Weathering of sulfidic shale and copper mine waste: secondary minerals and metal cycling in Great Smoky Mountains National Park,Tennessee, and North Carolina,USA

Metal cycling via physical and chemical weathering of discrete sources (copper mines) and regional (non-point) sources (sulfide-rich shale) is evaluated by examining the mineralogy and chemistry of weathering products in Great Smoky Mountains National Park, Tennessee, and North Carolina, USA. The elements in copper mine waste, secondary minerals, stream sediments, and waters that are most likely to have negative impacts on aquatic ecosystems are aluminum, copper, zinc, and arsenic because these elements locally exceed toxicity guidelines for surface waters or for stream sediments. Acid-mine drainage has not developed in streams draining inactive copper mines. Acid-rock drainage and chemical weathering processes that accompany debris flows or human disturbances of sulfidic rocks are comparable to processes that develop acid-mine drainage elsewhere. Despite the high rainfall in the mountain range, sheltered areas and intermittent dry spells provide local venues for development of secondary weathering products that can impact aquatic ecosystems.Electronic Supplementary Material  Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.

On the astrometric detection of neighboring planetary systems,II

Extensive testing suggests that astrometric techniques can be employed to detect and study virtually any planetary system that may exist within 40 light years (12.5 parsec) of the Sun. Following the conclusion of Paper I [G. Gatewood, Icarus27 (1976), 1–12], the astrometric group at the Allegheny Observatory began an intensive survey of 20 nearby stars to detect the nonlinear variations in their motion that planetary systems would induce. Several tests conducted to further our understanding of the limitations of this survey indicated that the photographic detector itself is responsible for the majority of the random error. A new photoelectric detector has been designed and a simplified prototype of it successfully tested. The new detector is expected to be able to utilize virtually all of the astrometric information transmitted through the Earth's atmosphere. This is sufficient to determine relative positions to within an accuracy of approximately 1 milliarcsec/hr. Such precisions exceed the design capabilities of the best existing astrometric telescopes, thus a feasibility study has been conducted for the design of an improved instrument. The study concludes that a new ground-based telescope and the new detector combined should be able to study stars as faint as the 17th magnitude with an annual accuracy of a few tenths of a milliarcsecond. However, to obtain the ultimate accuracy possible from current technology, we must place an astrometric system above the Earth's atmosphere. A space-borne instrument utilizing the new detector would in theory have sufficient accuracy to detect any Earth-like planet orbiting any of the several hundred stars nearest the Sun.     

Rapid colorimetric determination of phosphorus in geochemical survey samples

A colorimetric method for the determination of phosphorus in batches of geochemical survey samples is described. The powdered material is digested with a nitric-perchloric acid mixture, excess of acid is evaporated off and the residue is leached with water. Aliquots of the leachate are treated with vanadomolybdate reagent and the yellow phosphorus complex is extracted into isobutyl methyl ketone. The colour in the organic phase, which is stable for many days, is matched against a series of similarly prepared standards. Iron, other coloured ions, and titanium do not interfere. Standard deviations of ±0.02% about a mean value of 0.20% P₂ O₅ and ±0.4% about a mean of 11.6% P₂ O₅ were obtained. At least 40 powdered samples may be analysed per working day per person.     

Extrasolar Analogues to the Kuiper Belt

Debris disks are found around some 15% of main sequencestars and their dust is thought to be continuallyreplenished in collisions between planetesimals inextrasolar Kuiper belts.While they were discovered in 1984 by IRAS, it is onlywith more recent imaging that their true nature has beenrevealed. This paper discusses recent debris disk images andtheir impact on our understanding of extrasolar systems.Importantly these images confirm the extrasolar Kuiper belthypothesis for most (but not all) debris diskcandidates and show that the planetesimals within thesedisks must have grown to at least a few km.Asymmetries in imaged disk structures also provide informationabout the planetary systems orbiting inside these planetesimalbelts. The impact of debris disk studies on our understandingof the evolution of our own Kuiper belt, as well as theirpotential to solve puzzles such as the origin of the missingmass and the outer edge of the Kuiper belt, is alsodiscussed.     

Metabolic conversion of cyclohexane by Pacific salmon microsomal preparations

Hydrocarbons are being introduced into the marine environment from a variety of sources including combustion processes, crude oil spills, fuel oil spills, and controlled disposal such as processed ballast water. Even in the relatively clean waters of Alaska hydrocarbons are being released at an alarming rate. The purpose of this study was to determine the optimum conditions for the metabolism of a representative hydrocarbon by Coho Salmon Oncorhynchus kisutch liver microsomes. The product of cyclohexane metabolism in the salmon microsomal system was identified by gas chromatography-mass spectrometry as cyclohexanol. Conditions of the microsome incubation were varied systematically to determine the optimum temperature, pH, and ionic strength for cyclohexanol production. Cyclohexanol was quantified by capillary column gas chromatography. Maximum cyclohexanol formation was achieved at 20°C, a pH of 8·0–8·5 and an ionic strength of 0·026. A linear rate of cyclohexanol formation is seen from 0–60 min of incubation and there is an apparent decrease in the rate from 60–90 min. Poor stability of the microsomal preparation from the species studied was also identified and several stability studies have been undertaken using cyclohexane metabolism as a monitor.     

Volcanoes and peat bogs

Peat bogs in the British Isles contain tephra from volcanic eruptions in Iceland; tephra in the Falkland Islands most likely derives from Andean volcanoes. Study of these far-travelled volcanic products is making a significant contribution to our understanding of past environmental changes.