Estimation de la température maximale d'enfouissement du Toarcien et du Callovo-Oxfordien au centre du bassin de Paris par les marqueurs organiques

The thermal history of the central part of the Paris basin is reconstructed using C₃₁ hopane $\mathrm{S}/\mathrm{R}$ isomerisation ratios and organic matter transformation ratios measured on Lower Toarcian and Callovo-Oxfordian samples. Maximum burial palaeotemperatures range between 90 and 115?°C for the Toarcian shales, and between 75 and 95?°C for the Callovo-Oxfordian samples, from the East to the centre of the basin, respectively. The amount of Late Cretaceous erosion was evaluated to be between ca. 400 to 600 m in the eastern part of the studied area and 100 to 300 m in the centre of the basin. To cite this article: C. Ménétrier et al., C. R. Geoscience 337 (2005).     

Early diagenesis of carbohydrates and lignin in mangrove sediments subject to variable redox conditions (French Guiana)

A comparative study of lignin and neutral carbohydrate compositions, combined with C, N and δ¹³C analyses, was carried out on sedimentary cores, and on various vascular plant species collected in mangrove swamps of French Guiana. The main purpose of this study was to assess the diagenesis of carbohydrates and lignin in brackish to hypersaline fine-grained mangrove sediments characterized by great changes in redox conditions. Distribution of carbohydrates in sediments reflects both the lability of these compounds and their efficient recycling. They are subject to selective degradation, cellulosic glucose and xylose appearing to be the two most labile neutral sugars. In contrast a relative increase in arabinose, rhamnose, fucose and hemicellulosic glucose between plants and sediments, suggests that they may be more refractory and/or that they also derive from microbial synthesis. The total carbon from lignin-derived phenols is higher in sediments than in mangrove plants as a consequence of their rather refractory character. Nevertheless, evidence of lignin decomposition was found to be independent of local environmental conditions. The various redox processes that occur in mangrove sediments depend on plant species, stages in forest development and season. Different redox conditions induce different mechanisms for the decomposition of lignin and thus induce changes in phenol distributions. At depth, in most mangroves, an increase in (Ad/Al)_v ratios and in deoxy sugars (fucose and rhamnose) content was significantly correlated with increased proportions of oxidized allochthonous organic debris deriving from the Amazonian detrital discharge, thus suggesting a specific source effect rather than a diagenesis induced change. Therefore, this study illustrates that both lignin and cellulose, derived from vascular plant debris, can be degraded in waterlogged mangrove sediments, and that their distribution depends on environmental conditions.     

Evolution of clay mineral assemblages and organic matter in the late glacial-Holocene sedimentary infill of Lake Annecy, (northwestern Alps): paleoenvironmental implications

The basin fill of Lake Annecy was investigated from a 44 m core which reached down to glacial sediments of the last glaciation (called Würm in the alpine areas). We analyzed three main parameters: sediment texture (optical microscopy and laser microgranulometry), clay mineral assemblages (CMA by XRD), and organic matter (OM by Rock-Eval pyrolysis). Settling of suspended load, under variable hydrodynamic conditions is the main depositional process. Both CMA and OM provenances can be recognized for the different sedimentary and igneous-metamorphic formations (Carboniferous to Quaternary, and older crystalline basement) and corresponding areas, in the surrounding region of Lake Annecy. Oligocene-Miocene molasses, Early Cretaceous marls, and Early-Middle Jurassic marls and shales are the main sedimentary sources. Two distinct processes were operating: destruction of glacial sediments (till sensu largo) and reworking, or direct erosion and run-off from ice-free catchment areas. Clay minerals related to pedogenesis, and non-reworked terrestrial and lacustrine OM, were progessively added to these primary sources during the Late Würmian/Holocene transition to warmer climatic conditions. Rapid modifications of CMA and OM sources during the earlier phase of sedimentary infilling (Unit 2) suggest that valley glaciers connected to the lake basin almost completely disappeared within a few centuries.     

Experimental study of mechanisms of fixation and reduction of uranium by sedimentary organic matter under diagenetic or hydrothermal conditions

Interactions between lignite and soluble uranyl species have been investigated experimentally at different temperatures from 20° to 400°C. Fixation of uranyl species by lignite (45° to 250°C) and their reduction to uraninite (120° to 400°C) were observed. The fixation of uranyl species by lignite results in the formation of stable organo-uranyl compounds. The reduction of uranyl species by lignite results in a stoichiometric liberation of H⁺ in the solution medium and in a dehydrogenation of lignite. This dehydrogenation can be attributed to two different processes. The first is an oxidation of alcohol functional groups into aldehyde or ketone functions accompanied by a simultaneous reduction of uranyl species. The second is a dehydrogenation of hydrocarbonaceous aliphatic moieties induced by the uranium species. The molecular hydrogen produced during this process is subsequently used for an additional reduction of uranyl species.     

