The Greenland 8200 cal. yr BP event detected in loss‐on‐ignition profiles in Norwegian lacustrine sediment sequences

High‐resolution loss‐on‐ignition analyses of lacustrine sediment cores from both proglacial and non‐glacial lakes in southern Norway have revealed a specific pattern characterised by a significant, two‐peaked reduction of the loss‐on‐ignition values in the basal half of the cores. In non‐glacier‐fed lakes, the loss‐on‐ignition variations are interpreted to reflect mainly lake productivity and hence variability in surface summer air temperature. Sediments deposited in proglacial lakes, however, reflect mainly the glacier activity in the lake catchment. Bulk AMS radiocarbon dates from the core sequences and the loss‐on‐ignition curve pattern suggest that this event correlates with the ‘8200 cal. yr BP event’ recorded in the GRIP and GISP2 Greenland ice‐cores, termed the Finse event in southern Norway. Copyright © 2001 John Wiley & Sons, Ltd.     

Using the potassium-argon laser experiment (KArLE) to date ancient,low-K chondritic meteorites

Several laboratories have been investigating the feasibility of in situ K-Ar dating for use in future landing planetary missions. One drawback of these laboratory demonstrations is the insufficient analogy of the analyzed analog samples with expected future targets. We present the results obtained using the K-Ar laser experiment (KArLE) on two old and K-poor chondritic samples, Pułtusk and Hvittis, as better lunar analogs. The KArLE instrument uses laser ablation to vaporize rock samples and quantifies K content by laser-induced breakdown spectroscopy (LIBS), Ar by quadrupole mass spectrometry (QMS), and ablated mass by laser profilometry. We performed 64 laser ablations on the chondrites to measure spots with a range of K₂O and Ar content and used the data to construct isochrons to determine the chondrite formation age. The KArLE isochron ages on Pułtusk and Hvittis are 5059 ± 892 Ma and 4721 ± 793 Ma, respectively, which is within the uncertainty of published reference ages, and interpreted as the age of their formation. The uncertainty (2σ) on the KArLE ages obtained in this study is better than 20% (18% for Pułtusk and 17% for Hvittis). The precision, which compares our obtained ages to the reference ages, is also better than 20% (11% for Pułtusk and 4% for Hvittis). These results are encouraging for understanding the limits of this technique to measure ancient planetary samples and for guiding future improvements to the instrument.     

A multi-proxy approach to assessing isolation basin stratigraphy from the Lofoten Islands, Norway

This study takes a comprehensive approach to characterizing the isolation sequence of Heimerdalsvatnet, a coastal lake in the Lofoten Islands, northern Norway. We use established methods and explore new techniques to assess changes in marine influence. Bathymetric and sub-bottom profiles were acquired to examine basin-wide sedimentation and a 5.8 m sediment core spanning the last 7800 cal yr BP was analyzed. We measured magnetic susceptibility, bulk organic matter properties, molecular biomarkers, diatom assemblages, and elemental profiles acquired by scanning X-ray fluorescence. These characteristics of the sediment reflect detailed changes in salinity and water column conditions as the lake was progressively isolated. Three distinct litho/chemo-stratigraphic units represent a restricted marine phase (7800-6500 cal yr BP), a transitional phase characterized by intermittent marine influence (6500-4900 cal yr BP), and complete isolation and freshwater sedimentation (4900 cal yr BP to present). Although there are uncertainties in the estimate of the threshold elevation of the lake, the timing of these phases generally corresponds with previous interpretations of the local relative sea-level history. This record captures sea-level regression following the Tapes transgression and supports the interpretation of a subsequent sea-level stillstand, dated in Heimerdalsvatnet from 6500 to 4900 cal yr BP.     

