The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset I: The Nyong River Basin,Cameroon

Simultaneously acquiring time series of climate, hydrology and hydrochemical data over decades on river systems is pivotal to understand the complex interactions involving rock, soil water, air and biota in the Critical Zone, to build integrated modelling and to propose predictive scenarios. Among the Critical Zone Observatories (CZOs) implemented in the past 25 years, only a few are located in the humid Tropics despite the importance of these regions in terms of population density, fast-changing land use, biodiversity hotspots, biomass stock on continents, size of river systems, etc. Since 1994, weathering and erosion processes and fluxes have been investigated at both local (experimental watershed) and regional scales in the Nyong River Basin (Cameroon) which belongs to the Critical Zone Observatories network named Multiscale TROPIcal CatchmentS (M-TROPICS). The data shared by M-TROPICS in Cameroon are: (1) rainfall; (2) air temperature, air relative humidity, wind speed and direction, and global radiation; (3) stream and river water level; (4) pH, electrical conductivity, water temperature and suspended particulate matter (SPM) concentration; (5) major ion, alkalinity and dissolved organic carbon (DOC) concentrations. The dataset already contributed to describe the water partitioning in these tropical humid watersheds, to better understand the factors controlling chemical weathering and physical erosion in tropical ecosystems, particularly the role of organic matter. The dataset also contributed to calculate elemental weathering fluxes and saprolite production rate and to propose denudation rates on tropical cratonic landscapes. Hydrological modelling allowed quantification of the geographical water sources contributing to streamflow. DOC data were used to determine greenhouse-gas emissions and carbon budgets from African inland waters. However, long-term solute concentrations at the outlet of a small tributary of the Nyong River exhibit non-stationary behaviour over the last 26 years. The processes governing those fluctuations are not yet fully understood and might be related to changes in the hydrological regime, land-cover and land-use. The latter highlights the need for longer time-series and continued support for CZOs particularly in the humid tropics.     

Recuperated optically stimulated luminescence dating of middle-size quartz grains from the Palaeolithic site of Bonneval (Eure-et-Loir,France)

The site of Bonneval (France) exhibits a 6 m thick stratigraphical sequence in which Middle and Lower Palaeolithic artefacts were discovered. The stratigraphy of the site consists of an alternation of loess-like silt layers deposited along glacial stages, and paleosoil horizons corresponding to the vegetal stabilization of the area during interglacials. These layers hence provide past environmental informations and can be used as stratigraphical markers and compared with well dated sequences of Northern France. Eight sediment samples from this Middle and Upper Pleistocene sequence were dated using the recuperated optically stimulated luminescence (Re-OSL) signal of quartz grains. The middle-size fraction (40–63 μm) shows a good reproducibility of the OSL signals which allows the application of a multiple-aliquot additive-dose approach for D_e determination. For all samples, the growth curves are linear up to an accumulated dose of 3000 Gy. The Re-OSL ages range from ～100 to ～450 ka and are in good agreement with the independent chronological information; they establish when handaxe industries have been made during the Middle and Upper Pleistocene in the Paris Basin.     

Tracing and dating recent chemical transfers in weathering profiles by trace-element geochemistry and U---U---Th disequilibria: the example of the Kaya lateritic toposequence (Burkina-Faso)

The paper presents a synthesis of the approach recently developed to constrain the nature and the age of recent element mobility in weathering profiles. The approach relies on a comparison of variations of trace elements and U-series disequilibria in weathering profiles. It is exemplified in the case of old lateritic profiles from the Kaya toposequence, Burkina Faso. Trace elements and ²³⁸U---²³⁴U---²³⁰Th disequilibria have been analysed in whole rock samples from two pits located in very contrasted topographical positions. Trace element data show that the whole toposequence is marked by an intense chemical remobilization, including uranium, from the cap to the lower part of the profiles. ²³⁸U---²³⁴U---²³⁰Th disequilibrium data outline that all the levels of the profiles are affected by recent U---Th fractionations, and that each level of the toposequence is marked by U gains and losses. The chronological approach developed in this paper leads to an age of about 400 kyr for the dismantling of the iron cap, and ages ranging from 0 to 400 kyr for U accumulation in the pink clay horizon of the profiles. The depth repartition of U accumulation in the profile implies that the remobilisation processes in this toposequence varied through time, on time constants similar to those of climatic variations. To cite this article: F. Chabaux et al., C. R. Geoscience 335 (2003).     

Paleomagnetism and potassium-argon age of the Messejana dike (Portugal and Spain): angular limitation to the rotation of the Iberian Peninsula since the Middle Jurassic

A paleomagnetic and potassium-argon dating investigation has been carried out on a 530-km-long dike system which transects the western Iberian Peninsula in a northeasterly direction. The K-Ar age determinations were made on mineral separates exclusively. They range between 160 and 200 Ma and the authors suppose that this reflects the actual time interval of the intrusion, in accord with previous results. The paleomagnetic pole derived from 12 sites regularly distributed along the dike (71°N, 236°E) coincides well with other Mesozoic paleomagnetic poles from the western Africa. A contemporaneous pole from stable Europe is tentatively deduced from African and North American Late Triassic/Early Jurassic poles using different reconstruction models around the North Atlantic Ocean. The divergence between this pole and the Iberian pole corresponds to the result obtained for Permian poles.     

