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排序方式: 共有252条查询结果,搜索用时 15 毫秒
1.
Jérôme Nomade Emmanuel Chapron Marc Desmet Jean-Louis Reyss Fabien Arnaud Vincent Lignier 《地学学报》2005,17(4):350-357
Sediment archives from a mountain lake are used as indicators of seismotectonic activity in the Grenoble area (French western Alps, 45°N). Sedimentological analysis (texture and grain-size characteristics) exhibits several layers resulting from instantaneous deposits in Lake Laffrey: six debris flow events up to 8 cm thick can be attributed to slope failure along the western flank of the basin. Dating with 210Pb and 137Cs gamma counting techniques and the reconnaissance of historical events, provide a constrained age-depth model. Over the last 250 years, five of such debris flow deposits could be related to historical earthquakes of MSK intensities greater than VI over an area of <60 km. One debris flow deposit triggered at the beginning of the last century can be related to an historical landslide possibly triggered by the artificial regulation of the lake level. 相似文献
2.
In order to assess in fish the maternal transfer of alkylphenolic compounds to the progeny, the identification and quantification of the labelled compounds present in oocytes and embryos was conducted after dietary exposure of mature female mosquitofish to 14C-4n-nonylphenol during vitellogenesis and embryogenesis respectively. Radioactivity found in bile and liver extracts accounted for 0.9-0.6 and 0.2-0.1% of ingested radioactivity for females exposed during vitellogenesis and embryogenesis respectively. The amount of extractable radioactivity present in oocytes and embryos was 0.19 and 0.07% of the ingested dose respectively. The radio-HPLC profiles obtained from bile, liver, oocyte and embryo extracts were similar. They showed the presence of 4n-NP-glucuronide as the major metabolite and traces of unchanged 4n-NP. The other metabolites corresponded to 8-hydroxynonylphenol, 9-(4-hydroxyphenyl)-nonanoic acid and para-hydroxybenzoic acid which is the final product of the alkyl chain oxidation. Our results indicate that exposure of ovoviviparous female fish to 4-NP during vitellogenesis and embryogenesis leads to the contamination of the progeny by 4-NP and its metabolites. 相似文献
3.
Four sediment cores from the Polar frontal zone and the Antarctic zone in the Indian sector of the Southern Ocean present an increase of authigenic uranium during glacial periods. We show that this increase in uranium is due to a combination of (i) an increase in the lateral transport of organic matter, (ii) a decrease in the oxygen in deep waters, and (iii) a process of diagenesis. It appears that uranium concentration cannot be used as a proxy of palaeoproductivity in the Southern Ocean, as previously suggested by Kumar et al. in 1995. To cite this article: L. Dezileau et al., C. R. Geoscience 334 (2002) 1039–1046. 相似文献
4.
Abderrahim Essaifi Alain Potrel Ramon Capdevila Jean-Louis Lagarde 《Comptes Rendus Geoscience》2003,335(2):193-203
The bimodal magmatism of central Jebilet is dated to 330.5+0.68?0.83 Ma by UPb dating on zircons. This age, similar to that of the syntectonic Jebilet cordierite-bearing granitoids, corresponds to the age of the local major tectonometamorphic event. The syntectonic plutonism of the Jebilet massif, composed of tholeiitic, alkaline, and peraluminous calc-alkaline series, is variegated. Magmas emplacement was favoured by the local extension induced by the motion along the western boundary of the Carboniferous basins of the Moroccan Meseta. The Jebilet massif exemplifies the activation of various magmas sources during an episode of continental convergence and crustal wrenching. 相似文献
5.
Jean-Louis Le Mouël Pierre-Noël Mayaud Peter Shebalin 《Comptes Rendus Geoscience》2003,335(13):935-941
Big perturbations of the magnetic field (amplitudes larger than 250 nT) are simply detected by subtracting the values of a model from the measurements of CHAMP satellite. Taking a full year of CHAMP data and organizing them in four subsets of three months length (spring, summer, autumn, winter), it is found that: (a) the two domains where such big perturbations mainly exist are limited, in both hemispheres, by a parallel of high latitude of the corrected geomagnetic coordinates system; (b) a conspicuous seasonal (annual) variation affects the density of the perturbations and is opposite in the two hemispheres. We hold that these perturbations are linked to the midday magnetic activity within the auroral zone, long ago described by one of us (Mayaud, 1956). The source of the perturbations observed at the satellite altitude would be field-aligned currents resulting from the penetration of the solar wind into the magnetospheric cusps. To cite this article: J.-L. Le Mouël et al., C. R. Geoscience 335 (2003). 相似文献
6.