The Effect of Specimen Size on Strength and Other Properties in Laboratory Testing of Rock and Rock-Like Cementitious Brittle Materials

The effect of specimen size on the measured unconfined compressive strength and other mechanical properties has been studied by numerous researchers in the past, although much of this work has been based on specimens of non-standard dimensions and shapes, and over a limited size range. A review of the published literature was completed concentrating on the presentation of research pertaining to right cylindrical specimens with height:diameter ratios of 2:1. Additionally, new data has been presented considering high strength (70 MPa) cement mortar specimens of various diameters ranging from 63 to 300 mm which were tested to failure. Currently, several models exist in the published literature that seek to predict the strength–size relationship in rock or cementitious materials. Modelling the reviewed datasets, statistical analysis was used to help establish which of these models best represents the empirical evidence. The findings presented here suggest that over the range of specimen sizes explored, the MFSL (Carpinteri et al. in Mater Struct 28:311–317, 1995) model most closely predicts the strength–size relationship in rock and cementitious materials, and that a majority of the empirical evidence supports an asymptotic value in strength at large specimen diameters. Furthermore, the MFSL relationship is not only able to model monotonically decreasing strength–size relationships but is also equally applicable to monotonically increasing relationships, which although shown to be rare do for example exist in rocks with fractal distributions of hard particles.     

A study on measurement and analysis of radon-222 (uranium series) emitted to the atmosphere from construction materials (cement block, kaolin brick, and gypsum board) in living environment

The purpose of this study was to measure, compare, and analyze the air concentration of radon that was emitted to the atmosphere from construction materials such as cement brick, tile, red clay tile, and gypsum tile. The study method was to use continuous radon monitoring equipment (RTM 1688-2) to measure concentrations of radon and thoron contained in brick, tile, red clay tile, and gypsum tile. According to the measurement results, the cement brick among the four samples showed the highest measurement value for radon, while the red clay tile showed the highest measurement value for thoron. When the radon emission concentration was estimated based on materials required for construction per unit area (3.3 m²) in an actual construction, the cement brick had the highest measurement values for radon and thoron. This study confirmed the degree of radon emission from construction materials. The purpose of this study was also to suggest a method to examine the effects of radon and reduce the dose of personal radiation exposure. It is believed that the government should be active in publicizing and managing use of construction materials that have lower levels of radon emission.     

The spatio-temporal characteristics of total rainfall during September in South Korea according to the variation of ENSO

A significant negative correlation between the total rainfall averaged over South Korea and the Niño-3.4 index was found for the month of September. To find out the reason for this negative correlation, composite analyses were carried out for the highest and lowest 8 years of the Niño-3.4 index. During the strong El Niño year, an anomalous anticyclone occurs in the continental East Asia, while an anomalous cyclone emerges in the subtropical western Pacific. The resultant eastward pressure gradient force induces anomalous northerlies in most regions of East Asia, which produces anomalous cold and dry conditions throughout the troposphere between 120° and 140°E, reducing the Korean rainfall. It is also found that during El Niño year, tropical cyclones (TCs) tend to recurve far east offshore of Japan because the weakening of the western North Pacific subtropical high (WNPSH). During La Niña years, on the other hand, the strengthening and westward extension of the WNPSH render more TCs influencing the Korean peninsula. Therefore, the TC track changes associated with El Niño-Southern Oscillation is another contributor to change of the Korean rainfall.     

Evaluation of cloud and precipitation parameterization using a single-column model: A TWP-ICE case study

Cloud and precipitation parameterization schemes are evaluated, and their sensitivity to the method and/or parameters used to determine cloud physical processes is examined using a singlecolumn version of the Unified Model (SCUM). In the experiment for TWP-ICE, cloud fraction is overestimated (underestimated) in the upper (lower) troposphere due to the wet (dry) bias. The precipitation rate is well simulated during the active monsoon period, but overestimated during the suppressed monsoon and clear skies periods. In the moist convection scheme, trigger condition and entrainment process affect the lower tropospheric humidity through the impact on convective occurrence frequency and intensity, respectively. Strengthening the trigger condition and using the adaptive entrainment method alleviate the low-level dry bias. In the microphysics scheme, more large-scale precipitation is produced with prognostic rain, due to rain sedimentation considering vertical velocity of rain drop, than with diagnostic rain. Less ice/snow deposition with the prognostic two-ice category results in lower ice water content and upper-level cloud fraction than with the diagnostic splitting method for the twoice category. In the cloud macrophysics scheme, the prognostic cloud fraction and cloud/ice water content scheme produces a larger cloud fraction and more cloud/ice water content than the diagnostic scheme, mainly due to detrainment from moist convection (cloud source) that surpasses the effect of convective heating and drying (cloud sink). This affects temperature by influencing the radiative, convective, and microphysical processes. The experiment with combined modifications in cloud and precipitation schemes shows that interaction between modified moist convection and cloud macrophysics schemes results in more alleviation of the cold bias not only at the lower levels but also at the upper levels.     

