Minerals and design of new waste forms for conditioning nuclear waste

Safe storage of radioactive waste is a major challenge for the nuclear industry. Mineralogy is a good basis for designing ceramics, which could eventually replace nuclear glasses. This requires a new storage concept: separation-conditioning. Basic rules of crystal chemistry allow one to select the most suitable structures and natural occurrences allow assessing the long-term performance of ceramics in a geological environment. Three criteria are of special interest: compatibility with geological environment, resistance to natural fluids, and effects of self-irradiation. If mineralogical information is efficient for predicting the behaviour of common, well-known minerals, such as zircon, monazite or apatite, more research is needed to rationalize the long-term behaviour of uncommon waste form analogs.     

Tritium�Chelium groundwater age used to constrain a groundwater flow model of a valley-fill aquifer contaminated with trichloroethylene (Quebec, Canada)

Tritium?Chelium groundwater dating was carried out in a trichloroethylene (TCE)-contaminated valley-fill aquifer system in Quebec, Canada, where a numerical groundwater flow model was developed. Forty seven discrete groundwater and dissolved gas samples were obtained along two flow paths originating from known TCE source zones whose related plumes converge down gradient to form a single plume. Sampling points in monitoring wells were projected onto vertical sections showing particle tracks along the two flow paths. At these points, simulated advective ages obtained from particle tracking were matched to tritium?Chelium ages using different porosity values; the best match was 0.35. Ages were also obtained above and below a prodeltaic silty aquitard in a portion of the aquifer where some source zones are located, which provide groundwater and TCE transit times through the aquitard as well as a mean vertical hydraulic conductivity that agrees with previous estimates used in the model. In certain locations, anomalously old ages associated with high terrigenic ⁴He indicate areas where groundwater from the underlying proglacial unit flows upward into the deltaic sand aquifer through aquitard windows. Upflow locations correspond with increased TCE concentrations, suggesting significant TCE provenance through the proglacial unit originating from a previously unrecognized TCE source zone.     

Seasonal variations in ectotherm growth rates: Quantifying growth as an intermittent non steady state compensatory process

Generally, growth rates of living organisms are considered to be at steady state, varying only under environmental forcing factors. For example, these rates may be described as a function of light for plants or organic food resources for animals and these could be regulated (or not) by temperature or other conditions. But, what are the consequences for an individual's growth (and also for the population growth) if growth rate variations are themselves dynamic and not steady state? For organisms presenting phases of dormancy or long periods of stress, this is a crucial question. A dynamic perspective for quantifying short-term growth was explored using the daily growth record of the scallop Pecten maximus (L.). This species is a good biological model for ectotherm growth because the shell records growth striae daily. Independently, a generic mathematical function representing the dynamics of mean daily growth rate (MDGR) was implemented to simulate a diverse set of growth patterns. Once the function was calibrated with the striae patterns, the growth rate dynamics appeared as a forced damped oscillation during the growth period having a basic periodicity during two transitory phases (mean duration 43 days) and appearing at both growth start and growth end. This phase is most likely due to the internal dynamics of energy transfer within the organism rather than to external forcing factors. After growth restart, the transitory regime represents successive phases of over-growth and regulation. This pattern corresponds to a typical representation of compensatory growth, which from an evolutionary perspective can be interpreted as an adaptive strategy to coping with a fluctuating environment.     

A multi-frequency Acoustic Concentration and Velocity Profiler (ACVP) for boundary layer measurements of fine-scale flow and sediment transport processes

The use of acoustics to measure sediment transport boundary layer processes has gained increasing acceptance over the past two decades. This has occurred through the development of increasingly sophisticated measuring systems and theoretical developments, which have enabled flow and suspended sediment parameters to be obtained from acoustic data with a high degree of accuracy. Until relatively recently, separate acoustic systems were used to measure flow and suspended sediment concentration. Over the past few years, however, the technology has become sufficiently advanced so that flow and sediment measurements can be integrated into a single system. This integration provides, quasi-instantaneous, non-intrusive, co-located, high temporal-spatial resolution measurements of benthic flow and sediment processes. Here the development of such an instrument, the Acoustic Concentration and Velocity Profiler (ACVP) is described. The theory underpinning its application is outlined, new approaches to velocity de-aliasing and suspended sediment inversion instabilities using multi-frequency capabilities are presented and the application of the system to sediment transport processes over a sandy ripple bed is illustrated. The observations clearly show the value of such instrumentation for studying the dynamical interaction between the bed, the flow and the sediments at and within the bottom boundary layer.     

Lithospheric tectonic structures developed under high-grade metamorphism in the Southern part of Madagascar

Abstract

This paper describes the tectono-metamorphic evolution of a segment of the Precambrian deep crust, in the southern Madagascar island. This crust corresponds to an Archaean basement reworked by a widespread, late panAfrican event (550–580 Ma) during the formation of the Mozambican belt. The finite geometry and associated metamorphism are depicted by satellite imaging, field mapping and P-T estimations using both conventional thermobarometric methods and TWEEQ software program with internally consistent thermodynamic data and uniform set of solution models. The structural pattern developed during high-grade metamorphism shows the juxtaposition of domains with complex fold geometries separated by a 15 km wide ductile shear zone. Within the folded domains, kilometre scale interference patterns associated with strongly dipping metamorphic stretching lineations can be described as superposed folding (F1 and F2 folds). The tight and upright F2 folds result from East-West horizontal shortening. The shear zone is defined by homogeneous orientations of steep foliations, sub-horizontal stretching lineations, and kilometre scale strain gradient. Within the shear zone, we observe dominant non-coaxial criteria at various scales that are consistent with a sinistral strike-slip system during D2 deformation stage. Nevertheless, we have also found in the shear zone, geometries typical of a horizontal shortening. Such a strain pattern is characteristic of transpression tectonics.

