The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset I: The Nyong River Basin,Cameroon

Simultaneously acquiring time series of climate, hydrology and hydrochemical data over decades on river systems is pivotal to understand the complex interactions involving rock, soil water, air and biota in the Critical Zone, to build integrated modelling and to propose predictive scenarios. Among the Critical Zone Observatories (CZOs) implemented in the past 25 years, only a few are located in the humid Tropics despite the importance of these regions in terms of population density, fast-changing land use, biodiversity hotspots, biomass stock on continents, size of river systems, etc. Since 1994, weathering and erosion processes and fluxes have been investigated at both local (experimental watershed) and regional scales in the Nyong River Basin (Cameroon) which belongs to the Critical Zone Observatories network named Multiscale TROPIcal CatchmentS (M-TROPICS). The data shared by M-TROPICS in Cameroon are: (1) rainfall; (2) air temperature, air relative humidity, wind speed and direction, and global radiation; (3) stream and river water level; (4) pH, electrical conductivity, water temperature and suspended particulate matter (SPM) concentration; (5) major ion, alkalinity and dissolved organic carbon (DOC) concentrations. The dataset already contributed to describe the water partitioning in these tropical humid watersheds, to better understand the factors controlling chemical weathering and physical erosion in tropical ecosystems, particularly the role of organic matter. The dataset also contributed to calculate elemental weathering fluxes and saprolite production rate and to propose denudation rates on tropical cratonic landscapes. Hydrological modelling allowed quantification of the geographical water sources contributing to streamflow. DOC data were used to determine greenhouse-gas emissions and carbon budgets from African inland waters. However, long-term solute concentrations at the outlet of a small tributary of the Nyong River exhibit non-stationary behaviour over the last 26 years. The processes governing those fluctuations are not yet fully understood and might be related to changes in the hydrological regime, land-cover and land-use. The latter highlights the need for longer time-series and continued support for CZOs particularly in the humid tropics.     

Crustal features of the northeastern South China Sea: insights from seismic and magnetic interpretations

We interpret seven two-dimensional deep-penetration and long-offset multi-channel seismic profiles in the northernmost South China Sea area, which were collected by R/V Marcus G. Langseth during the TAIwan GEodynamics Research (TAIGER) project in 2009. To constrain the crustal characteristics, magnetic inversion and forward magnetic modeling were also performed. The seismic results clearly show tilted faulting blocks in the upper crust and most of the fault plane connects downward to a quasi-horizontal detachment as its bottom in the south of the Luzon-Ryukyu transform plate boundary. North of the plate boundary, a small-scale failed rifted basin (minimum 5 km in crustal thickness) with negative magnetization probably indicates an extended continental origin. Significant lower crustal material (LCM) was imaged under a crustal fracture area which indicated a continent and ocean transition origin. The thickest LCM (up to 6.5 km) is located at magnetic isochron C15 that is probably caused by the magma supply composite of a Miocene syn-rift volcanic event and Pliocene Dongsha volcanic activity for submarine volcanoes and sills in the surrounding area. The LCM also caused Miocene crustal blocks to be uplifted reversely as 17 km crustal thickness especially in the area of magnetic isochron C15 and C16. In addition, the wide fault blocks and LCM co-existed on the magnetic striped area (i.e. C15–C17) in the south of the Luzon-Ryukyu transform plate boundary. Magnetic forward modeling suggests that the whole thick crustal thickness (>12 km thick) needs to be magnetized in striped way as oceanic crust. However, the result also shows that the misfit between observed and synthetic magnetic anomaly is about 40 nT, north of isochron C16. The interval velocity derived from pre-stack time migration suggests that the crust is composed of basaltic intrusive upper crust and lower crustal material. The crustal nature should refer to a transition between continent and ocean. Thus, the magnetic reversals may be produced in two possible ways: basaltic magma injected along the crustal weak zone across magnetic reversal epoch and because some undiscovered ancient piece of oceanic crust existed. The crustal structure discrimination still needs to be confirmed by future studies.     

