Clay mineral weathering and contaminant dynamics in a caustic aqueous system: I. Wet chemistry and aging effects

Caustic high level radioactive waste induces mineral weathering reactions that can influence the fate of radionuclides released in the vicinity of leaking storage tanks. The uptake and release of Cs^I and Sr^II were studied in batch reactors of 2:1 layer-type silicates—illite (Il), vermiculite (Vm) and montmorillonite (Mt)—under geochemical conditions characteristic of leaking tank waste at the Hanford Site in WA (0.05 m Al_T, 2 m Na⁺, 1 m NO₃⁻, pH ∼14, Cs and Sr present as co-contaminants). Time series (0 to 369 d) experiments were conducted at 298 K, with initial [Cs]₀ and [Sr]₀ concentrations from 10⁻⁵ to 10⁻³ mol kg⁻¹. Clay mineral type affected the rates of (i) hydroxide promoted dissolution of Si, Al and Fe, (ii) precipitation of secondary solids and (iii) uptake of Cs and Sr. Initial Si release to solution followed the order Mt > Vm > Il. An abrupt decrease in soluble Si and/or Al after 33 d for Mt and Vm systems, and after 190 d for Il suspensions was concurrent with accumulation of secondary aluminosilicate precipitates. Strontium uptake exceeded that of Cs in both rate and extent, although sorbed Cs was generally more recalcitrant to subsequent desorption and dissolution. After 369 d reaction time, reacted Il, Vm and Mt solids retained up to 17, 47 and 14 mmol kg⁻¹ (0.18, 0.24 and 0.02 μmol m⁻²) of Cs, and 0, 27 and 22 mmol kg⁻¹ (0, 0.14 and 0.03 μmol m⁻²) Sr, respectively, which were not removed in subsequent Mg exchange or oxalic acid dissolution reactions. Solubility of Al and Si decreased with initial Cs and Sr concentration in Mt and Il, but not in Vm. High co-contaminant sorption to the Vm clay, therefore, appears to diminish the influence of those ions on mineral transformation rates.     

Genetic Environment of the Intrusion-related Yuryang Au-Te Deposit in the Cheonan Metallogenic Province, Korea

Abstract. The Yuryang gold deposit, comprising a Te‐bearing Au‐Ag vein mineralization, is located in the Cheonan area of the Republic of Korea. The deposit is hosted in Precambrian gneiss and closely related to pegmatite. The mineralized veins display massive quartz textures, with weak alteration adjacent to the veins. The ore mineralization is simple, with a low Ag/Au ratio of 1.5:1, due to the paucity of Ag‐phases. Ore mineralization took place in two different mineral assemblages with paragenetic time; early Fe‐sulfide mineralization and late Fe‐sulfide and Au‐Te mineralization. The early Fe‐sulfide mineralization (pyrite + sphalerite) occurred typically along the vein margins, and the subsequent Au‐Te mineralization is characterized by fracture fillings of galena, sphalerite, pyrrhotite, Te‐bearing minerals (petzite, altaite, hessite and Bi‐Te mineral) and electrum. Fluid inclusions characteristically contain CO₂ and can be classified into four types (Ia, Ib, IIa and IIb) according to the phase behavior. The pressure corrected temperatures (≥500d?C) indicate that the deposit was formed at a distinctively high temperature from fluids with moderate to low salinity (<12 wt% equiv. NaCl) and CH₄ (1?22 mole %). The sphalerite geo‐barometry yield an estimated pressure about 3.5 ?2.1 kbar. The dominant ore‐deposition mechanisms were CO₂ effervescence and concomitant H₂S volatilization, which triggered sulfidation and gold mineralization. The measured and calculated isotopic compositions of fluids (δ¹⁸O_H2^O = 10.3 to 12.4 %o; δD_H2^O = ‐52 to ‐77 %o) may indicate that the gold deposition originated from S‐type magmatic waters. The physicochemical conditions observed in the Yuryang gold deposit indicate that the Jurassic gold deposits in the Cheonan area, including the Yuryang gold deposit are compatible with deposition of the intrusion‐related Au‐Te veins from deeply sourced fluids generated by the late Jurassic Daebo magmatism.     

Analysis of sinkhole occurrences over abandoned mines using fuzzy reasoning: a case study

In Korea most of the old mine workings were worked with room and pillar method or sublevel caving method and today they possess great possibility of surface subsidence especially for shallow depth mines. In most of the cases, mine roadways, rooms and pillars are irregular in shape and information about the local geology is uncertain. For these reasons, it is difficult to standardize the estimating method of subsidence especially sinkhole type over abandoned mine area. This paper describes the application procedure for the fuzzy reasoning techniques to analyze the possibility of sinkhole occurrences over abandoned mines. This technique is implemented in software which can simplify the analysis procedure and present the possibility of sinkhole subsidence without having precise information about local geological/mining conditions. This technique has been applied to forecast sinkhole possibilities at Bonghwa site where a massive sinkhole has already been occurred.     