Indices de confinement dans les dépôts lacustres holocènes de Sarliève (Limagne,France)

The autochthonous magnesian carbonates and the gypsum depicted in the Holocene deposits from the ‘Marais de Sarliève’ (Limagne, France) result from an alkaline, magnesian and sulphated composition of waters. This is also recorded by the composition of algal micro- and macrophytes. This may be explained by the dissolved fluxes from the Oligocene catchment and from a restriction. During the historical period, the lake evolved towards a lesser restriction. To cite this article: J.-G. Bréhéret et al., C. R. Geoscience 335 (2003).     

Ecological transitions indicated by foraminiferal assemblages in paralic environments

The foraminiferal assemblages of about 1,500 samples collected worldwide in various types of paralic environments, supplemented by selected published data, led to the determination of several species assemblages typical of paralic subenvironments. These assemblages are shown on a series of models, giving a view of the response of foraminifera to a variety of gradients in different situations. Given the proposed models, it should be possible to go to a new environment, and based on the assemblage found, determine the average characteristics of the paralic subenvironment. Three main biotic trends are evident from oceanic to continental end members, and are related to marine-to-freshwater transition where freshwater input is sufficient or marine-to-hypersaline water in inverse estuaries; to marine-to-confined water transition in choked tropical and Mediterranean lagoons; and to water-to-land transition from shallow subtidal zones up to marshes in all kinds of environments. On the basis of these results, a ternary diagram is proposed, where paralic environments can be plotted according to their dominant characteristic.     

Chemical weathering in the drainage basin of a tropical watershed (Nsimi-Zoetele site, Cameroon) : comparison between organic-poor and organic-rich waters

This study deals with the weathering processes operating at the scale of a small catchment (Nsimi-Zoetele, Cameroon) and is focused on the role of organic colloids on mineral weathering and transport of elements in natural waters. Samples of river, spring and groundwaters from Nsimi-Zoetele were filtered through membranes of decreasing pore size (0.22 μm, 0.025 μm, or: 300,000 Da, 5000 Da) to separate colloidal fractions from the truly dissolved one. Major and trace elements and dissolved organic carbon (DOC) were analysed in each fraction. Two kinds of waters can be distinguished in the catchment: clear and coloured waters. Clear waters exhibit low concentrations of major and trace elements and DOC. Elements are carried in these solutions in a true dissolved form except Al and rare earth elements (REEs). By contrast, the higher abundances of Al, Fe and trace elements in coloured waters are controlled by the colloidal fraction. Thermodynamic equilibrium calculations show that clear waters are in equilibrium with kaolinite and iron oxi-hydroxide which are major minerals in the weathered soil. For coloured waters, the aqueous speciation of Ca, Mg, Cu, Fe, Al, La and Th was calculated taking into account the complexes with humic acids. Speciation calculations for Cu, Fe, Al, La, Th show a strong complexation with humic acids, in good agreement with the results of the filtration experiments. By contrast, although filtration experiments show a strong control of major cations by organic matter (for example 75% for Ca), speciation calculations reveal that their complexes with humic ligands do not exceed a few percent of total dissolved elements. This discrepancy is explained as an artefact induced by the organic colloids and occurring during the filtration procedure. Finally, both filtration experiments and speciation calculations show that organic matter plays an important role in natural DOC-rich waters. Organic acids increase significantly the dissolution rates of silicates and oxi-hydroxides and thus the amounts of solutes and of complexed elements leaving the catchment.     

Deccan flood basalts at the Cretaceous/Tertiary boundary?

Joint consideration of new paleomagnetic, paleontological and geochronological data from the Deccan continental flood basalts in India and critical discussion of earlier results lead us to suggest that volcanic activity may have lasted less than 1 Ma, thus possibly ranking as one of the largest volcanic catastrophes in the last 200 Ma. Available data are best satisfied if volcanism spanned the Cretaceous/Tertiary boundary, followed shortly afterwards by rifting of the Arabian Sea. These results point out the need for further work which may help in choosing between “external” and “internal” models of the Cretaceous/Tertiary boundary events.     

Long-period Love wave overtone data in North America and the Pacific Ocean: new evidence for upper mantle anisotropy

Two Tonga-trench earthquakes recorded in North America on WWSSN long-period instruments have been processed by making use of spatial analysis techniques to retrieve the phase velocities of Love wave modes. Dispersion data up to the third overtone at periods longer than 30 s have been obtained for two broad areas: the Pacific Ocean and North America. It is found that the observed Love wave phase velocities are not in agreement with the values predicted from the previously published models inferred from Rayleigh wave data. Phase velocity discrepancies as large as 3–4% in the Pacific Ocean and 2% in North America are observed up to the second overtone. Preliminary direct computations, which have been performed in the framework of transversely isotropic models with the axis of symmetry oriented vertically, suggest that the cause for this departure from isotropy probably extends to depths > 200 km.