Mineralogy and geochemical behaviour during weathering of greenstone belt under tropical dry conditions in the extreme North Cameroon (Central Africa)

Mineralogy, major, trace and rare earth elements of a weathering profile developed on tertiary greenstone belt in the extreme North Cameroon are reported. The aim of which was to investigate mineralogical evolution and element mobilization and redistribution during weathering under dry tropical climate. The weathering profile consists of four main horizons: (1) a spheroidal weathering zone constituted by a corestone–shell complex, (2) a C horizon, (3) a Bw horizon and an Ah horizon. The results indicate that nontronite, a Fe-rich smectite, is the exclusive clay mineral formed in the exfoliated shells and the C horizon. It is associated with kaolinite in the upper horizons. The coexistence of these two clay minerals induced a decrease of CEC and pH which becomes neutral. The weathering index (WI) values reveal that weathering becomes more and more intensive from the corestone up to Bw horizon, which is the most weathered horizon in the weathering profile. Mass balance calculations, using Th as immobile element, indicate that Ti is quite mobile and that Al and Fe are relatively enriched at the bottom and strongly leached at the top of the profile. Alkalis and alkaline earth elements are strong leached through out the profile, except Ca which displays similar trend as Al and Fe. The same goes for LILE (Cs, Sr), TTE (Cr, Co, Ni) and HSFE (Y, Nb, Hf). In opposite, REE are depleted at the bottom and enriched in the upper horizons, with more enrichment for LREE than for HREE. It appears that weathering of greenstone belt causes a fractionation of HREE and induces a concentration of LREEs. Ce and Eu anomalies display opposite behaviour.     

The challenge of dating early pleistocene fossil teeth by the combined uranium series–electron spin resonance method: the Venta Micena palaeontological site (Orce,Spain)

The palaeontological site of Venta Micena (Orce, Andalusia, Spain) lies in the eastern sector of the Guadix–Baza basin, one of the best documented areas in Europe for Plio‐Pleistocene biostratigraphy. The combination of biochronological and palaeomagnetic results, combined with the radiometric data obtained for Atapuerca Sima del Elefante, indicated that the Venta Micena stratum was formed between the Jaramillo and Olduvai palaeomagnetic events, most likely between 1.22 and 1.77 Ma. Five fossil teeth from two outcrops (sites A and B) were selected to assess the potential of combined uranium series–electron spin resonance (US‐ESR) dating of Early Pleistocene sites. Although the US‐ESR results of the first outcrop showed a large scatter between the three teeth, the mean age of 1.37 ± 0.24 Ma can be considered a reasonable age estimate for Venta Micena. The mean ESR age of 0.62 ± 0.03 Ma obtained for site B seems to be a severe underestimation when compared with the independent age control. This underestimation is attributed to a relative recent U‐mobilization event that led to some U‐leaching. The results show that any ESR age calculations of old samples are extremely sensitive to variations in the measured ²³⁰Th/²³⁴U ratios in dental tissues. Although the results demonstrate that ESR can in principle be applied to Early Pleistocene sites, they also reveal the complexity of dating such old teeth. It is necessary to continue research in several directions, such as study of the behaviour of ESR signals in old teeth and understanding recent U‐mobilization processes, to improve the reliability of the combined US‐ESR dating method applied to Early Pleistocene times, a period for which the number of available numerical dating techniques is very limited. Copyright © 2011 John Wiley & Sons, Ltd.     

Time‐scale analysis in unsaturated porous media under external wave loads

Extreme waves caused by tsunamis and storm surges can lead to soil failures in the near‐shore region, which may have severe impact on coastal environments and communities. Multiphase flows in deformable porous media involve several coupled processes and multiple time scales, which are challenging for numerical simulations. The objective of this study is to investigate the roles of the various processes and their interactions in multiphase flows in unsaturated soils under external wave loading, via theoretical time‐scale analysis and numerical simulations. A coupled geomechanics–multiphase flow model based on conservation laws is used. Theoretical analysis based on coupled and decoupled models demonstrates that transient and steady‐state responses are governed by pore pressure diffusion and saturation front propagation, respectively, and that the two processes are essentially decoupled. Numerical simulations suggest that the compressibility of the pore fluids and the deformation of the soil skeleton are important when the transient responses of the media are of concern, while the steady‐state responses are not sensitive to these factors. The responses obtained from the fully coupled numerical simulations are explained by a simplified time‐scale analysis based on coupled and decoupled models. Copyright © 2010 John Wiley & Sons, Ltd.     

Preliminary spectral characterization of snow in a high altitude tropical glacier and potential effects of impurities in snow on albedo of tropical glaciers

This paper presents some preliminary measurements of snow spectral reflectance on the tropical Bolivian Zongo glacier. Measurements show a correct agreement with theoretical spectral albedo of pure snow in the near infrared region, but lower values in the visible region (by 10–20%) probably due to aerosols contained in snow. Impurity contents ranged from 10 to 100 ppmw in one‐week‐old snow collected from the Zongo glacier, but measurements are scarce. Large amounts of snowfall partly compensate the proximity of dust sources in mid‐latitude glaciers, whereas on outer‐tropical glaciers precipitations are not abundant and are very seasonal, and sources of aerosols are proximate. Copyright © 2007 John Wiley & Sons, Ltd.     