Turbulence modeling of compound open-channel flows with and without vegetation on the floodplain using the Reynolds stress model

A Reynolds stress model for the numerical simulation of compound open-channel flows with vegetation on the floodplain is described. The Reynolds stress model consists of various sub-models such as Speziale et al.’s model, Mellor and Herring’s model, and Rotta’s model for the pressure–strain correlation term, the turbulent diffusion term, and the dissipation term, respectively. For validation of the model, plain compound open-channel flows are simulated. The computed results were compared with measured data by [Tominaga A, Nezu I. Turbulent structure in compound open-channel flows. J Hydraul Eng, ASCE 1991;117(1):21–41] and the results show that the Reynolds stress model successfully simulates the mean flow and turbulence structure of plain compound channel flows. The model was then applied to compound open-channel flows with vegetated floodplains. Good agreement between the simulated results and data from an algebraic stress model by [Naot D, Nezu I, Nakagawa H. Hydrodynamic behavior of partly vegetated open channels. J Hydraul Eng, ASCE 1996;122(11):625–33] was found. However, it was shown that the RSM is capable of predicting the velocity dip and lateral shift in the maximum streamwise velocity, which were not observed in the data from algebraic stress modeling. Finally, a depth-averaged analysis of the streamwise momentum equation was performed to investigate the lateral momentum transfer in compound channel flows with vegetated floodplains. Compared with components by the secondary currents and Reynolds stress, the drag force due to the presence of vegetation appears to be a factor in reducing the bottom shear stress in both main channel and floodplain.     

A crystal-chemical basis for Pb retention and fission-track annealing systematics in U-bearing minerals, with implications for geochronology

This study develops an empirical crystal-chemical framework for systematizing the kinetics of Pb loss and fission-track annealing in U-bearing minerals. Ionic porosity, Z (the fraction of a mineral's unit-cell volume not occupied by ions) potentially accounts for kinetic behavior by monitoring mean metal-oxygen bond length/strength. Various tests of a general kinetics-porosity relationship are presented, based upon diverse mineral data including: (1) Pb diffusion parameters; (2) measured closure temperatures (T_C) for fission-track annealing and (3) retentivities of both Pb and fission tracks, from apparent-age data. Every kinetic parameter (including T_C and mineral age for both the U/Pb and fission-track systems) is inversely correlated with Z within the sub-assemblage: zircon (Z ≈ 29%), titanite ( 34%) and apatite ( 38%). Assuming a diffusional closure model, Pb isotopic transport phenomena are described by a T_C-Z scale “calibrated” with field-based T_C data for titanite (≥ 680 ± 20°C) and apatite ( 500°C). Extrapolation of this scale yields T_C estimates for the following minerals: staurolite (T_C ≥ 1060°C, Z ≈ 25%); garnet (≥ 1010°C, 26.5%); zircon (≥900°C); monazite, xenotime, and epidote (≥ 750°C, 32%); and Ca-clinopyroxene (≥ 670 ± 30°C, 34 ± 1%, depending on composition). These empirical results imply that a (U/)Pb/Pb date for staurolite or garnet records the time of mineral growth, not post-growth isotopic closure, as also concluded in recent field studies. Because Z systematizes fission-track annealing, this recrystallization process, like volume-diffusion, must also be rate-limited by the strength of chemical bonds. The extent to which other recrystallization processes are likewise rate-limited is important to U/Pb geochronology because they potentially compete with diffusion as mechanisms for Pb-isotopic resetting in nature.     

Genetic environment of germanium-bearing gold-silver vein ores from the Wolyu mine,Republic of Korea

The Wolyu mine is one of the largest vein-type gold-silver-bearing epithermal systems in the Youngdong district and is the first gold-silver deposit in Korea found to contain significant germanium, in the form of argyrodite (Ag₈GeS₆). Mineralized veins (78.9 ± 1.2 Ma) crosscutting Late Cretaceous hostrock tuff and quartz porphyry (81.5 ± 1.8 Ma) consist of three stages of quartz and carbonates, the first of which contains pyrite, basemetal sulfides and Au-Ag-minerals. Stage I Au-Ag-Ge-mineralized veins show a systematic variation of mineral assemblage with time: (1) quartz + pyrite; (2) quartz + pyrite + sphalerite + electrum + argentite; (3) carbonate + quartz + sphalerite + electrum + argentite; (4) carbonate + native silver + argentite + Ag-sulfosalts + argyrodite + sphalerite. Calculated values of temperature and sulfur activity are: assemblage (1), 360-280°C and 10^–7-10^–10; (2), 280-210°C and 10^–10-10^–14; (3), 210-180°C and 10^–14-10^–16; (4), 180-155°C and 10^–17-10^–18. These data, the frequent association of gold with sulfides, and the abundance of pyrite in alteration zones indicate that decreasing sulfur activity and cooling were important in triggering gold deposition. Hydrogen and oxygen isotope compositions of ore fluids display a systematic variation with increasing time. Within the main Ag-Au-Ge mineralization, D and ¹⁸O values decrease with the transition from quartz to carbonate deposition (from -78 and –2.8% to –90 and –8.7%., respectively), indicating increasing involvement (mixing) of less evolved meteoric water which resulted in progressive cooling and dilution of ore fluids in the shallow ( 370–600 m) Wolyu epithermal system.     