Long-term multi-hazard assessment for El Misti volcano (Peru)

We propose a long-term probabilistic multi-hazard assessment for El Misti Volcano, a composite cone located <20 km from Arequipa. The second largest Peruvian city is a rapidly expanding economic centre and is classified by UNESCO as World Heritage. We apply the Bayesian Event Tree code for Volcanic Hazard (BET_VH) to produce probabilistic hazard maps for the predominant volcanic phenomena that may affect c.900,000 people living around the volcano. The methodology accounts for the natural variability displayed by volcanoes in their eruptive behaviour, such as different types/sizes of eruptions and possible vent locations. For this purpose, we treat probabilistically several model runs for some of the main hazardous phenomena (lahars, pyroclastic density currents (PDCs), tephra fall and ballistic ejecta) and data from past eruptions at El Misti (tephra fall, PDCs and lahars) and at other volcanoes (PDCs). The hazard maps, although neglecting possible interactions among phenomena or cascade effects, have been produced with a homogeneous method and refer to a common time window of 1 year. The probability maps reveal that only the north and east suburbs of Arequipa are exposed to all volcanic threats except for ballistic ejecta, which are limited to the uninhabited but touristic summit cone. The probability for pyroclastic density currents reaching recently expanding urban areas and the city along ravines is around 0.05 %/year, similar to the probability obtained for roof-critical tephra loading during the rainy season. Lahars represent by far the most probable threat (around 10 %/year) because at least four radial drainage channels can convey them approximately 20 km away from the volcano across the entire city area in heavy rain episodes, even without eruption. The Río Chili Valley represents the major concern to city safety owing to the probable cascading effect of combined threats: PDCs and rockslides, dammed lake break-outs and subsequent lahars or floods. Although this study does not intend to replace the current El Misti hazard map, the quantitative results of this probabilistic multi-hazard assessment can be incorporated into a multi-risk analysis, to support decision makers in any future improvement of the current hazard evaluation, such as further land-use planning and possible emergency management.     

A transmission electron microscopy (TEM) investigation of opaque phases in shocked chondrites

Abstract— Shock defects in the most common silicate minerals of chondrites (olivine, pyroxenes and feldspars) have been investigated in detail, but there have been almost no studies of the shock defects in other components, like metal and sulfide. This probably stems from the fact that these latter phases are opaque in the optical microscope. The same reason explains why veins and melt pockets, which are constituted of microcrystalline or glassy phases (i.e., isotropic) are also poorly documented. We have investigated such phases by analytical transmission electron microscopy (ATEM) in two shocked chondrites, Tenham (L6) and Gaines County (H5). We have characterized shock defects in troilite very similar to those occurring in silicates (i.e., a mosaic texture and sets of straight and very narrow, ?10 nm, lamellae of amorphized FeS). There are many small regions in shocked chondrites that are composed of very fine grained (?1 μm) mixtures of metal and sulfide or of various silicates. They must result from local melting followed by a rapid cooling that prevented grain growth. We have determined the chemical compositions and the volume proportions of the tiny grains in these veins and melt pockets, which has allowed their temperature and pressure (T, P) history to be partially deciphered. Finally, we have observed a dense network of very narrow fractures (down to 10 nm) in the olivine and enstatite grains. These fractures are systematically filled with an amorphous (or cryptocrystalline) material that stems from the melt pockets and was injected when the fractures were opened by the rarefaction wave. This material was then quenched at the contact with the colder crystalline rims.     

Internal structure of Piton de la Fournaise volcano from seismic wave propagation and earthquake distribution