Thermochronological evidence for Mio‐Pliocene late orogenic extension in the north‐eastern Albanides (Albania)

New apatite and zircon (U–Th)/He and apatite fission‐track (FT) data allow constraining the timing of Miocene–Pliocene extensional exhumation that affected the central part of the Dinarides‐Albanides‐Hellenides orogen. Apatite (U–Th)/He ages in the northern and western Internal Albanides range from 57 to 17 Ma, contrasting to younger ages of 5.2–9.3 Ma in the eastern Internal Albanides. Eastward younging is also reflected in zircon (U–Th)/He ages varying from 101 Ma in the north‐western Internal Albanides to 19–50 Ma in the east, as well as in recently published apatite FT ages. Thermal history predictions with the new data point to a phase of rapid exhumation of the eastern Internal Albanides around 6–4 Ma, while the western Internal Albanides record slower continuous exhumation since the Eocene. This asymmetric exhumation pattern is most likely linked to extensional reactivation of NE–SW‐trending thrusts east of the Mirdita zone and within the Korabi zone of the eastern Internal Albanides.     

Hubble Space Telescope photometry of globular clusters in the Sombrero galaxy

We explore the rich globular cluster (GC) system of the nearby Sa galaxy M104, the 'Sombrero' (NGC 4594), using archive Wide Field Planetary Camera 2 data. The GC colour distribution is found to be bimodal at the >99 per cent confidence level, with peaks at     and     . The inferred metallicities are very similar to those of GCs in our Galaxy and M31. However, the Sombrero reveals a much enhanced number of red (metal-rich) GCs compared to other well-studied spirals. Because the Sombrero is dominated by a huge bulge and only has a modest disc, we associate the two subpopulations with the halo and bulge components, respectively. Thus our analysis supports the view that the metal-rich GCs in spirals are associated with the bulge rather than with the disc. The Sombrero GCs have typical effective (half-light) radii of ∼2 pc with the red ones being ∼30 per cent smaller than the blue ones. We identify many similarities between the GC system of the Sombrero and those of both late-type spirals and early-type galaxies. Thus both the GC system and the Hubble type of the Sombrero galaxy appear to be intermediate in their nature.     

AGB Phase Transition in Globular Clusters: A Tool for Dating Starbursts

A new method to detect and study young star clusters is presented. This is based on the knowledge that the light of stellar populations with ages between ∼ 200 Myr and ∼ 1/2 Gyr is dominated by very red, bright AGB stars. Star clusters undergoing this so-called ‘AGB phase transition’ are featured by very red V-K colours, like those of Magellanic Clouds clusters, while optical colours like B-V remain blue typical for young populations. The best channel for detecting star clusters in this age range is therefore the near IR. From the theoretical side, SSP models including properly the contribution of the bright AGB are required (Maraston, 1998). Using this strategy, we succesfully detected the AGB phase transition among the clusters of the merger remnant galaxy NGC 7252 (see Maraston etal., 2001). This revised version was published online in September 2006 with corrections to the Cover Date.     

Biodegradation and transport of benzene,toluene, and xylenes in a simulated aquifer: comparison of modelled and experimental results

Both laboratory experiments and numerical modelling were conducted to study the biodegradation and transport of benzene–toluene–xylenes (BTX) in a simulated semi‐confined aquifer. The factors incorporated into the numerical model include advection, hydrodynamic dispersion, adsorption, and biodegradation. The various physico‐chemical parameters required by the numerical model were measured experimentally. In the experimental portion of the study, BTX compounds were introduced into the aquifer sand. After the contaminants had been transported through the system, BTX concentrations were measured at 12 equally spaced wells. Subsequently, microorganisms obtained from the activated sludge of a sewage treatment plant and cultured in BTX mixtures were introduced into the aquifer through the 12 sampling wells. The distribution data for BTX adsorption by the aquifer sand form a nonlinear isotherm. The degree of adsorption by the sand varies, depending on the composition of the solute. The degradation time, measured from the time since the bacteria were added to the aquifer until a specific contaminant was no longer detectable, was 35–42 h for BTX. The dissolved oxygen, after degradation by BTX compounds and bacteria, was consumed by about 40–60% in the entire simulated aquifer; thus the aerobic conditions were maintained. This study provides insights for the biodegradation and transport of BTX in aquifers by numerical modelling and laboratory experiments. Experimental and numerical comparisons indicate that the results by Monod degradation kinetics are more accurate than those by the first‐order degradation kinetics. Copyright © 2002 John Wiley & Sons, Ltd.     

Synrift to syntransform deformation along the Côte d’Ivoire–Ghana transform margin: evidence from deep-sea dives

Fourteen deep dives were conducted along the southern slope of the Côte d’Ivoire–Ghana marginal ridge. Detrital rock samples reveal Early Cretaceous synrift sediments. In situ observations and microtectonic analysis identify the nature and the timing of three successive episodes of deformation. Clay layers are affected by early diagenetic deformational structures such as slump microfolds and normal microfaults. Most of the clastic deposits display a second deformational episode. These structures result from a layer-parallel extension and are related to extensional synrift tectonics. The last stage of deformation is identified by right lateral wrench folds associated with brittle joints and slaty cleavage. It is attributed to the syntransform evolution of the Côte d’Ivoire–Ghana marginal ridge.