Amphibolite facies conditions in the oceanic crust: example of amphibolitized flaser-gabbro and amphibolites from the Chenaillet ophiolite massif (Hautes Alpes,France)

Petrological and mineralogical data on amphibolitized gabbros from an Alpine ophiolite massif (Chenaillet Massif, France) are presented. Comparison with metagabbros dredged from the ocean floor shows that synkinematic amphibolite facies conditions may be reached in gabbros after their initial crystallization in the vicinity of the ridge. It is suggested that sub-horizontal plastic flow took place in the gabbroic layer near the axis of a slowly spreading ocean ridge before the intrusion of diabase dykes. This thermo-tectonic regime which at the Chenaillet produced flaser-gabbros and layers of foliated amphibolites with brown hornblende and pargasite, probably also affected most of the other ophiolitic gabbros of the Piemont zone prior to the low-temperature/high-pressure Alpine metamorphism.     

Hercynite–quartz-bearing granulites from Brejões Dome area, Jequié Block, Bahia, Brazil: Influence of charnockite intrusion on granulite facies metamorphism

In the present study, we describe and discuss the geology of aluminous–magnesian granulites and associated garnet-bearing charnockitic granulite from the Brejões Dome area, located in the Jequié Block, part of the São Francisco Craton in Bahia, Brazil. Investigation of metamorphic mineral assemblages allows the evaluation of P–T conditions for the formation of these rocks, and therefore to obtain constraints for the better understanding of the geological evolution of the area. We conclude that the rocks from the Brejões Dome area were formed under granulite facies conditions of low to intermediate pressure (5–8 kbar). Temperatures determined in samples of aluminous–magnesian granulites collected away from the dome are in the order of 850 °C, similar to those determined elsewhere in the southern part of the Itabuna–Salvador–Curaçá Orogen. However, samples of the same rock type collected close to the Brejões Dome are hercynite + quartz-bearing and record higher temperatures of about 900–1000 °C. It is suggested that the intrusion of the Brejões charnockite diapir was responsible for a local increase in temperature above the peak temperature of regional granulite metamorphism.     

Morphology and geochemistry of zircon: a case study on zircon from the microgranitoid enclaves

There are three types of zircon (i.e. Zircon A, Zircon B and Zircon C) in the microgranitoid enclaves from the Qingtian granite. Zircon A is of the smallest I_pr, I_py and I_el values with the largest range of variations; Zircon C is of the largest I_pr, I_py and I_el values with the smallest range of variations; and Zircon B is intermediate among the three types. The microprobe analysis of zircon demonstrates that the contents of trace elements (Hf, U, Y, Th) increase progressively with larger and larger variation from Zircon A through Zircon B to Zircon C. These characters snggest that the three types of zircon in the enclaves may have formed successively during the cooling mess of enclave magma, corresponding to different sites along with the intrusion of enclave magma. Because of positive correlations of the UO₂/HfO₂ratio with I_pr, the Th0₂/Y₂0₃ ratio with I_py, and the UO₂/(ThO₂+Y₂0₃) ratio with I_el, it is suggested that the variation in zircon typology is caused by selective substitution of trace elements on different surfaces of zircon. On the basis of enclave petrology and zircon typomorphism, it is believed that the enclave magma may be generated from partial melting of residual materials in deep regions where the granitic magma has been extracted. Project supported by the National Natural Science Foundation of China (Grant No. 49632080).     

Structure and metamorphism of the Karakorum gneisses in the Braldu-Baltoro Valley (North Pakistan)

Abstract

The Karakorum gneisses outcrop north of the complex suture separating the Indian-Pakistan plate from the Europe-Asia block; they grade to deformed earlier members of the Karakorum batholith ranging in age from Cretaceous to Miocene and are cross-cut by its later members. The main interest of the region lies in the fact that very young high-grade gneisses (Miocene), outline the southern edge of the Europe-Asia Plate. The tectonic and metamorpic evolution of the Braldu-Baltoro region is interpreted here as resulting from a poly phased history. The following structural sequence has been defined : - (1) A Dl isoclinal folding was accompanied by subparallel healed shear zones and by intense boudinage, and cross-cut by a dense net of post-Dl hetero-geneous leucogranitic veins and stocks; - (2) a major phase of EW trending recumbent folds (D2), is followed by (3) large open D3 folds generating EW trending domai structures (Dassu and Panmah domes); and (4) a late set of brittle to locally more ductile structures such as the southern thrust contact of the Karakorum gneisses with the Shyok suture zone. The sequence proposed here differs from other interpretations (Rex et al. 1988). We consider that the Dl event only may be attributed to the main India-Asia collision and that the D2-D3 events, interpreted as having occurred in a continuum, correspond to a late reactivation of the major thrusts and sutures related to continuing continental subduction.