The synkinematic metamorphic conditions are estimated on mafic garnetiferous metabasites. Results show that regional transpression tectonics has developed under very high and constant thermal regime (about 800°C). A pressure gap, of about 3 kbar between the domains separated by the shear zone is identified. This implies tectonic coupling of two different structural levels during tranpressive tectonic.     

Volatile transport on inhomogeneous surfaces: I – Analytic expressions,with application to Pluto’s day

The two orders of magnitude drop between the measured atmospheric abundances of non-radiogenic argon, krypton and xenon in Earth versus Mars is striking. Here, in order to account for this difference, we explore the hypothesis that clathrate deposits incorporated into the current martian cryosphere have sequestered significant amounts of these noble gases assuming they were initially present in the paleoatmosphere in quantities similar to those measured on Earth (in mass of noble gas per unit mass of the planet). To do so, we use a statistical-thermodynamic model that predicts the clathrate composition formed from a carbon dioxide-dominated paleoatmosphere whose surface pressure ranges up to 3 bars. The influence of the presence of atmospheric sulfur dioxide on clathrate composition is investigated and we find that it does not alter the trapping efficiencies of other minor species. Assuming nominal structural parameters for the clathrate cages, we find that a carbon dioxide equivalent pressure of 0.03 and 0.9 bar is sufficient to trap masses of xenon and krypton, respectively, equivalent to those found on Earth in the clathrate deposits of the cryosphere. In this case, the amount of trapped argon is not sufficient to explain the measured Earth/Mars argon abundance ratio in the considered pressure range. In contrast, with a 2% contraction of the clathrate cages, masses of xenon, krypton and argon at least equivalent to those found on Earth can be incorporated into clathrates if one assumes the trapping of carbon dioxide at equivalent atmospheric pressures of ～2.3 bar. The proposed clathrate trapping mechanism could have then played an important role in the shaping of the current martian atmosphere.     

The remarkable surface homogeneity of the Dawn mission target (1) Ceres

Dwarf-planet (1) Ceres is one of the two targets, along with (4) Vesta, that will be studied by the NASA Dawn spacecraft via imaging, visible and near-infrared spectroscopy, and gamma-ray and neutron spectroscopy. While Ceres’ visible and near-infrared disk-integrated spectra have been well characterized, little has been done about quantifying spectral variations over the surface. Any spectral variation would give us insights on the geographical variation of the composition and/or the surface age. The only work so far was that of Rivkin and Volquardsen ([2010], Icarus 206, 327) who reported rotationally-resolved spectroscopic (disk-integrated) observations in the 2.2–4.0 μm range; their observations showed evidence for a relatively uniform surface.Here, we report disk-resolved observations of Ceres with SINFONI (ESO VLT) in the 1.17–1.32 μm and 1.45–2.35 μm wavelength ranges. The observations were made under excellent seeing conditions (0.6″), allowing us to reach a spatial resolution of ～75 km on Ceres’ surface. We do not find any spectral variation above a 3% level, suggesting a homogeneous surface at our spatial resolution. Slight variations (about 2%) of the spectral slope are detected, geographically correlated with the albedo markings reported from the analysis of the HST and Keck disk-resolved images of Ceres (Li et al. [2006], Icarus 182, 143; Carry et al. [2008], Astron. Astrophys. 478, 235). Given the lack of constraints on the surface composition of Ceres, however, we cannot assert the causes of these variations.     

Characterization of subsurface fluxes at the plot scale during flash floods in the Valescure catchment,France

This study focuses on a 10-m² plot within a granitic hillslope in Cevennes mountainous area in France, in order to study infiltration and subsurface hydrological processes during heavy rainfalls and flash floods. The monitoring device included water content at several depths (0–70 cm for the shallow soil water; 0–10 m for the deep water) during both intense artificial and natural rainfall events, chemical and physical tracers, time-lapse electrical resistivity tomography. During the most intense events, the infiltrated water was estimated to be some hundreds of millimetres, which largely exceeds the topsoil capacity (≤40 cm deep in most of the cases). The weathered/fractured rock area below the soil clearly has an active role in the water storage and sub-surface flow dynamics. Vertical flow was dominant in the first 0–10 m, and lateral flow was effective at 8–10 m depth, at the top of the saturated area. The speed of the vertical flow was estimated between 1 and 10 m/hr, whereas it was estimated between 0.1 and 1 m/hr for the lateral flow. The interpretation of the experiments might lead to a local pattern of the 2D-hydrological processes and profile properties, which could be generic for most of the mountainous catchments under Mediterranean climate. It suggests that fast triggering of floods at the catchment scale cannot be explained by a mass transfer within the hillslope, but should be due to a pressure wave propagation through the bedrock fractures, which allows exfiltration of the water downstream the hillslope.     

Opening and resetting temperatures in heating geochronological systems

We present a theoretical model for diffusive daughter isotope loss in radiochronological systems with increasing temperature. It complements previous thermochronological models, which focused on cooling, and allows for testing opening and resetting of radiochronometers during heating. The opening and resetting temperatures are, respectively,