XANES mapping of organic sulfate in three scleractinian coral skeletons

The presence and localization of organic sulfate within coral skeletons are studied by using X-ray absorption near edge structure spectroscopy (XANES) fluorescence. XANES spectra are recorded from four reference sulfur-bearing organic molecules: three amino acids (H-S-C bonds in cysteine; C-S-C bonds in methionine; one disulfide bond C-S-S-C bonds in cystine) and a sulfated sugar (C-SO₄ bonds in chondroitin sulfate). Spectral responses of three coral skeletons show that the sulfated form is extremely dominant in coral aragonite, and practically exclusive within both centres of calcification and the surrounding fibrous tissues of coral septa. Mapping of S-sulfate concentrations in centres and fibres gives us direct evidence of high concentration of organic sulfate in centres of calcification. Additionally, a banding pattern of S-sulfate is visible in fibrous part of the coral septa, evidencing a biochemical zonation that corresponds to the step-by-step growth of fibres.     

Growth of the Namche Barwa Syntaxis and associated evolution of the Tsangpo Gorge: Constraints from structural and thermochronological data

The eastern syntaxis of the Himalaya, Namche Barwa, is dominated by a north-plunging antiform which began to decompress/grow at approximately 4 Ma. New fission-track analyses on both apatite and zircon, combined with previous geochronological ages, indicate that the Namche Barwa Dome also extended laterally while growing vertically. Zircon fission-track ages range from 17.6 to 0.2 Ma and have a strong relationship to the main faults of the region, including the Tertiary Tsangpo Suture, with the younger ages inside the fault bounds towards the syntaxis core on the Indian Plate and the older ages away from the fault. Apatite ages reveal that the dome has grown laterally and now impinges over the older faulted margin onto the Asian Plate. The dome is traversed by the Tsangpo which has followed the trace of the Suture for over 1300 km from its source to the entrance of the dome near Dania. As the Tsangpo crosses the dome it departs from the Suture but rejoins it some 60 km northeastwards. We construe that the Suture has been displaced by the growing antiform and as a consequence, the antecedent river has been “dragged” in a left-lateral sense along the exhuming north-plunging dome. Restoring the Suture to its position prior to 4 Ma reveals a path of the Tsangpo eastwards across the present southwestern position of the Namche Barwa indentation. This geometric reconstrunction implies that the Tsangpo and the Brahmaputra were always one and the same river. In addition, the Tsangpo was tectonically forced into juxtaposition with a tributary of the Jiali-Parlung which it probably then captured. The capture was due to tectonic forcing, in the last 4 Ma, rather than headward retreat of the paleo-Brahmaputra as has been previously suggested.     

Experimental study of silica diffusion during metasomatic reactions in the presence of water at 550°C and 1000 bars

Metasomatic reactions between quartz and incompatible oxides or hydroxides were experimentally studied at 550°C and 1000 bars water pressure. Two porous pellets of the initial reagents pressed one against the other were used. Reaction rims in the millimeter range develop at the initial boundary in the oxide pellet. All the experiments show that an important transfer of silica occurs by diffusion in the stationary intergranular solution.The chemical transfer of silica through the intergranular fluid is quantitatively determined by studying the kinetics of growth of the forsterite rim in the system quartz-brucite. The kinetics limiting stage being silica transfer, the experiments allow the determination of the diffusion coefficient of silica through the solution. At 550°C and 1000 bars, a value of 2.4 × 10^?1cm² s¹ is found.This high value shows the importance of chemical diffusion in the intergranular fluid of rocks during metamorphic processes.     

Shallow seismicity at Montagne Pelée volcano,Martinique, Lesser Antilles

Continuous seismic monitoring at Martinique since the 1902 eruption of the Montagne Pelée volcano did not detect local earthquakes for the first 70 years. For the only eruption which occurred in this time span in 1929 the seismograph was 20 km away and of a standard type, not particularly suited for the detection of small-scale local seismicity. Improvement of the monitoring array over the last 15 years with the installation of sensors on the volcano itself allowed the detection of signals of local origin which were interpreted as being due to surface sources, such as rockfalls and landslides. Since December 1985 seismic sources in the volcano itself, i.e. small earthquakes at shallow depth, were identified and located with the aid of a temporary upgrading of the array close to these weak sources. Such an onset of local seismicity could not have been detected with previous seismic equipment; such episodes of seismicity in the volcano might have occurred in the past, apparently quiescent history of the volcano as the reinterpretation of seismograms of some events in 1976 would indicate, without evolving to more important volcanic phenomena. For seismographs on volcanoes the constant upgrading of observation capabilities is certainly perferred to a strict continuity of standard observations.     

