Microtremor Analyses at Teide Volcano (Canary Islands,Spain): Assessment of Natural Frequencies of Vibration Using Time-dependent Horizontal-to-vertical Spectral Ratios

We use time-dependent horizontal-to-vertical spectral ratios (HVSR) of microtremors to determine the dominant frequencies of vibration of the geological structures beneath several recording sites in the vicinity of Teide volcano (Canary Islands, Spain). In the microtremors, the time-dependent HVSRs (ratiograms) are a useful tool to discriminate between the presence of real dominant frequencies linked to resonances of the subsurface structure and the spurious appearance of peaks due to local transients. We verified that the results are repeatable, in the sense that microtremors recorded at the same site but at different times yield a very similar HVSR function. Two types of results are found: (1) sites where there is no resonance of the propagating microtremors, and therefore no value of a dominant frequency can be assessed; and (2) sites where a stationary peak in the HVSR is found and a dominant frequency related to resonance of the shallow structure can be estimated. These resonant frequencies show substantial spatial variations even for nearby sites, which reflects the complexity of the shallow velocity structure in the Las Cañadas area. Large dominant frequencies occur near the caldera walls and also at a few locations that coincide with the intersections of the inferred rims of the three calderas forming Las Cañadas. Small dominant frequencies also occur near the caldera rim, and may be due to discontinuities in the caldera wall and/or to local velocity anomalies. Intermediate frequencies are mostly found in the eastern part of the caldera, where a tentative profile of the basement depth has been obtained. Intermediate frequencies have also been measured south of Ucanca and south of Montaña Blanca. In view of the present results, we conclude that the use of ratiograms constitutes an improvement of the HVSR method and provides an appropriate tool to investigate the shallow velocity structure of a volcanic region.     

Holocene environmental change on the Atlantic coast of NW Iberia as inferred from the Ponzos wetland sequence

The intertidal environment of the Ponzos beach (NW Iberian Peninsula) hosts a sedimentary sequence (including large wood fragments) deposited during the first half of the Holocene in a hygrophilous continental wetland. Pollen and macrofossil data alongside radiocarbon dating allow reconstruction of the changes that occurred during the Early and Middle Holocene in the landscape of the NW Iberia coastal lowlands, as well as the local wetland plant communities, in response to the climate variations and the eustatic sea-level oscillations. The sequence represents the evolution of a coastal wetland from its initial phases as a hygrophilous wetland towards the subsequent installation of a freshwater lagoon. Pollen data show the dominant role of Atlantic (mainly deciduous) woody taxa, the scarcity of conifers and the lack of Mediterranean elements in the coastal landscapes around the Ponzos site. The presence and abundance of some taxa such as deciduous Quercus, Castanea, Fagus, Tilia and Ulmus during the Early Holocene provides further support for the occurrence of glacial refuges in the Cantabrian-Atlantic area during the Last Glaciation. The diverse vegetation that characterizes the modern landscapes in this territory established later, spreading from these glacial reservoirs of biodiversity. In this sense, the notable and early presence of Fagus at the beginning of the Holocene, a tree also previously recorded during several phases of the Last Glacial Cycle on the NW Iberia coasts, is noteworthy. In addition, during the Early and Middle Holocene are recorded other trees that are currently extirpated as natural taxa in the area, such as Pinus, Tilia and Carpinus.     

Geochemical modeling and low-frequency geoelectrical methods to evaluate the impact of an open dump in arid and deltaic environments

In Mexico, open dumps that are maintained by the municipality but provide no covering of waste are not uncommon. Further, disposal at these sites is often performed by burning. The aim of this study was to determine the leachate plume from an open dump located in a depositional deltaic environment, with arid climate, low rainfall and where the water table is about 2 m below the surface. The methodology comprised analysis of groundwater monitoring wells and geophysical and geochemical prospecting techniques. The 3D geoelectric interpretation shows a typical area of these depositional environments with low resistive values (10–20 Ω-m) associated with the presence of sands and clays interbedded. However, there is a very low resistivity zone associated with the dump’s impact which reaches values below 5 Ω-m, and it is located where the disposal and burning of wastes occurred. Another zone with values above 16 Ω-m appears as a limit for the advance of the saline. This is interpreted as a sandy lenses area. These sandy lenses with higher porosity transport aquifer’s water. Thus the dump is in direct contact by this conduct with clean groundwater. Piper diagrams constructed with the chemical data analysis reveal that the groundwater in the area corresponds to the chlorinated and/or sulfated sodium type, showing the impact caused by the dump. The monitoring well (NP8, on-site) with the highest dissolved solids content behaves anomalously and belongs to the more conductive zone according to the geoelectric profiles. The subsoil geochemical behavior is influenced by the seasonal water table variations provoking the dissolution of burned and unburned wastes, but the effects of slow flows in the direction of the regional flow are not discarded. Although the most impacted area within the dump is characterized to a depth of 10 m, there is a slow flow in the direction of the regional flow that has been moving pollutants out of the dumpsite during its almost 20 years of operation. The results of this study provide valuable information for the authorities to carry out an appropriate restoration project.     

