Further quantification of the sources and sinks of thermospheric O1D) atoms

In this paper we confirm an earlier finding that the reaction

constitutes a major source of OI 6300 Å dayglow. The rate coefficient for this reaction is found to be consistent with an auroral result, namely k₁ ≈ 6 × 10^?12cm³s^?1. We correct an error in an earlier publication and demonstrate that reaction (1) is consistent with the laboratory determined quenching rate for the reaction

where $\text{k}{}_2\text{= 2.3 × 10}{}^{\mathrm{?11}}\text{cm}{}^3\text{s}{}^{\mathrm{?1}}$. Dissociative recombination of O⁺₂ with electrons is found to be a major daytime source in summer above ～220 km.     

Quenching of O+(2D) by electrons in the thermosphere

A major loss process for the metastable species, O⁺(²D), in the thermosphere is quenching by electrons

$\text{O}{}^{\mathrm{+}}\text{(}{}^2\text{D) + e → O}{}^{\mathrm{+}}\text{(}{}^4\text{S) + e}$

.To date no laboratory measurement exists for the rate coefficient of this reaction. Thermospheric models involving this process have thus depended on a theoretically calculated value for the rate coefficient and its variation with electron temperature. Earlier studies of the O⁺(²D) ion based on the Atmosphere Explorer data gathered near solar minimum, could not quantify this process. However, Atmosphere Explorer measurements made during 1978 exhibit electron densities that are significantly enhanced over those occurring in 1974, due to the large increases that have occurred in the solar extreme ultraviolet flux. Under such conditions, for altitudes ? 280 km, the electron quenching process becomes the major loss mechanism for O⁺(²D), and the chemistry of the N⁺₂ ion, from which the O⁺(²D) density is deduced, simplifies to well determined processes. We are thus able to use the in situ satellite measurements made during 1978 to derive the electron quenching rate coefficient. The results confirm the absolute magnitude of the theoretical calculation of the rate coefficient, given by the analytical expression k(T_e) = 7.8 × 10^?8 (T_e/300)^?0.5cm³s^?1. There is an indication of a stronger temperature dependence, but the agreement is within the error of measurement.     

Zodiacal light surface brightness measurements by Atmosphere Explorer-C

Using the visible airglow photometer on the Atmosphere Explorer-C satellite, we have mapped the zodiacal light surface brightness at the wavelengths monitored by the instrument: 3371, 4278, 5200, 5577, 6300, and 7319 Å. The study constitutes a survey over this wavelength range, covering most of the celestial sphere, from altitudes above the atmospheric emissions, and free from atmospheric scattering and attenuation. The intensity variations reveal enhancements near elongations of 130°, and possibly near 60°, at all wavelengths. The intensity of the zodiacal light near the ecliptic pole is found to be ～30 S₁₀. The color ratio with respect to the Sun is found to be redder than the Sun (0.7) at all elongations.     

N2 vibrational distribution in aurorae

The N₂ vibrational distribution is calculated for a specific IBC Class II aurora using as input, data obtained from coordinated rocket and satellite observations and currently accepted excitation and quenching rates. The results of the calculations indicate no significant vibrational enhancements for this specific aurora nor for “upper limit” estimates for more intense aurorae. We conclude from this study that if significantly larger concentrations of vibrationally excited N₂ molecules exist in the aurora, as recent rocket e.u.v. measurements suggest, current concepts of the sources and sinks of N₂ vibrational excitation will require significant revision.     

Phytoplankton distribution and productivity in a highly turbid, tropical coastal system (Bach Dang Estuary, Vietnam)

Phytoplankton diversity, primary and bacterial production, nutrients and metallic contaminants were measured during the wet season (July) and dry season (March) in the Bach Dang Estuary, a sub-estuary of the Red River system, Northern Vietnam. Using canonical correspondence analysis we show that phytoplankton community structure is potentially influenced by both organometallic species (Hg and Sn) and inorganic metal (Hg) concentrations. During March, dissolved methylmercury and inorganic mercury were important factors for determining phytoplankton community composition at most of the stations. In contrast, during July, low salinity phytoplankton community composition was associated with particulate methylmercury concentrations, whereas phytoplankton community composition in the higher salinity stations was more related to dissolved inorganic mercury and dissolved mono and tributyltin concentrations. These results highlight the importance of taking into account factors other than light and nutrients, such as eco-toxic heavy metals, in understanding phytoplankton diversity and activity in estuarine ecosystems.     