Gleb S Pokrovski Jacques Schott Jean-Louis Hazemann 《Geochimica et cosmochimica acta》2003,67(19):3559-3573
The influence of aqueous silica on the hydrolysis of iron(III) nitrate and chloride salts in dilute aqueous solutions (mFe ∼ 0.01 mol/kg) was studied at ambient temperature using X-ray absorption fine structure (XAFS) spectroscopy at the Fe K-edge. Results show that in Si-free iron nitrate and chloride solutions at acid pH (pH < 2.5), Fe is hexa-coordinated with 6 oxygens of H2O- and/or OH-groups in the first coordination sphere of the metal, at an Fe-O distance of 2.00 ± 0.01 Å. With increasing pH (2.7 < pH < 13), these groups are rapidly replaced by bridging hydroxyls (-OH-) or oxygens (-O-), and polymerized Fe hydroxide complexes form via Fe-(O/OH)-Fe bonds. In these polymers, the first atomic shell of iron represents a distorted octahedron with six O/OH groups and Fe-O distances ranging from 1.92 to 2.07 Å. The Fe octahedra are linked together by their edges (Fe-Fe distance 2.92-3.12 Å) and corners (Fe-Fe distance ∼3.47 ± 0.03 Å). The Fe-Fe coordination numbers (Nedge = 1-2; Ncorner = 0.5-0.7) are consistent with the dominant presence of iron dimers, trimers and tetramers at pH 2.5 to 2.9, and of higher-polymerized species at pH > 3.At pH > 2.5 in the presence of aqueous silica, important changes in Fe(III) hydrolysis are detected. In 0.05-m Si solutions (pH ∼ 2.7-3.0), the corner linkages between Fe octahedra in the polymeric complexes disappear, and the Fe-Fe distances corresponding to the edge linkages slightly increase (Fe-Feedge ∼ 3.12-3.14 Å). The presence of 1 to 2 silicons at 3.18 ± 0.03 Å is detected in the second atomic shell around iron. At basic pH (∼12.7), similar structural changes are observed for the iron second shell. The Fe-Si and Fe-Fe distances and coordination numbers derived in this study are consistent with (1) Fe-Si complex stoichiometries Fe2Si1-2 and Fe3Si2-3 at pH < 3; (2) structures composed of Fe-Fe dimers and trimers sharing one or two edges of FeO6-octahedra; and (3) silicon tetrahedra linked to two neighboring Fe octahedra via corners. At higher Si concentration (0.16 m, polymerized silica solution) and pH ∼ 3, the signal of the Fe second shell vanishes indicating the destruction of the Fe-Fe bonds and the formation of different Fe-Si linkages. Moreover, ∼20 mol.% of Fe is found to be tetrahedrally coordinated with oxygens in the first coordination shell (RFe-O = 1.84 Å). This new finding implies that Fe may partially substitute for Si in the tetrahedral network of the silica polymers in Si-rich solutions.The results of this study demonstrate that aqueous silica can significantly inhibit iron polymerization and solid-phase formation, and thus increase the stability and mobility of Fe(III) in natural waters. The silica “poisoning” of the free corner sites of iron-hydroxide colloids should reduce the adsorption and incorporation of trace elements by these colloids in Si-rich natural waters. 相似文献
7.
8.
Georges Aouad Valérie Geoffroy Jean-Marie Meyer Jean-Louis Crovisier Denis Damidot Peter Stille 《Comptes Rendus Geoscience》2005,337(15):1340-1347
The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005). 相似文献
9.
Claudio Marchesi William L. Griffin Carlos J. Garrido Jean-Louis Bodinier Suzanne Y. O’Reilly Norman J. Pearson 《Contributions to Mineralogy and Petrology》2010,159(3):315-330
The western part of the Ronda peridotite massif (Southern Spain) consists mainly of highly foliated spinel-peridotite tectonites
and undeformed granular peridotites that are separated by a recrystallization front. The spinel tectonites are interpreted
as volumes of ancient subcontinental lithospheric mantle and the granular peridotites as a portion of subcontinental lithospheric
mantle that underwent partial melting and pervasive percolation of basaltic melts induced by Cenozoic asthenospheric upwelling.
The Re–Os isotopic signature of sulfides from the granular domain and the recrystallization front mostly coincides with that
of grains in the spinel tectonites. This indicates that the Re–Os radiometric system in sulfides was highly resistant to partial
melting and percolation of melts induced by Cenozoic lithospheric thermal erosion. The Re–Os isotopic systematics of sulfides
in the Ronda peridotites thus mostly conserve the geochemical memory of ancient magmatic events in the subcontinental lithospheric
mantle. Os model ages record two Proterozoic melting episodes at ~1.6 to 1.8 and 1.2–1.4 Ga, respectively. The emplacement
of the massif into the subcontinental lithospheric mantle probably coincided with one of these depletion events. A later metasomatic
episode caused the precipitation of a new generation of sulfides at ~0.7 to 0.9 Ga. These Proterozoic Os model ages are consistent
with results obtained for several mantle suites in Central/Western Europe and Northern Africa as well as with the Nd model
ages of the continental crust of these regions. This suggests that the events recorded in mantle sulfides of the Ronda peridotites
reflect different stages of generation of the continental crust in the ancient Gondwana supercontinent. 相似文献
10.
Pits in ocean basalt glass are often attributed to the activity of microorganisms, however, neither the mechanism of formation of pits in glass nor the involvement of microorganisms have been confirmed by experimentation. Experimental abiotic corrosion of basalt glass with 1% hydrofluoric acid (HF), a proxy for more slowly acting organic acids, produces pits that are similar in size, shape, and distribution to pits found in basalt glass collected from the ocean floor and basalt glass incubated with microorganisms. This pit formation by HF etching was demonstrated by comparing secondary electron images taken before and after the acid treatment. The formation of pits by abiotic corrosion of basalt glass is an alternate hypothesis for the origin of these features, and the interpretation of these features as biomarkers may require a resolution of these alternative hypotheses. 相似文献