Carbon isotope fractionation between dissolved and gaseous carbon dioxide

Fractionation of the stable carbon isotopes between dissolved and gaseous carbon dioxide has been measured at temperature 25°C by two methods. In the first method the open system conditions and different methods of CO₂ sampling were arranged. In the second method—the closed system conditions and CO₂ gas extraction were used. The results obtained by these methods are very consistent. Gaseous CO₂ is enriched in heavy isotope by 1.03±0.02 permil in comparison to dissolved carbon dioxide.     

Genotoxic impacts in Klaipeda Marine port and Bŭtinge oil terminal areas (Baltic Sea)

Genotoxic effects were evaluated in the somatic and gonadal cells of bivalve and gastropod molluscs inhabiting different sites of Klaipeda port area in Lithuania. The occurrence of aneuploidy and polyploidy of cells, meiotic injures, centromere dissociation and fragmented polyploid nuclei as cytogenetic indicators of environmental stressors was assessed in snails Lymnaea ovata . The highest level of environmental genotoxicity (in 43.2 and 46.2% of studied cells) was observed in the tissues of snails inhabiting Malku Bay in 1995 and 1996. Dredging and thus removal of contaminated sediments from Malku Bay resulted in significant decrease (up to 27.2% in 1999) of cytogenetic injures in molluscs studied over the period from 1997 to 1999. However, the frequency of cytogenetic disturbances in molluscs from Vilhelmo Channel was increasing (1.8 times) from 1995 to 1999. Therefore, the ecological safety of the biggest drinking water supply for Klaipeda population became questionable. Assessment of cytogenetic damage in Mytilus edulis (MN test) and the crustacean, Balanus improvisus, (aneugenic effects) inhabiting the Baltic Sea at B?tinge oil terminal has shown the highest genotoxicity level in the zone of sewage effluents from Palanga town and Mazeikiai oil refinery plant. Extensive cytogenetic injuries in gonadal cells indicated the potential long-term hazards of pollutants to ecological health and integrity of aquatic species.     

Organic fades in Recent sediments of carbonate platforms: Southwestern Puerto Rico and Northern Belize

Our organic facies model of a platform environment is based on the analysis of (1) total organic carbon, (2) visual protokerogen types and hydrogen indices of the sediments, (3) sediment mineralogy and grain size, and (4) reef patterns, water circulation, and relief of the adjacent land.TOC values are lowest on reefs and outer platforms (0.2%); intermediate in sediments fringing carbonate islands (0.5–2.0%), on sea-grass meadows (0.5–0.7%), and in forereef lagoons (0.1–0.7%); highest in inner platform lagoons (0.5–5.0%) and mangrove swamps (2.7–3.5%). Paniculate organic matter comprises structured terrestrial, marine, and amorphous types. On average, terrestrial material accounts for 28% of OM in Puerto Rico and 12% in Belize. The mean hydrogen index of the sediment is 355 (mg hydrocarbons/g TOC) in Puerto Rico and 719 in Belize.This study indicates that TOC values are mainly related to platform subenvironment, while OM types are controlled by distance from the shoreline. Organic facies dominated by structural terrestrial OM occur closer to the shore, whereas toward the shelf margin marine and amorphous OM contents increase.     

Modeling of a Multiply Jointed Voussoir Beam in the Centrifuge

Summary The mechanics and kinematics of a multiply jointed Voussoir beam have been studied based on the response of small scale beams tested in the centrifuge. The model beams were made up of six blocks, confined between fixed abutments. The tests included monitoring of beam deflection, development of axial thrust and distribution of strain within the beam. The models were subjected to accelerations of up to 90 g, depending upon the beam geometry. Two different beam geometries were considered. The test data were analysed in the light of pseudo analytical algorithms accepted in the analysis of singly jointed Voussoir beams. The data show that small translations and rotations of the block at the beam-abutment interface are required for a stable compression arch to set up in the beam. The computations and physical models indicate that the development of thrust is in linear proportion with the applied acceleration and is independent of beam thickness. The distribution of strains along the beam leads to the conclusion that the depth of the compression arch varies from the total beam thickness, to approximately one half of the beam thickness, under stable conditions. The data should be of considerable use to researchers looking to calibrate/validate numerical techniques used in describing the response of discontinuous rock masses.     

Tournaisian age of granitoids from the Odra Fault Zone (southwestern Poland): equivalent of the Mid-German Crystalline High?

The Odra Fault Zone of southwestern Poland is a NW-trending horst marked by gravimetric and magnetic anomalies and composed of high- to low-grade metamorphic and igneous rocks which are only known from boreholes. This zone embraces a concealed border between Variscan internides and externides. It also contains an array of several I-type, metaluminous to peraluminous, high potassic granitoid bodies which intruded earlier metamorphosed rocks. Except for one case, they remain unfoliated and undeformed, and presumably play a role of stitching plutons at the suture between two obliquely colliding terranes. U–Pb TIMS dating of single zircons from one foliated and one unfoliated granitoid samples yielded identical concordant ages of 344±1 Ma (Tournaisian). They resemble a Pb–Pb age of 350±5 Ma obtained for S-type granitoids from the Luckau area further west in Germany, which is generally regarded as an eastern segment of the Mid-German Crystalline High. Carboniferous granitic intrusions in the high are generally younger (340–290 Ma). Correlations of the the Odra Fault Zone with the Mid-German Crystalline High appear plausible, but by no means certain and require further confirmation.     