The European coastal zone: characterization and first assessment of ecosystem metabolism

The geomorphic, oceanographic, terrestrial and anthropogenic attributes of the European coastal zone are described and published data on ecosystem function (primary production and respiration) are reviewed. Four regions are considered: the Baltic Sea, Mediterranean Sea, Black Sea and the European Atlantic coast including the North Sea. The metabolic database (194 papers) suffers from a non-homogeneous geographical coverage with no usable data for the Black Sea which was therefore excluded from this part of our study. Pelagic gross primary production in European open shelves is, by far, the most documented parameter with an estimated mean of 41 mmol C m⁻² d⁻¹, the lowest value is reported in the Mediterranean Sea (21 mmol C m⁻² d⁻¹) and the highest one in the Atlantic/North Sea area (51 mmol C m⁻² d⁻¹). Microphytobenthic primary production, mostly measured in shallow areas, is extrapolated to the entire 0–200 m depth range. Its contribution to total primary production is low in all regions (mean: 1.5 mmol C m⁻² d⁻¹). Although macrophyte beds are very productive, a regional production estimate is not provided in this study because their geographical distribution along the European coastline remains unknown. Measurements of pelagic community respiration are clearly too sparse, especially below the euphotic zone, to yield an accurate picture of the fate of organic matter produced in the water column. With a mean value of 17 mmol C m⁻² d⁻¹, benthic community respiration consumes approximately 40% of the pelagic organic matter production. Estuaries generally exhibit high metabolic rates and a large range of variation in all parameters, except microphytobenthic primary production. Finally, the problem of eutrophication in Europe is discussed and the metabolic data obtained in the framework of the Land–Ocean Interactions in the Coastal Zone (LOICZ) project are compared with available direct measurements of net ecosystem production.     

A new method to determine the gravity field of small bodies from line-of-sight acceleration data

We present a new method to derive line-of-sight acceleration observables from spacecraft radio tracking data. The observables can be used to estimate the mass and gravity of a natural satellite as a spacecraft flyby. The corresponding observation model adapts to one-way and two/three-way tracking modes. As a test case for method validation and application, we estimated the mass and degree two gravity field for the Martian moon Phobos using simulated tracking data when the spacecraft Mars Express flew by Phobos on 2013 December 29. We have a few real tracking data during flyby and they will be used to confirm raw data simulation. The main purpose of this paper is to demonstrate the method of line-of-sight acceleration reduction from raw tracking data and the feasibility to estimate mass and gravity of a natural satellite using this type of observable. This novel method is potentially applicable to planet and asteroid gravity field studies combined with Doppler tracking data.     

Circumstellar dynamics and transfer

This paper is both a review and a presentation of new models. Observation and modelization of circumstellar envelopes of early type or late type stars are now quickly evolving because of new techniques and facilities for observations, and increased power of computers. More and more complex physical phenomena involved in mass driving can now be modelized, at many different size scales. While most of models were previously based on informations derived from spectrophotometric data only or on measurements concerning objects observed with no spatial resolution, observations at much increased angular resolution can provide constraints on models of these phenomena. Theory and modelization must take this new situation into account. Two approaches are possible and effectively used. On the one hand, dynamical/physical self consistent models can be built; on the other hand, elaborate semi-empirical models including complicated distributions of matter with asymmetries (3D models) can be built and fitted for direct comparison with results of High Angular Resolution Measurements. Adding such constraints to classical constraints leads to a new insight in the physics of circumstellar matter and, through it, of stellar and interstellar evolution. Two examples have been chosen, in which new models are presented and assuming or not spherical symmetry is carefully discussed:

?Circumstellar matter around evolved stars

?Shock waves propagating in the circumstellar matter around evolved stars.

     

Energy budget for the Sahel surface layer during the ECLATS experiment

The measurements obtained during the ECLATS experiment were used in order to determine the surface energy budget of the Sahel region (Niamey, Niger). This expedition was carried out from November 15 to December 10, 1980, during the dry period. Some data were collected by an instrumented aircraft, from which the turbulent fluxes were obtained in the boundary layer around midday; data were also collected at a surface station in order to estimate the surface energy budget continuously by the profile method. The aircraft measurements show the homogeneity of the vertical fluxes over large areas, allowing generalization to the bushy steppe of the Sahel region. The mean diurnal cycle of the energy budget is characterized by high values of ground heat flux and weak values of latent heat flux (deduced from the balance of the energy budget). This cycle is compared with that of the Koorin expedition, performed in similar conditions (tropical savanna in the dry period). We compare the three midday budgets: during Koorin; during ECLATS, at the ground station, and with the aircraft. The important differences that appear in the net radiative flux are explained by the difference in surface albedo.Ecole des Sciences, Université de Niamey, B.P. 10662 Niamey, Niger.     

Inland saline lakes with lagoonal biota: some reflections on the concept and nature of athalassic (non-marine), paralic and marine saline waters

First, some inland basins with lagoonal (or paralic) biota are brieffly described. The different kinds of saline aquatic environments are then defined and the composition of their biota are discussed. Finally, the still unknown microbiogeochemical composition of concentrated inland waters is discussed. Under arid and endorheic conditions, it seems that the wider and the more geologically complex a hydrological basin is, the more biogeochemically similar to seawater is the water of its terminal lake. The evolution of the microbiogeochemical complexity of seawater through geological times is considered.This paper has been the subject of considerable discussion among referees. Not all of the views expressed by the author are accepted by them.