The impact of spatial elements on the forecasting of Spanish labour series

In this paper, we analyse the ability of a dynamic spatial panel data model without explanatory variables to explain a variable of interest, in this case employment in the fifty Spanish provinces. The best model is a dynamic fixed effect with a spatial lag structure in an equation estimated through the unconditional ML procedure. Predictions derived from this selected model are compared with those derived from fifty seasonal ARIMA models that also treat outlier observations. The results indicate that forecasts derived from a single estimated spatial panel data model are as accurate as those derived from the estimation of fifty seasonal ARIMA models. This shows that spatial panel data models play an important role in forecasting.     

Metalliferous sediments from the H.M.S. Challenger voyage (1872-1876)

The legendary cruise of H.M.S. Challenger (1872-1876) around the globe must always occupy an eminent place in the annals of oceanography, as being the first systematic attempt made on a global scale to explore the ocean. This expedition made fundamental discoveries in biology and geology which have not been surpassed by any later scientific cruise. Sediment with high content of metals (later called “metalliferous”) was among the enigmatic findings taken onboard. Although the nature of metalliferous sediments is well known today, the very first sampled sediments of this type have not been studied to date. Motivated by the historical value of Challenger’s metalliferous sediment collection we undertook an investigation addressing two questions: (1) the composition of sediments from seafloor for which we have very limited data; (2) Sr-Nd-Pb-Fe-Zn-isotope signature of these sediments collected before the substantial human impact on the ocean during the 20th century.The SE Pacific metalliferous sediments sampled by the Challenger’s explorers are of 2 types: (1) metalliferous oozes blanketing ridge crests and flanks down to the calcite compensation depth (CCD); and (2) stripped of CaCO₃ metalliferous sediments located beneath the CCD in the deeps near the mid-ocean ridges. The abiogenic part of these sediments is composed mainly of poorly-crystalline to X-ray amorphous Fe-Mn-oxyhydroxides, and an amorphous silicate phase. These sediments have geochemical features similar to those of all the other metalliferous sediments: very high Fe and Mn content (on abiogenic basis), very low Al/(Al + Fe + Mn), and high content (on abiogenic basis) of As, Ba, Be, Bi, Cd, Co, Cu, Mo, Ni, Pb, Sb, Th, Tl, U, V, W, Y, Zn and Zr. Their REE distribution patterns are similar to that of deep seawater and show weak signs of hydrothermal imprint (weak positive or no Eu anomaly).Seawater and/or terrigenous input from South America control the Sr-Nd-Pb-isotope signature of the Challenger metalliferous sediments and have almost completely obliterated any original MORB-derived hydrothermal signal. Zn isotopes are mainly contributed from seawater although other Zn sources (hydrothermal fluid and detrital aluminosilicates, barite and volcanic glass) are necessary to fully explain Zn-isotope ratios. Fe isotopes indicate relatively slow Fe²⁺ to Fe³⁺ oxidation in the non-buoyant plume, thus producing relatively lighter Fe-isotope signature of the FeOOH particles that formed the studied metalliferous sediments.     

Phytoplankton pigments and epifluorescence microscopy as tools for ecological status assessment in coastal and estuarine waters, within the Water Framework Directive

Inverted microscopy is widespread employed for the analysis of phytoplankton composition within water quality monitoring networks. However, the analysis at the lowest taxonomical level is not always required for ecological status assessment. In addition, inverted microscopy can underestimate the small phytoplankton, and not always distinguish photoautotrophic from heterotrophic cells. In this study, as alternative tools, epifluorescence microscopy and High Performance Liquid Chromatography (HPLC) were employed to characterize phytoplankton communities within waters of different trophic condition. Epifluorescence microscopy confirmed its effectiveness to count the small phytoplankton. Furthermore, significant correlations between nutrients of anthropogenic origin and nanoplankton abundances were found. However, this technique resulted very time-consuming. HPLC together with the CHEMTAX program was more appropriate than inverted microscopy, in terms of cost-effectiveness. Also, the main variability patterns observed in the phytoplankton community structure by HPLC coincided with previous findings in the study area. Nevertheless, a rapid screening at the inverted microscope is recommended.     

Error determination in the photogrammetric assessment of shoreline changes

The evaluation of error or uncertainty in shoreline change studies is an issue of prime importance for providing an adequate framework for calculated rates of change and to allow the establishment of threshold values above which the rates would be significant. In this note, a practical, easy-to-use method is presented to estimate error involved in the calculation of shoreline changes on aerial photographs, including the three most used types of shoreline indicators: high water line, dune/cliff toe and cliff top. This approach takes into account the specific characteristics of each shoreline proxy, such as relief in the case of the cliff top or tidal oscillations in the case of the high water line. At the same time it includes the error components that are independent from the proxy, basically related to the technical aspects of the process such as photo scanning and georeferencing. A practical example of application of the method is provided for several types of data inputs, based on shoreline changes around the Bay of Cádiz (SW Spain).