A comparison between the Linear Regression Model with autocorrelated errors and the Partial Adjustment Model

In this paper we consider a Linear Regression Model with a design matrix that fits the periodic structure of a time series. As a consequence, the residuals are very often autocorrelated. The main problem is that residual autocorrelation does not necessarily entail error autocorrelation. To analyse the effects of selecting different formulations to accommodate the autocorrelation in the residuals, we consider two seemingly different ways to deal with this problem: the Linear Regression Model with the error terms following an Autoregressive Stationary Process and the Partial Adjustment Model. We study the equivalence between the two formulations. We go over the problem of estimating the parameters and, especially, of making inferences in this framework. After parameter estimation, we analyse the adequacy of the models. We demonstrate that the issue of selecting the most appropriate model to capture the autocorrelation in the residuals is, in this context, a kind of an artefact since the main results concerning the fitted values and forecasting features are the same. These modelling procedures are applied to the Portuguese coastal upwelling data and we compare the estimated models.     

Seasonal variability of Holocene climate: a palaeolimnological study on varved sediments in Lake Jues (Harz Mountains, Germany)

Studies combining sedimentological and biological evidence to reconstruct Holocene climate beyond the major changes, and especially seasonality, are rare in Europe, and are nearly completely absent in Germany. The present study tries to reconstruct changes of seasonality from evidence of annual algal successions within the framework of well-established pollen zonation and ¹⁴C-AMS dates from terrestrial plants. Laminated Holocene sediments in Lake Jues (10°20.7′ E, 51°39.3′ N, 241 m a.s.l.), located at the SW margin of the Harz Mountains, central Germany, were studied for sediment characteristics, pollen, diatoms and coccal green algae. An age model is based on 21 calibrated AMS radiocarbon dates from terrestrial plants. The sedimentary record covers the entire Holocene period. Trophic status and circulation/stagnation patterns of the lake were inferred from algal assemblages, the subannual structure of varves and the physico-chemical properties of the sediment. During the Holocene, mixing conditions alternated between di-, oligo- and meromictic depending on length and variability of spring and fall periods, and the stability of winter and summer weather. The trophic state was controlled by nutrient input, circulation patterns and the temperature-dependent rates of organic production and mineralization. Climate shifts, mainly in phase with those recorded from other European regions, are inferred from changing limnological conditions and terrestrial vegetation. Significant changes occurred at 11,600 cal. yr. BP (Preboreal warming), between 10,600 and 10,100 cal. yr. BP (Boreal cooling), and between 8,400 and 4,550 cal. yr. BP (warm and dry interval of the Atlantic). Since 4,550 cal. yr. BP the climate became gradually cooler, wetter and more oceanic. This trend was interrupted by warmer and dryer phases between 3,440 and 2,850 cal. yr. BP and, likely, between 2,500 and 2,250 cal. yr. BP.     

Mass mortality of the fan mussel,Pinna nobilis in Turkey (eastern Mediterranean)

This study reported the mass mortality events (MMEs) of Pinna nobilis based on diving surveys in Turkey. Data were collected across 12 sites in the Aegean Sea, and one site in the Sea of Marmara, within the period of June-September 2019. The results showed that a low mortality rate of 10% was found in the Sea of Marmara, and a MME was not detected for this area. In contrast, 97% mortality was recorded for the P. nobilis population distributed in the Turkish Aegean Sea. This discrepancy might be related to the seawater temperature and salinity values of these two seas. The waters of the Sea of Marmara were colder and less salty than the Aegean Sea. The findings highlighted the importance of protecting the healthy population of critically endangered fan mussels in the Sea of Marmara. It was recommended that sound management plans comprising of monitoring, enforcement and public awareness activities could be implemented in order to achieve this.     

Refinements in BaSO4 to CO2 Preparation and δ18 O Calibration of the Sulfate Reference Materials NBS-127, IAEA SO-5 and IAEA SO-6

Refinements have been made to achieve over 99% yield in the conversion of CO to CO₂ in order to improve the reproducibility and accuracy of δ¹⁸ O measurements in sulfates. BaSO₄ (10-15 mg) was mixed with an identical amount of spectrographic-grade graphite and loaded into a Pt boat. The mixture was gradually heated to 1100 °C to reduce sulfate to CO and CO₂; the former gas was simultaneously converted to CO₂ by a glow discharge between Pt electrodes immersed in a magnetic field (produced by a pair of external neodymium magnets). A small memory effect was noticed during the analysis (less than 0.3‰ per 10‰ difference in δ¹⁸ O between two subsequently analysed samples). The memory effect, however, was suppressed by repetitive preparation of the same specimen. CO₂ produced in this way from sulfate reference samples was analysed on a dual inlet and triple collector mass spectrometer along with CO₂ equilibrated with VSMOW, GISP and SLAP water reference samples. To avoid large departures of measured isotope ratios from ¹⁸O/¹⁶O of the working calibrator we used CO₂ gas prepared from ocean water sulfate for this purpose. The calibrated δ¹⁸ O values (in ‰) obtained in this way for NBS-127, IAEA SO-5 and IAEA SO-6 reference materials were 8.73 ± 0.05, 12.20 ± 0.07 and -10.43 ± 0.12, respectively.