A Dl-related intermediate pressure assemblage is preserved (Grt-St-Ky) in the upper levels of the tectonic pile; the estimated PT conditions determined are 10-4 Kb and 700°--525°C. In the core of the large D3 domes, late granoblastic recrystallization is widespread together with almost complete S1-S2 transposition, incipient melting and development of a low-pressure sillimanite-bearing assemblage where relicts of higher pressure minerals are locally preserved. Corresponding PT conditions are 650°-550°C and a lower pressure (5.5 to 2.5 Kb). As most of the observed structures at the lower levels (mineral lineations, boudinage) are clearly associated with (or reworked by) D2 and accentuated by D3 which was accompagnied by partial melting, D2 and D3 are interpreted as representing a continuum developed in the same PT field. It can be assumed also that the Baltoro granite was emplaced by the end of this combined D2-D3 event. From the Miocene ages published for the Baltoro granite (20 Ma to 8 Ma), the low-pressure evolution of the Karakorum gneisses may represent a very young high-grade assemblage. The age of Dl is less defined but at least older than 36 Ma old leucogranites.

The sharp contact along the Shyok Suture zone, interpreted as a large thrust (Main Karakorum Thrust - MKT) of this young high-grade metamorphic terrene against the older (older than 30-45 Ma from late undeformed intrusives) Kohistan-Ladakh island-arc domain, is interpreted, following Mattauer (1985), as resulting from the interaction between the still-ongoing northward movement of the Indo-Pakistan plate and an opposite southward continental subduction, seismically active, operating in Pamir.     

Organic Geochemistry of the Cenomanian–Turonian Bahloul Formation Petroleum Source Rock,Central and Northern Tunisia

Total organic carbon (TOC) determination, Rock‐Eval pyrolysis, extractable organic matter content (EOM) fractionation, gas chromatography (GC) and gas chromatography–mass spectrometry (GC–MS) analyses, were carried out on 79 samples from eleven outcrop cross sections of the Bahloul Formation in central and northern Tunisia. The TOC content varied between 0.23 to 35.6%, the highest average values (18.73%, 8.46% and 4.02%) being at the east of the study area (at Ain Zakkar, Oued Bahloul and Dyr Ouled Yahia localities, respectively). The Rock‐Eval maximum pyrolysis temperature (Tmax) values in the 424–453°C range delineated a general east‐west trend increase in the organic matter (OM) maturity. The disparity in hydrogen index (HI) values, in the range 114–824 mg hydrocarbons (HC) g^?1 TOC, is relevant for the discrepancy in the level of OM preservation and maturity among localities and samples. The n‐alkane distributions, maximizing in the C17 to C20 range, are typical for a marine planktonic origin, whereas pristine/phytane (Pr/Ph) average values in the 1–2 range indicate an oxic to suboxic depositional environment. Pr/n‐C17 and Ph/n‐C18 ratios in the 0.38–6.2 and 0.68–3.25 range, respectively, are consistent with other maturity indicators and the contribution of specific bacteria to phytol as a precursor of isoprenoids. The thermal maturity varies between late diagenesis to main‐stage of petroleum generation based on the optic and the cis‐trans isomerisation of the C29 sterane [20S/(20S+20R) and 14β(H),17β(H)/(14β(H),17β(H)+14α(H),17α(H)), respectively] and the terpane [18α(H)22,29,30‐Trisnorneohopane/(18α(H)22,29,30‐Trisnorneohopane+17α(H)22,29,30‐Trisnorhopane): Ts/(Ts+Tm)] ratios. The Bahloul OM is represented by an open marine to estuarine algal facies with a specific bacterial contribution as revealed by the relative abundance of the ααα‐20R C27 (33–44%), C28 (22–28%) and C29 (34–41%) steranes and by the total terpanes/total steranes ratio (1.2–5.33). These results attested that the Bahloul OM richness was controlled both by an oxygen minimum zone induced by high productivity and restricted circulation in narrow half graben structures and around diapirs of the Triassic salt.     

Les « Porphyroı̈des » de Bretagne méridionale : une unité de HP–BT dans la chaı̂ne hercynienneEvidence for HP–LT Hercynian metamorphism within the ‘Porphyroı̈des’ of South Brittany (France)

The so-called ‘Porphyro??des’ Unit of South Brittany is located below units marked by an early HP–LT event (blueschists from the Île de Groix) and above units marked by Upper Carboniferous HT metamorphism. P–T estimates in the Porphyro??des (at Belle-Île-en-Mer), using the phengite–chlorite thermobarometer, indicate pressures around 8 kbar and temperatures of 350–400 °C. These new estimates suggest that the early tectonic history of the ‘Porphyro??des’ should be linked to that of the overlying Blueschists, and imply a much larger areal extension of the HP–LT domain in this part of the Hercynian Belt. To cite this article: F. Le Hébel et al., C. R. Geoscience 334 (2002) 205–211.