Machine learning approaches to coastal water quality monitoring using GOCI satellite data

Since coastal waters are one of the most vulnerable marine systems to environmental pollution, it is very important to operationally monitor coastal water quality. This study attempts to estimate two major water quality indicators, chlorophyll-a (chl-a) and suspended particulate matter (SPM) concentrations, in coastal environments on the west coast of South Korea using Geostationary Ocean Color Imager (GOCI) satellite data. Three machine learning approaches including random forest, Cubist, and support vector regression (SVR) were evaluated for coastal water quality estimation. In situ measurements (63 samples) collected during four days in 2011 and 2012 were used as reference data. Due to the limited number of samples, leave-one-out cross validation (CV) was used to assess the performance of the water quality estimation models. Results show that SVR outperformed the other two machine learning approaches, yielding calibration R² of 0.91 and CV root-mean-squared-error (RMSE) of 1.74 mg/m³ (40.7%) for chl-a, and calibration R² of 0.98 and CV RMSE of 11.42 g/m³ (63.1%) for SPM when using GOCI-derived radiance data. Relative importance of the predictor variables was examined. When GOCI-derived radiance data were used, the ratio of band 2 to band 4 and bands 6 and 5 were the most influential input variables in predicting chl-a and SPM concentrations, respectively. Hourly available GOCI images were useful to discuss spatiotemporal distributions of the water quality parameters with tidal phases in the west coast of Korea.     

Accumulation of butyltin compounds in finless porpoises (Neophocaena asiaeorientalis) from Korean coast: Tracking the effectiveness of TBT regulation over time

The concentrations of butyltin compounds (BTs) were measured in the livers of finless porpoises (Neophocaena asiaeorientalis) caught off the Korean coast in 2003 and 2010, to assess the effectiveness of legislative action against BTs. The concentrations of BTs ranged from 65.1 to 1432 (average: 370) ng/g wet weight, within the ranges reported by previous studies. The levels of BTs in almost all the samples exceeded the suggested threshold value, implying potential adverse health effects from the BT exposures. Concentrations of BTs were significantly correlated with body length, weight, and age of finless porpoises, but were not correlated with sex. Spatial differences in the concentrations of BTs were not observed between Yellow and South Seas, while there was a significant decrease in BTs between the sampling years of 2003 and 2010. Our result indicates that the effectiveness on TBT ban has reached to marine mammals in the coastal waters of Korea.     

Historical record of metal accumulation and lead source in the southeastern coastal region of Korea

Concentrations of heavy metals and Pb isotopes were measured in the 1-M HCl leaching fraction of core sediments spanning the last 400 years. This sedimentary record of pollution history in metal concentrations shows a good correlation with the increases in industrialization, urbanization, and energy consumption since 1901s. Notably, the Pb concentration and the ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb ratios were constant before the 1910s (16.7 μg/g, 0.844, and 2.098, respectively), whereas they increased steadily up to 21.9 μg/g, 0.848, and 2.101 after the 1910s. The correlations between Pb isotope ratios (²⁰⁶Pb, ²⁰⁷Pb, and ²⁰⁸Pb) showed different linear regression trends for core sediments before and after the 1910s, indicating differences in Pb sources. Our interpretation suggests that the source of anthropogenic Pb in Korean coastal region and the Yellow Sea shelf was presumed to be Chinese coals or ores, which have also played a major role as sources of atmospheric particulate Pb.