Uptake of macroelements by the helophytePhalaris arundinacea L.

Helophytes are often incorporated into biological wastewater treatment plants. In favourable situations, they can take up large amounts of nutrients. One helophyte, the reed canarygrass (Phalaris arundinacea L.), is fast growing when supplied with sufficient light and nutrients. Experiments were carried out under natural climatic conditions in small plastic tanks filled with sand with regular additions of a balanced and concentrated nutrient solution. In the growing season (May–October), plant production reached 10.5 kg m^–2 of dry biomass, of which 66% was in the aerial parts. Maximum nutrient uptake capacity was reached just after flowering and before senescence (beginning of October): 49% N, 34% P, 52% K and 34% Mg of the input was fixed in the aerial parts, which are easily harvestable. The corresponding values for the below ground parts were 12%, 10%, 11% and 11% respectively. Excretion of K and Mg has been observed when nutrients are translocated to the storage organs.     

Depositional mechanics of turbulent nuées ardentes (surges) from their grain sizes

The ability of turbulent nuées ardentes (surges) to transport coarse pyroclasts has been questioned on the basis that settling velocities of coarse fragments in the deposits are much too high for them to have been supported by turbulence in a dilute gas suspension. A computer model is used to evaluate the settling velocity of pyroclasts in suspensions of varying concentration and temperature. Since suspension of grains in low-concentration surges occurs if the shear velocity exceeds the settling velocity, the shear velocities related to the 16th and 84th percentiles, and the mean of the grain-size distribution are compared in surge deposits of the Vulsini, with the shear velocity necessary to move the coarsest grain on the bed surface (the Shields criterion). The results show that the settling velocities do not vary significantly in gaseous suspensions having volume concentrations lower than 15%, and that an increase in concentration to 25% is not sufficient to decrease the settling velocity of the coarser fraction, if it represents flow shear velocity. It is shown that the settling velocity of the mean grain size (M _z ) best depicts the shear velocity of a dilute turbulent suspension. Applying the results to the May 1902 paroxysmal nuées ardentes of Mount Pelée shows that the estimated mean velocities are well within the observed velocities, and sufficient to support all the clasts in dilute, turbulent suspensions.     

Carboxylic monoacids in the air of mayombe forest (Congo): Role of the forest as a source or sink

In the tropical rain forests of the Congo during the dry season, from June to September 1987, carboxylic acid partial pressures (P _gas) in the air above the canopy, at ground level, and at the boundary layer, were estimated from water samples such as fog and rainwater. The concentrations of these acids were also measured in the sap of tree leaves. Tree leaves act as a sink or as a source if the acid P _gas is greater of lower than the acid concentrations in molecular form in sap. For each of these soluble gases, there is a value of P _gas where the exchange is nul. This is called the compensation point. Values of the compensation point for some tree leaves were evaluated according to Henry's law. Henry's law coefficients at ppm levels were redetermined for formic (HCOOH), acetic (CH₃COOH), propionic (CH₃CH₂COOH), and isobutyric (CH₃CH(CH₃)COOH) acids.By comparison of P _gas and compensation points, it is concluded that the forest was a potential source for these acids. The soil-or the litter-acts as a significant source of a carboxylic acid of C₃ or C₄ atoms in the aliphatic chain. This carboxylic acid, not yet fully characterized, could play an important role in the rain acidity in forested zones of the equatorial areas.The direct emission of these carboxylic acids by vegetation was the main source in the boundary layer above the forest. The average emissions were 3.1×10⁹, 7.8×10⁹, and 8.4×10⁹ molecules cm^-2 s^-1 for HCOOH, CH₃COOH, and CH₃CH₂COOH, respectively. The savanna is an exogenous source of HCOOH and CH₃CH₂COOH during moderately rainy days for 30% of the time. The ozonolysis of isoprene seems to be a small source of HCOOH.     

