Correlation between molecular absorption spectral slope ratios and fluorescence humification indices in characterizing CDOM

Ultraviolet–visible absorption spectral slope ratios S_R (slope in 275–295 nm divided by slope in 350–400 nm) and humification index (HIX, integrated fluorescence emission in 435–480 nm divided by that in 435–480 and 300–345 nm) were compared when characterizing chromophoric dissolved organic matter (CDOM) in three humic acids and 44 whole water samples. HIX increased with increasing pH for humic acids, while their S_R showed much more complicated dependencies on pH. There was a negative correlation between S_R and HIX. S_R increased in the order terrestrial coal/peat < terrestrial soil/river < seawater, while HIX increased in the order seawater < terrestrial soil/river < terrestrial coal/peat. The comparative study in this work indicates that terrestrially derived CDOM has higher HIX and lower S_R than marine CDOM. Investigators may potentially use these two indices to compare qualitatively the character of CDOM in different sources (e.g., terrestrial vs. marine).     

Effects of long-term medieval agriculture on soil properties: A case study from the Kislovodsk basin,Northern Caucasus,Russia

The chemical properties and biological activities of soils were studied in the vicinity of the medieval settlement Podkumskoe-3 in the Kislovodsk basin (Northern Caucasus, Russia). Between the 5th and 8th centuries this area was ploughed regularly, but it was then abandoned up to the present day. It has been established that past human activity leads to soil undergoing significant transformations in terms of microbial communities and enzyme activity, and that such changes are maintained over long periods. Long-term manuring in the middle of the first millennium AD led to an increase in organic carbon content and the accumulation of nitrate nitrogen. Soils of ancient abandoned fields are associated with increases in microbial biomass, number of saprotrophic bacteria, urease activity, and fungal mycelium biomass. The observed changes in the microbiological and biochemical properties of soil were conditioned by secondary anthropogenically induced succession after the abandonment of arable lands.     

Control strategies and experimental verifications of the electromagnetic mass damper system for structural vibration control

The electromagnetic mass damper （EMD） control system, as an innovative active control system to reduce structural vibration, offers many advantages over traditional active mass driver/damper （AMD） control systems. In this paper, studies of several EMD control strategies and bench-scale shaking table tests of a two-story model structure are described. First, two structural models corresponding to uncontrolled and Zeroed cases are developed, and parameters of these models are validated through sinusoidal sweep tests to provide a basis for establishing an accurate mathematical model for further studies. Then, a simplified control strategy for the EMD system based on the pole assignment control algorithm is proposed. Moreover, ideal pole locations are derived and validated through a series of shaking table tests. Finally, three benchmark earthquake ground motions and sinusoidal sweep waves are imposed onto the structure to investigate the effectiveness and feasibility of using this type of innovative active control system for structural vibration control. In addition, the robustness of the EMD system is examined. The test results show that the EMD system is an effective and robust system for the control of structural vibrations.     

Corrosion behavior of anodic oxidized TiO<Subscript>2</Subscript> film in seawater

TiO₂ films were formed on metallic titanium substrates by the anodic oxidation method in H₂SO₄ solution under the 80V D.C.. Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions. Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves. The result showed that the TiO₂ film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface. The average water contact angle of the film was 116.4° in dark, in contrast to an angle of 42.7° under the UV illumination for 2 hours, which demonstrates good hydrophobic property. The anti-corrosion behavior of the TiO₂ film was declining with the extended immersion time. Under dark conditions, however, the hydrophobic TiO₂ film retarded the water infiltrating into the substrate. The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight. All of those mentioned above indicate that the TiO₂ film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.     

From sequential to parallel growth of cities: Theory and evidence from Canada

This paper examines city growth patterns and the corresponding city size distribution evolution over long periods of time using a simple New Economic Geography(NEG) model and urban population data from Canada. The main findings are twofold. First, there is a transition from sequential to parallel growth of cities over long periods of time: city growth shows a sequential mode in the stage of rapid urbanization, i.e., the cities with the best development conditions will take the lead in growth, after which the cities with higher ranks will become the fastest-growing cities; in the late stage of urbanization, city growth converges according to Gibrat′s law, and exhibits a parallel growth pattern. Second, city size distribution is found to have persistent structural characteristics: the city system is self-organized into multiple discrete size groups; city growth shows club convergence characteristics, and the cities with similar development conditions eventually converge to a similar size. The results will not only enhance our understanding of urbanization process, but will also provide a timely and clear policy reference for promoting the healthy urbanization of developing countries.     