Arrival times of seismic waves from local earthquakes are inverted for both locating the source and defining the 3-D velocity heterogeneity of Piton de la Fournaise.The lateral heterogeneity of the 2632 m high edifice is resolved as a high-velocity plug, 1.5 km in diameter, surrounded by a low-velocity ring, which may be interpreted as due to the construction of Fournaise on the flank of the older volcano Piton des Neiges. Wave mode conversion detected on three-component seismograms provides evidence for boundaries of contrasted velocities.Pre-eruptive swarm earthquakes cluster in the high-velocity zone, under the Dolomieu summit crater. Low strength and cohesion of the surrounding material account for the lack of seismicity for the final 1–3 km radial flow of magma to the vents in Enclos Fouqué.Beneath the high-velocity plug the existence of a body with low velocity for P, and even for S, waves is well constrained. However, the walls and base are poorly defined because of the lack of deep earthquakes for sampling. The few earthquakes that are located in this depth region usually occur at a depth of around 1.5 km below sea level in the region of the cone. This can be considered providing the upper constraint on the lower limit of the aseismic part of the low-velocity body. The coincidence in time of their occurrence with the swarms above sea level and the eruptions suggests magmatic activation of the low-velocity aseismic volume 1.5 km below sea level under the high-velocity plug of the cone. Further down, the concentration of seismicity in two swarms, between 2 and 4 km, under the eastern flank does not allow the structure to be sampled effectively.     

Effects of granulometric and mineralogical composition on spectral reflectance of soils in a Sahelian area

During the Hapex-Sahel international investigation, portable radiometers (Barringer and Cimel) were used to study, in the optical domain, the relationship between soil mineralogical and granulometric compositions and radiometric indices: redness index, colour index and texture index. The results show that the granulometric distribution and the mineralogical composition have both important influence on these indices.In this Sahelian area, for soils having more than 1% of hematite, the redness index presents a high correlation with hematite content. For soils with less than 1% of hematite, the redness index depends on the size of the particles and their distribution at the surface.For eolian sandy and ferricrust soils, the colour and texture indices present good correlations, respectively, with iron oxide and kaolinite content. No such correlation is observed for ferruginous soils because of the complex interactions existing between iron oxides, kaolinite and the size of particles.     

Tracing and dating recent chemical transfers in weathering profiles by trace-element geochemistry and U---U---Th disequilibria: the example of the Kaya lateritic toposequence (Burkina-Faso)

The paper presents a synthesis of the approach recently developed to constrain the nature and the age of recent element mobility in weathering profiles. The approach relies on a comparison of variations of trace elements and U-series disequilibria in weathering profiles. It is exemplified in the case of old lateritic profiles from the Kaya toposequence, Burkina Faso. Trace elements and ²³⁸U---²³⁴U---²³⁰Th disequilibria have been analysed in whole rock samples from two pits located in very contrasted topographical positions. Trace element data show that the whole toposequence is marked by an intense chemical remobilization, including uranium, from the cap to the lower part of the profiles. ²³⁸U---²³⁴U---²³⁰Th disequilibrium data outline that all the levels of the profiles are affected by recent U---Th fractionations, and that each level of the toposequence is marked by U gains and losses. The chronological approach developed in this paper leads to an age of about 400 kyr for the dismantling of the iron cap, and ages ranging from 0 to 400 kyr for U accumulation in the pink clay horizon of the profiles. The depth repartition of U accumulation in the profile implies that the remobilisation processes in this toposequence varied through time, on time constants similar to those of climatic variations. To cite this article: F. Chabaux et al., C. R. Geoscience 335 (2003).     

Evidence for recent warming from perturbed geothermal gradients: examples from eastern Canada

Recent variations of the surface temperature of the Earth can be inferred from borehole temperature measurements. Generalized inversion is used to extract the information from the data; the potential of the method is evaluated. Tests were performed with synthetic data to demonstrate the effectiveness of the inversion to recover the gross features of the surface temperature history even when the data are affected by noise and errors. The tests show that it is possible to reconstruct the long term changes in ground temperature during the past 300 years; the resolution decreases with time, in particular if noise and errors must be filtered. Temperature logs, obtained in eastern Canada, and not suspected of being affected by non-climatic factors, have been inverted. The analysis confirms that eastern Canada has experienced warming by 1 to 2°C over the past 100–200 years. The relationship between air and ground temperatures has been examined. In eastern Canada ground temperature follows air temperature closely in summer but stays well above air temperature in winter. The number of days with snow on the ground correlates with the difference between annual mean ground and air temperature.Contribution to Clima Locarno — Past and Present Climate Dynamics; Conference September 1990, Swiss Academy of Sciences — National Climate-Program