The African rain forest vegetation and palaeoenvironments during late quaternary

This review paper presents first the main pollen results on the vegetation history of the rain forest during the late Quaternary.- The Lake Bosumtwi record (Ghana) shows the disappearance of rain forest from the base of the core (ca. 28 000 yr BP) to ca. 9000 yr BP. During this time interval the vegetation was of montane type with sparse clumps of trees. There is synchronism between montane vegetation disappearance and rain forest reappearance. This phenomenon occurred abruptly around 9000 yr BP.- The Lake Barombi Mbo record (West Cameroon) shows clearly that from ca. 24 000 yr BP until the present time, rain forest persisted with limited variations, and thus, this area represents a refuge area.From these data and other, one concludes that Afromontane vegetation extended to lowland during cool and humid phases.Other palaeoenvironmental data were obtained by diverse geological analyses of the lacustrine sediments. For Bosumtwi, the relatively precise reconstruction of lake-level fluctuations permitted several palaeoclimatic interpretations for the main Holocene phases.For Barombi Mbo, the evolution of total organic carbon (TOC) and total nitrogen (TON) seems to be related mainly to temperature evolution. By comparison with present-day mountain environments, TOC and TON increase in cool environments, but decrease when warmth and humidity increase, as during Holocene time, because the recycling processes speed up in the topsoil. For the same period the alteration of the soils in the catchment produced a strong increase of kaolinite. All these change intervened ca. 9500 yr BP, which is a key date in tropical Africa.In conclusion, climatic correlations between equatorial and dry north tropical Africa illustrate how changes in the forest block must have important effects on adjacent climatic zones.     

Intercrystalline cation partitioning between minerals of the triplite-zwieselite-magniotriplite and the triphylite-lithiophilite series in granitic pegmatites

Minerals of the triphylite-lithiophilite, Li(Fe, Mn)PO₄, and the triplite-zwieselite-magniotriplite series, (Mn, Fe, Mg)₂PO₄F, occur in the late stage period of pegmatite evolution. Unfortunately, neither are the genetic relationships between these phosphates fully understood nor are thermodynamic data known. Consequently, phosphate associations and assemblages from 8 granitic pegmatites — Clementine II, Rubicon II and III, and Tsaobismund (Namibia); Hagendorf-Süd and Rabenstein (Germany); Valmy (France); Viitaniemi (Finland) — have been tested for compositional zoning and intercrystalline partitioning of main elements by electron microprobe techniques. Although the selected pegmatites display varying degrees of fractionation, and the intergrowth textures indicate different genetic relationships between the phosphates, the plots of mole fractions X _Fe=Fe/(Fe+Mn+Mg+Ca), X _Mn=Mn/(Fe+Mn+Mg+Ca), and X _Mg=Mg/(Fe+Mn+Mg+Ca) can be fitted relatively well with smooth curves in Roozeboom diagrams. Their deviations from symmetrical distribution curves are mainly dependent upon X _Mg or X _Ca, and upon non-ideal solutions. Surprisingly small differences between the partition coefficients were detected for intergrowths of different origin. However, the partitioning of shared components among coexisting phases is clearly dependent upon the conditions of formation. Compositional zoning is observed only when both Fe–Mn phosphates are intergrown mutually or with other Fe–Mn–Mg mineral solid-solutios. Thus, the zoning does not seem to be due to continuous crystallization, but to later diffusion processes. The triplite structure has preference for Mn, Mg, and Ca, while Fe prefers minerals of the triphylite series. A quantification of main element fractionation between minerals of the triphylite and the triplite series is possible in the cases where diffusion can be excluded. For the Fe/(Fe+Mn) ratios of core compositions an equation with a high correlation coefficient (R=0.988) was determined: Fe/(Fe+Mn)_Tr=[Fe/(Fe+Mn)_Li]/{2.737-(1.737)[Fe/(Fe+Mn)_Li]} (Tr=triplite series, Li=triphylite series). Consequently, the Fe/(Fe+Mn) ratio of the triplite series can now also be used in the interpretation of pegmatite evolution, just like that of the triphylite series which has been successfully applied in the past.     

Volcanic hazards in the surroundings of Pico de Orizaba,eastern Mexico

Volcanic hazards from Pico de Orizaba volcano are presented here tor the first time. Some 1.3 million people live within the hazard zone, which in the most severe case would encompass the Mexican Gulf coast, east of the volcano. Three major cities located in the eastern part of the hazard zone account for 800 000 of this population and about 200 000 people live within a 20 km radius of the volcano. Probability calculations are presented as an attempt to quantify the hazards in the surroundings of the volcano. Such quantification can be of use in planning for future land use within the hazard zones.A zone of about 10 km radius centred on the top crater is a high hazard zone for gravity-driven flows and fallout ejecta. For large volume eruptions, the radius could be extended to 120 km to the east and 60 km to the west. The asymmetrical distribution is related to the topography of the volcano. Hazards from Pyroclastic-fall deposits are principally to the west of the volcano, since easterly winds are dominant in the area lava-flow hazards are greatest within a 10 km radius from the summit crater. Pyroclastic flow hazards are high up to 20 km from the volcano summit.In the case of reactivation of the volcano, melting of a glacier covering the summit of Pico de Orizaba having a volume equivalent to some 45 × 10⁹ litres of water, would produce lahars which would descend the flanks of the volcano.