃ and organic compounds (C₁-C₄ alkanes, ethene, propene, benzene and toluene) compared with fluids from the ODP Mound field. The ODP Mound fluids, however, are characterized by higher C₁/(C₂ + C₃) and benzene:toluene ratios than those from the Dead Dog field. The aqueous organic compounds in these fluids have been derived from both bacterial processes (methanogenesis in low temperature regions during recharge) as well as from thermogenic processes in higher temperature portions of the subsurface reaction zone. As the sediments undergo hydrothermal alteration, carbon dioxide and hydrocarbons are released to solution as organic matter degrades via a stepwise oxidation process. Compositional and isotopic differences in the aqueous hydrocarbons indicate that maximum subsurface temperatures at the ODP Mound are greater than those at the Dead Dog field. Maximum subsurface temperatures were calculated assuming that thermodynamic equilibrium is attained between alkenes and alkanes, benzene and toluene, and carbon dioxide and methane. The calculated temperatures for alkene-alkane equilibrium are consistent with differences in the dissolved Cl concentrations in fluids from the two fields, and confirm that subsurface temperatures at the ODP Mound are hotter than those at the Dead Dog field. Temperatures calculated assuming benzene-toluene equilibrium and carbon dioxide-methane equilibrium are similar to observed exit temperatures, and do not record the hottest subsurface conditions. The difference in subsurface temperatures estimated using organic geochemical thermometers reflects subsurface cooling processes via mixing of a hot, low salinity vapor with a cooler, seawater salinity fluid. Because of the disparate temperature dependence of alkene-alkane and benzene-toluene equilibria, the mixed fluid records both the high and low temperature equilibrium conditions. These calculations indicate that vapor-rich fluids are presently being formed in the crust beneath the ODP Mound, yet do not reach the surface due to mixing with the lower temperature fluids.     

Micromorphological Analysis of Coastal Sediments from Willapa Bay, Washington, USA: A Technique for Analysing Inferred Tsunami Deposits

Tsunami deposits are provisionally distinguished in the field on the basis of anomalous sand horizons, fining-up and fining-landward, coupled with organic-rich, fragmented `backwash' sediments. In this paper, micromorphological features of a sediment sequence previously interpreted as being of tsunami origin are described. These characteristics are shown to be consistent with the macro-scale features used elsewhere, but show additional details not seen in standard stratigraphies, including possible evidence for individual waves, possibly wave-magnitude progression, organic fragment alignment and intraclast microstructures. Although replication and more complete studies are needed, this analysis confirms the identification of a tsunami in Willapa Bay in ca.1700 AD, while demonstrating a widely applicable technique for confirming or refuting possible tsunami deposits.     

How do streamflow generation mechanisms affect watershed hypsometry?

Several studies have shown that the dominant streamflow generation mechanism in a river basin can leave distinct geomorphological signatures in basin topography. In particular, it has been suggested previously that basins generated by groundwater discharge tend to have a larger hypsometric integral than surface runoff basins because fluvial erosion is more focused in the valleys where groundwater discharge tends to occur. In this analysis, we aim to clarify this relationship by developing an alternative method to quantify the effects of streamflow generation mechanisms on basin hypsometry and by using a numerical model that can generate streamflow by different processes to evaluate the sensitivity of the results to the hydrological and geomorphological properties of the basin. The model results suggest that the hypsometric characteristics that are usually associated with groundwater discharge basins, such as a larger hypsometric integral, occur primarily when drainage networks are still advancing in the watershed. During later stages of development, an additional factor such as lithological controls or a distinct geomorphological process would be needed to preserve these features. The model results also show that the hypsometric effects are stronger when the parameters of the fluvial erosion process promote the influence of small discharge rates. Copyright © 2007 John Wiley & Sons, Ltd.     

同位素示踪剂在流域水文模拟中的应用

主要目的是通过对同位素在流域水文模拟应用中的一些假定、限制条件以及方法进行澄清和系统化,从而促进同位素在流域水文模拟中一些新的研究方向和研究热点.主要从三个方面,即同位素流量过程线分割、流域平均滞时与不同水源混合、与水文模型耦合,讨论同位素示踪剂在流域水文模拟中的研究进展情况.同时指出了同位素在流域水文模拟中应用存在的一些主要问题,包括:①降雨同位素含量的时空变化;②不同径流成分的采样;③径流输出同位素含量的空间变化;④流域平均滞时分布函数的确定;⑤水文同位素耦合模型.     

The Triassic age for oceanic eclogites in the Dabie orogen: Entrainment of oceanic fragments in the continental subduction

Low-temperature and high-pressure eclogites with an oceanic affinity in the western part of the Dabie orogen have been investigated with combined Lu–Hf and U–Pb geochronology. These eclogites formed over a range of temperatures (482–565 °C and 1.9–2.2 GPa). Three eclogites, which were sampled from the Gaoqiao country, yielded Lu–Hf ages of 240.7 ± 1.2 Ma, 243.3 ± 4.1 Ma and 238.3 ± 1.2 Ma, with a corresponding lower-intercept U–Pb zircon age of 232 ± 26 Ma. Despite the well-preserved prograde major- and trace-element zoning in garnets, these Lu–Hf ages mostly reflect the high-pressure eclogite-facies metamorphism instead of representing the early phase of garnet growth due to the occurrence of omphacite inclusions from core to rim and the shell effect. An upper-intercept zircon U–Pb age of 765 ± 24 Ma is defined for the Gaoqiao eclogite, which is consistent with the weighted-mean age of 768 ± 21 Ma for the country gneiss. However, the gneiss has not been subjected to successive high-pressure metamorphism. The new Triassic ages are likely an estimate of the involvement of oceanic fragments in the continental subduction.