Time-series of δ26Mg values in a headwater catchment reveal decreasing magnesium isotope variability from precipitation to runoff

Data on temporal variability in Mg isotope ratios of atmospheric deposition and runoff are critical for decreasing the uncertainty associated with construction of isotope mass balances in headwater catchments, and statistical evaluation of isotope differences among Mg pools and fluxes. Such evaluations, in turn, are needed to distinguish between biotic and abiotic contributions to Mg²⁺ in catchment runoff. We report the first annual time-series of δ²⁶Mg values simultaneously determined for rainfall, canopy throughfall, soil water and runoff. The studied 55-ha catchment, situated in western Czech Republic, is underlain by Mg-rich amphibolite and covered by mature spruce stands. Between 1970 and 1996, the site received extremely high amounts of acid deposition and fly ash form nearby coal-burning power plants. The δ²⁶Mg values of open-area precipitation (median of −0.79‰) at our study site were statistically indistinguishable from the δ²⁶Mg values of throughfall (−0.73‰), but significantly different from the δ²⁶Mg values of soil water (−0.55‰) and runoff (−0.55‰). The range of δ²⁶Mg values during the observation period decreased in the order: open-area precipitation (0.57‰) > throughfall (0.27‰) > runoff (0.21‰) > soil water (0.16‰). The decreasing variability in δ²⁶Mg values of Mg²⁺ from precipitation to soil water and runoff reflected an increasing homogenization of atmospheric Mg in the catchment and its mixing with geogenic Mg. In addition to atmospheric Mg, runoff also contained Mg mobilized from the three major solid Mg pools, bedrock (δ²⁶Mg of −0.32‰), soil (−0.28‰), and vegetation (−0.31‰). The drought of summer 2019 did not affect the nearly constant δ²⁶Mg value of runoff. Collectively, our data show that within-catchment processes buffer the Mg isotope variability of the atmospheric input.     

Inter‐comparison of hydro‐climatic regimes across northern catchments: synchronicity,resistance and resilience

The higher mid‐latitudes of the Northern Hemisphere are particularly sensitive to climate change as small differences in temperature determine frozen ground status, precipitation phase, and the magnitude and timing of snow accumulation and melt. An international inter‐catchment comparison program, North‐Watch, seeks to improve our understanding of the sensitivity of northern catchments to climate change by examining their hydrological and biogeochemical responses. The catchments are located in Sweden (Krycklan), Scotland (Mharcaidh, Girnock and Strontian), the United States (Sleepers River, Hubbard Brook and HJ Andrews) and Canada (Catamaran, Dorset and Wolf Creek). This briefing presents the initial stage of the North‐Watch program, which focuses on how these catchments collect, store and release water and identify ‘types’ of hydro‐climatic catchment response. At most sites, a 10‐year data of daily precipitation, discharge and temperature were compiled and evaporation and storage were calculated. Inter‐annual and seasonal patterns of hydrological processes were assessed via normalized fluxes and standard flow metrics. At the annual‐scale, relations between temperature, precipitation and discharge were compared, highlighting the role of seasonality, wetness and snow/frozen ground. The seasonal pattern and synchronicity of fluxes at the monthly scale provided insight into system memory and the role of storage. We identified types of catchments that rapidly translate precipitation into runoff and others that more readily store water for delayed release. Synchronicity and variance of rainfall–runoff patterns were characterized by the coefficient of variation (cv) of monthly fluxes and correlation coefficients. Principal component analysis (PCA) revealed clustering among like catchments in terms of functioning, largely controlled by two components that (i) reflect temperature and precipitation gradients and the correlation of monthly precipitation and discharge and (ii) the seasonality of precipitation and storage. By advancing the ecological concepts of resistance and resilience for catchment functioning, results provided a conceptual framework for understanding susceptibility to hydrological change across northern catchments. Copyright © 2010 John Wiley & Sons, Ltd.     

Modelling rating curves using remotely sensed LiDAR data

Accurate stream discharge measurements are important for many hydrological studies. In remote locations, however, it is often difficult to obtain stream flow information because of the difficulty in making the discharge measurements necessary to define stage‐discharge relationships (rating curves). This study investigates the feasibility of defining rating curves by using a fluid mechanics‐based model constrained with topographic data from an airborne LiDAR scanning. The study was carried out for an 8m‐wide channel in the boreal landscape of northern Sweden. LiDAR data were used to define channel geometry above a low flow water surface along the 90‐m surveyed reach. The channel topography below the water surface was estimated using the simple assumption of a flat streambed. The roughness for the modelled reach was back calculated from a single measurment of discharge. The topographic and roughness information was then used to model a rating curve. To isolate the potential influence of the flat bed assumption, a ‘hybrid model’ rating curve was developed on the basis of data combined from the LiDAR scan and a detailed ground survey. Whereas this hybrid model rating curve was in agreement with the direct measurements of discharge, the LiDAR model rating curve was equally in agreement with the medium and high flow measurements based on confidence intervals calculated from the direct measurements. The discrepancy between the LiDAR model rating curve and the low flow measurements was likely due to reduced roughness associated with unresolved submerged bed topography. Scanning during periods of low flow can help minimize this deficiency. These results suggest that combined ground surveys and LiDAR scans or multifrequency LiDAR scans that see ‘below’ the water surface (bathymetric LiDAR) could be useful in generating data needed to run such a fluid mechanics‐based model. This opens a realm of possibility to remotely sense and monitor stream flows in channels in remote locations. Copyright © 2012 John Wiley & Sons, Ltd.     