Estimating Ore Production in Open-pit Mines Using Various Machine Learning Algorithms Based on a Truck-Haulage System and Support of Internet of Things

Natural Resources Research - This study aimed to develop and assess the feasibility of different machine learning algorithms for predicting ore production in open-pit mines based on a truck-haulage...     

Evolution of the Taebaeksan Basin,Korea: I,early Paleozoic sedimentation in an epeiric sea and break‐up of the Sino‐Korean Craton from Gondwana

The Taebaeksan Basin is located in the mid‐eastern part of the southern Korean Peninsula and tectonically belonged to the Sino‐Korean Craton (SKC). It comprises largely the lower Paleozoic Joseon Supergroup and the upper Paleozoic Pyeongan Supergroup which are separated by a disconformity representing a 140 myr?long hiatus. This paper explores the early Paleozoic paleogeographical and tectonic evolution of the Taebaeksan Basin on the basis of updated stratigraphy, trilobite faunal assemblages, and detrital zircon U–Pb ages of the Joseon Supergroup. The Joseon Supergroup is a shallow marine siliciclastic‐carbonate succession ranging in age from the Cambrian Series 2 to Middle Ordovician. The Ongnyeobong Formation is the sole Upper Ordovician volcanic succession documented in the Taebaeksan Basin. It is suggested that in the early Paleozoic the Taebaeksan Basin was a part of an epeiric sea, the Joseon Sea, in east Gondwana. The Joseon Sea was the depositional site for lower Paleozoic successions of the SKC. Early Paleozoic sedimentation in the Joseon Sea commenced during the Cambrian Stage 3 (～ 520 Ma) and ceased by the end of the Darriwilian (～ 460 Ma). In the early Paleozoic, the SKC was located at the margin of east Gondwana and was separated from the South China Craton by an oceanic basin with incipient oceanic ridges, the Helan Trough. The spreading oceanic ridges and associated transform faults possibly promoted the uplift of the Joseon Sea, which resulted in cessation of sedimentation and break‐up of the SKC from core Gondwana by the end of the Ordovician.     

Wave prediction in a port using a fully nonlinear Boussinesq wave model

A wave forecasting system using FUNWAVE-TVD which is based on the fully nonlinear Boussinesq equations by Chen(2006) was developed to provide an accurate wave prediction in the Port of Busan, South Korea. This system is linked to the Korea Operational Oceanographic System(KOOS) developed by Park et al.(2015). The computational domain covers a region of 9.6 km×7.0 km with a grid size of 2 m in both directions, which is sufficient to resolve short waves and dominant sea states. The total number of grid points exceeds 16 millions,making the model computational expensive. To provide real-time forecasting, an interpolation method, which is based on pre-calculated results of FUNWAVE-TVD and SWAN forecasting results at the FUNWAVE-TVD offshore boundary, was used. A total of 45 cases were pre-calculated, which took 71 days on 924 computational cores of a Linux cluster system. Wind wave generation and propagation from the deep water were computed using the SWAN in KOOS. SWAN results provided a boundary condition for the FUNWAVE-TVD forecasting system. To verify the model, wave observations were conducted at three locations inside the port in a time period of more than 7 months. A model/model comparison between FUNWAVE-TVD and SWAN was also carried out. It is found that, FUNWAVE-TVD improves the forecasting results significantly compared to SWAN which underestimates wave heights in sheltered areas due to incorrect physical mechanism of wave diffraction, as well as large wave heights caused by wave reflections inside the port.     

Is the North Atlantic Oscillation reflected in Scandinavian glacier mass balance records?

The North Atlantic Oscillation (NAO) is one of the modes of climate variability in the North Atlantic region. The atmospheric circulation during the winter season in this region commonly displays a strong meridional (north–south) pressure contrast, with low air pressure (cyclone) centred close to Iceland and high air pressure (anticyclone) near the Azores. This pressure gradient drives the mean surface winds and the mid‐latitude winter storms from west to east across the North Atlantic, bringing mild moist air to northwest Europe. The NAO index is based on the difference of normalised sea‐level pressures (SLP) between Ponta Delgada, Azores and Stykkisholmur, Iceland. The SLP anomalies at these stations are normalised by division of each monthly pressure by the long‐term (1865–1984) standard deviation. Interannual atmospheric climate variability in northwest Europe, especially over Great Britain and western Scandinavia has, during the last decades, been attributed mainly to the NAO, causing variations in the winter weather over the northeast North Atlantic and the adjacent land areas. A comparison between the NAO index and the winter (December–March) precipitation between ad 1864 and 1995 in western Norway shows that these are strongly linked (correlation coefficient 0.77). Variations in the NAO index are also reflected in the mass balance records of glaciers in western Scandinavia. The NAO index is best correlated with mass balance data from maritime glaciers in southern Norway (e.g. Ålfotbreen R² = 0.51). The record of Holocene (last ca. 11 500 cal. yr) glacier variations of maritime glaciers in western Scandinavia is thus a proxy of pre‐instrumental NAO variations. Copyright © 2000 John Wiley & Sons, Ltd.