Large vesicles record pathways of degassing at basaltic volcanoes

Volcanic degassing is directly linked to magma dynamics and controls the style of eruptive activity. To better understand how gas is transported within basaltic magma we perform a 3D investigation of vesicles preserved in scoria from the 2005 activity at Stromboli volcano (Italy). We find that clasts are characterized by the ubiquitous occurrence of one to a few large vesicles, exhibiting mostly irregular, tortuous, channel-like textures, orders of magnitude greater in volume than all the other vesicles in the sample. We compare observations on natural samples with results from numerical simulations and experimental investigations of vesicle size distributions and demonstrate that this type of vesicle invariably forms in magmas with vesicularities > 0.30 (and possibly > 0.10). We suggest that large vesicles represent pathways used by gas to flow non-explosively to the surface and that they indicate the development of an efficient system that sustains persistent degassing in basaltic systems.     

The interaction between surface water and groundwater and its effect on water quality in the Second Songhua River basin,northeast China

The relationship between surface water and groundwater not only influences the water quantity, but also affects the water quality. The stable isotopes (δD, δ ¹⁸O) and hydrochemical compositions in water samples were analysed in the Second Songhua River basin. The deep groundwater is mainly recharged from shallow groundwater in the middle and upper reaches. The shallow groundwater is discharged to rivers in the downstream. The runoff from upper reaches mainly contributed the river flow in the downstream. The CCME WQI indicated that the quality of surface water and groundwater was ‘Fair’. The mixing process between surface water and groundwater was simulated by the PHREEQC code with the results from the stable isotopes. The interaction between surface water and groundwater influences the composition of ions in the mixing water, and further affects the water quality with other factors.     

Climate change outlook for water resources management in a semiarid river basin: the effect of the environmental water demand

Iran is a developing country with arid and semiarid regions. Poor management of water resources combined with the effects of climate change is leading to the drying of several rivers and wetlands. Several planned water development projects, primarily for agricultural expansion, will be implemented in the coming years which could worsen impacts on vulnerable aquatic ecosystems. Proper water resources management is essential to meet present and future residential, environmental, industrial, and agricultural demands in semiarid regions. This paper presents projections of how the availability of water resources will change in the Karkheh river basin of Iran for the period 2010–2059 employing sustainability criteria in the form of time-based reliability, volumetric reliability, resiliency, and vulnerability. This paper’s results show that consideration of environmental receptors as a stakeholder of water use places limitations on agricultural development within the Karkheh river basin.     

Photosynthetic characteristics of dominant tree species and canopy in the broadleaved Korean pine forest of Changbai Mountains

Based on the light-photosynthesis response measurement at leaf level, combined with over-and under-canopy eddy covariance measurements, research on photosynthetic characteristics of single trees and forest canopy was conducted. The relationship between light intensity and photosynthetic rates for leaves and canopy can be well fitted by a non-rectangular hyperbola model. Mongolian oak presented a high light compensation point, L _cp (28 μmol·m^?2·s^?1), a light saturation point L _sp (>1800 μmol·m^?2·s^?1), and a maximal net photosynthetic rate P _max (9.96 μmol·m^?2·s^?1), which suggest that it is a typical heliophilous plant. Mono maple presented the highest apparent quantum efficiency α (0.066) but the lowest, L _cp (16 μmol·m^?2·s^?1), L _sp (≈800 μmol·m^?2·s^?1), and P _max (4.51 μmol·m^?2·s^?1), which suggest that it is heliophilous plant. Korean pine showed the lowest α value but a higher P _max, which suggest that it is a semi-heliophilous plant. At the canopy level, the values of both α and P _max approached the upper limit of reported values in temperate forests, while L _cp was within the lower limit. Canopy photosynthetic characteristics were well consistent with those of leaves. Both showed a high ability to photosynthesize. However, environmental stresses, especially high vapor pressure deficits, could significantly reduce the photosynthetic ability of leaves and canopy.