Quaternary of Norden

The Nordic countries have experienced multiple glaciations and intervening interglacials during the last ca. 2.5-3 million years. Although evidence from Greenland and Iceland shows that ice sheets started to expand some time before 3 Ma, little is known about the glaciations and intervening interglacials older than the last Glacial Maximum due to repeated phases of glacial erosion and reworking. The extensive Saalian glaciation （c. 140 ka BP） contributed to high sea levels in Greenland and in the Baltic area during the early part of the last interglacial （Eemian）. Temperatures were about 5 ℃ higher during the Eemian than they are today and the Greenland ice sheet was reduced to about half of its present size, causing globally higher sea levels than we have today. Ice extent in Fennoscandia was restricted during early Weichselian stadials, but middle Weichselian ice advances in Scandinavia reached as far as Denmark. During the Last Glacial Maximum, large ice sheets were present in all Nordic countries and coalesced with neighboring ice sheets. Deglaciation commenced around 17-15 ka BP in most areas and was promoted by rapidly rising global sea level and glacial isostasy. The Younger Dryas cold event（c. 12.6-11.5 ka BP） is seen as a short-term re-advance, still-stand or fluctuation of land-based ice sheet margins. Around 7-9 ka BP ice sheets had disappeared or had attained their present size. While uplift is still going on in some regions, others are subject to submergence. The different stages of development of the Baltic Sea are an example of how the intricare interplay between glacial eustasy and isostasy influences sedimentation, basin size and drainage patterns.     

Determination of the conduit structure in a karst aquifer based on tracer data—Lurbach system,Austria

A structure model was used to analyse solute‐transport parameter estimates based on tracer breakthrough curves. In the model system, groundwater flow is envisioned to be organised in a complex conduit network providing a variety of short circuits with relative small carrying capacities along different erosion levels. The discharge through the fully filled conduits is limited owing to void geometries and turbulent flow; thus, a hierarchic overflow system evolves where conduits are (re‐)activated or dried up depending on the flow condition. Exemplified on the Lurbach–Tanneben karst aquifer, the applicability of the model approach was tested. Information derived from multi‐tracer experiments performed at different volumetric flow rates enabled to develop a structural model of the karst network, under constraint of the geomorphological and hydrological evolution of the site. Depending on the flow rate, groundwater is divided into up to eight flow paths. The spatial hierarchy of flow paths controls the sequence of flow path activation. Conduits of the topmost level are strongly influenced by reversible alteration processes. Sedimentation or blocking causes an overflow of water to the next higher conduit. Flow path specific dissolutional denudation rates were estimated using the temporal development of the partial discharge. Copyright © 2012 John Wiley & Sons, Ltd.     

European summer temperature response to annually dated volcanic eruptions over the past nine centuries

The drop in temperature following large volcanic eruptions has been identified as an important component of natural climate variability. However, due to the limited number of large eruptions that occurred during the period of instrumental observations, the precise amplitude of post-volcanic cooling is not well constrained. Here we present new evidence on summer temperature cooling over Europe in years following volcanic eruptions. We compile and analyze an updated network of tree-ring maximum latewood density chronologies, spanning the past nine centuries, and compare cooling signatures in this network with exceptionally long instrumental station records and state-of-the-art general circulation models. Results indicate post-volcanic June–August cooling is strongest in Northern Europe 2 years after an eruption (?0.52?±?0.05 °C), whereas in Central Europe the temperature response is smaller and occurs 1 year after an eruption (?0.18?±?0.07 °C). We validate these estimates by comparison with the shorter instrumental network and evaluate the statistical significance of post-volcanic summer temperature cooling in the context of natural climate variability over the past nine centuries. Finding no significant post-volcanic temperature cooling lasting longer than 2 years, our results question the ability of large eruptions to initiate long-term temperature changes through feedback mechanisms in the climate system. We discuss the implications of these findings with respect to the response seen in general circulation models and emphasize the importance of considering well-documented, annually dated eruptions when assessing the significance of volcanic forcing on continental-scale temperature variations.     

Morpho-tectonic evolution of the Crimean mountains (Ukraine) as constrained by apatite fission track data

Apatite fission track thermochronology (AFT) is used to investigate the low-temperature thermal evolution of the Crimean Mountains and provide new insights into the geodynamic and geomorphic evolution of the westernmost tip of the Caucasus–Crimean fold-and-thrust belt. The vast majority of the samples taken from Jurassic sedimentary and magmatic rocks revealed AFT ages in the range of 51–32 Ma. These ages, together with modelled cooling paths, show that the mountain range experienced a thermal overprint after the Late Cimmerian orogeny. We interpret the overprint in terms of the burial of Cimmerian structures by a thick pile (>4 km) of platform sediments during Early Cretaceous–Late Eocene times. This scenario implies that highly elevated palaeosurfaces of Early Cretaceous age survived in large part because of the protection provided by thick accumulations of platform deposits. Since final uplift in the middle Pliocene, the palaeosurfaces have been significantly degraded and dissected by fluvial incision and large-scale landslides.     

Diamond precipitation from ascending reduced fluids in the Kaapvaal lithosphere: Thermodynamic constraints

Previous research has shown that the Kaapvaal lithospheric mantle is generally reduced and characterised by a decreasing redox state with increasing depth. As a consequence, C-O-H fluids in the Kaapvaal lithospheric mantle are dominated by H₂O, CH₄, and C₂H₆. Thermodynamic calculations demonstrate that diamond precipitation from such a fluid during ascend is possible as it is exposed to a more oxidised environment and both CH₄ and C₂H₆ are oxidised. However, the calculations also demonstrate that the diamond precipitation potential from such a fluid decreases when: (1) the mantle is either more reduced or oxidised compared to the Kaapvaal mantle, or (2) the change in temperature with pressure is smaller compared to that of the Kaapvaal mantle. Therefore, the presence of reduced mantle fluid species and a generally decreasing oxygen fugacity with increasing depth do not necessarily warrant diamond precipitation from a rising reduced fluid.