The seasonal effect of nitric oxide cooling on the thermospheric U.V. heat budget

It has recently been shown that radiative cooling of vibrationally excited NO at 5.3μm could result in a significant loss of heat from the lower thermosphere. In contrast to this effect, recent rocket measurements of atomic oxygen fine structure radiation at 63 μm suggests that radiation entrapment may greatly reduce the effectiveness of this process in cooling the lower thermosphere. In this paper we examine the effects of these processes on the u.v. heating efficiency ?. We point out that in the past the definition used for the heating efficiency runs counter to its logical application, and that strictly speaking, the above processes should be included as cooling processes in the energy equations. However, in order to compare out findings with past work we include the 0 and NO radiative cooling in the calculation of an effective heating efficiency, ?. We find that ? can vary from 45 to 60% depending on how the two radiative cooling mechanisms are included in the calculation. In addition it is found that the shape of the altitude profile of the heating efficiency varies significantly with season, while the peak value remains relatively invariant.     

Associative ionization of N(2D) and O

Recent laboratory measurements have shown that N(²P) atoms, and thus probably hot N(²D) atoms, will recombine with atomic oxygen via an associative ionization process at the gas kinetic rate. While the reaction is endothermic, it has been suggested that this has interesting implications for the upper atmosphere in that N(²D) atoms in the tail of the velocity distribution could provide an additional source of NO⁺ through the reverse of the dissociative recombination reaction

$\text{NO}{}^{\mathrm{+}}\text{+ e ?}\text{N}\text{(}{}^2\text{D}\text{) +}\text{O}$

. It has also been suggested that this process might account for the difference between a laboratory determination of the rate coefficient and that determined from the Atmospheric Explorer Satellite data. In this paper we investigate further the likelihood of the associative ionization of N(²D) and O playing a significant role in the normal ionosphere, in the light of several recent relevant studies. We conclude that the associative ionization process is not an important factor and that a more probable cause for disagreements in the various determinations of the recombination coefficient, is the difference in excited states of the ions in the various experiments.     

The 1988–2003 Greenland ice sheet melt extent using passive microwave satellite data and a regional climate model

Measurements from ETH-Camp and JAR1 AWS (West Greenland) as well as coupled atmosphere-snow regional climate simulations have highlighted flaws in the cross-polarized gradient ratio (XPGR) technique used to identify melt from passive microwave satellite data. It was found that dense clouds (causing notably rainfall) on the ice sheet severely perturb the XPGR melt signal. Therefore, the original XPGR melt detection algorithm has been adapted to better incorporate atmospheric variability over the ice sheet and an updated melt trend for the 1988–2003 period has been calculated. Compared to the original algorithm, the melt zone area increase is eight times higher (from 0.2 to 1.7% year⁻¹). The increase is higher with the improved XPGR technique because rainfall also increased during this period. It is correlated to higher atmospheric temperatures. Finally, the model shows that the total ice sheet runoff is directly proportional to the melt extent surface detected by satellites. These results are important for the understanding of the effect of Greenland melting on the stability of the thermohaline circulation.     

Charge exchange of metastable D oxygen ions with N2 in the thermosphere

Measurements of N₂⁺ and supporting data made on the Atmosphere Explorer-C satellite in the ionosphere are used to study the charge exchange process

$\text{O}{}^{\mathrm{+}}\text{(}{}^2\text{D}\text{)+}\text{N}{}_2\text{→}\text{k}\text{N}{}^{\mathrm{+}}{}_2\text{+}\text{O}$

The equality k = (5 ± 1.7) × 10^?10cm³s^?1. This value lies close to the lower limit of experimental uncertainty of the rate coefficient determined in the laboratory. We have also investigated atomic oxygen quenching of O⁺(²D) and find that the rate coefficient is 2 × 10^?11 cm³s^?1 to within approximately a factor of two.