New insights into the heterogeneity of the Tagish Lake meteorite: Soluble organic compositions of variously altered specimens

The Tagish Lake carbonaceous chondrite exhibits a unique compositional heterogeneity that may be attributed to varying degrees of aqueous alteration within the parent body asteroid. Previous analyses of soluble organic compounds from four Tagish Lake meteorite specimens (TL5b, TL11h, TL11i, TL11v) identified distinct distributions and isotopic compositions that appeared to be linked to their degree of parent body processing (Herd et al. 2011; Glavin et al. 2012; Hilts et al. 2014). In the present study, we build upon these initial observations and evaluate the molecular distribution of amino acids, aldehydes and ketones, monocarboxylic acids, and aliphatic and aromatic hydrocarbons, including compound‐specific δ¹³C compositions, for three additional Tagish Lake specimens: TL1, TL4, and TL10a. TL1 contains relatively high abundances of soluble organics and appears to be a moderately altered specimen, similar to the previously analyzed TL5b and TL11h lithologies. In contrast, specimens TL4 and TL10a both contain relatively low abundances of all of the soluble organic compound classes measured, similar to TL11i and TL11v. The organic‐depleted composition of TL4 appears to have resulted from a relatively low degree of parent body aqueous alteration. In the case of TL10a, some unusual properties (e.g., the lack of detection of intrinsic monocarboxylic acids and aliphatic and aromatic hydrocarbons) suggest that it has experienced extensive alteration and/or a distinct organic‐depleted alteration history. Collectively, these varying compositions provide valuable new insights into the relationships between asteroidal aqueous alteration and the synthesis and preservation of soluble organic compounds.     

Development of push moraines in deeply frozen sediment adjacent to a cold-based glacier in the McMurdo Dry Valleys,Antarctica

Previous studies of push moraines have concluded that structural architecture is controlled by a combination of stress exerted by flowing ice and the rheology of the deforming sediment. However, the relationship between deformation processes and the thermal/hydrologic conditions within the sediment remains ambiguous. Using a combination of surface mapping, logging exposures and ground penetrating radar we examine the relationships between surface morphology, material properties and development of deformation structures in deeply frozen sediment that has been deformed by Joyce Glacier, a cold-based glacier in the McMurdo Dry Valleys. The structural architecture of the push moraines is characterized by a combination of brittle and ductile deformation structures that have produced a structurally complex pattern of thrust faults, low angle listric thrusts and recumbent folds that extend 400 m beyond the glacier margin. Deformation is ductile where the ice concentration exceeds c. 65% volume and predominantly brittle where the ice concentration is less than c. 65%. The change in rheology reflects transition in behaviour from the material having a predominantly frictional character when the ice is limited to pore spaces to a non-frictional character in which strength is primarily determined by the cohesive strength of the ice. This work shows that glaciotectonic deformation can occur in deeply frozen permafrost where there is no liquid pore water. We conclude that the presence of liquid porewater is not a necessary condition for the development of glaciotectonic deformation or for the formation of push moraines. © 2019 John Wiley & Sons, Ltd.     

On the Importance of Time for GIS View Measures and Their Use in Hedonic Property Models: Does Being Temporally Explicit Matter?

Progress in GIScience has advanced the ability to represent and analyze view characteristics. GIS‐derived view measures requiring digital elevation surface models are used in hedonic property models to quantify the amenity value of view for parcel sales transactions. Ideally models should represent surface elevations that are temporally synchronized with parcel sale dates. Temporal synchronization for studies spanning multiple years may require significant effort. Few studies have undertaken this effort, leading us to investigate in this research the need to be temporally explicit. We evaluate two competing surface model approaches based on: (1) a single year 2000 LiDAR surface product; and (2) annual‐specific surface products for 1995–2002. Two competing view measures based on the different surface approaches are constructed for 561 parcel transactions during 1995–2002 in a coastal North Carolina county and are input into hedonic regression models. Results showed that being temporally explicit did matter in terms of finding significantly different view measures but did not matter in terms of finding significantly different effects of view on parcel sales prices. Despite mixed results for our case study, we advise that future research involving GIS‐based view measurement should consider the spatial and temporal contexts of study area development patterns when evaluating the need to be temporally explicit.     

Assessment of boundary-element method for modelling a free-floating sloped wave energy device. Part 2: Experimental validation

The boundary-element method has been widely used as a design tool in the offshore and ship building industry for more than 30 years. Its application to wave energy conversion is, however, more recent. This is the second of two papers on a comparison of numerical and physical modelling of a free-floating sloped wave energy converter. In the first paper the numerical modelling formulation for the power take-off mechanism was derived using the boundary-element method package WAMIT. It was verified against numerical benchmark data. In this paper, the outcome of the modelling of the whole device is compared with experimental measurements obtained from model testing in a wave tank. The agreement is generally good.     

Hydrocarbons in the intertidal environment of Kachemak Bay,Alaska

Intertidal animals and sediment from Kachemak Bay, Alaska were analysed to determine the concentrations of hydrocarbons. At Coal Point the herbivorous limpet Collisella pelta contained petroleum within its tissues while intertidal algae of the area have previously been shown to accumulate petroleum as a surface coating. At Coal Bay, a locality where both petroleum and coal are present, the filter feeding mussel Mytilus edulis contained petroleum hydrocarbons whereas the deposit feeding clam Macoma balthica contained an array of hydrocarbons suggesting detrital coal as the source. Animals higher in the food web including the gastropod Nucella lima and the urchin Strongylocentrotus droebachiensis showed no evidence of petroleum. All samples contained biogenic hydrocarbons of algal and planktonic origin.     

Effects of streamflow isotope sampling strategies on the calibration of a tracer-aided rainfall-runoff model

Isotopes are increasingly used in rainfall-runoff models to constrain conceptualisations of internal catchment functioning and reduce model uncertainty. However, there is little guidance on how much tracer data is required to adequately do this, and different studies use data from different sampling strategies. Here, we used a 7-year time series of daily stable water isotope samples of precipitation and streamflow to derive a range of typical stream sampling regimes and investigate how this impacts calibration of a semi-distributed tracer-aided model in terms of flow, deuterium and flux age simulations. Over the 7 years weekly sampling facilitated an almost identical model performance as daily, and there were only slight deteriorations in performance for fortnightly sampling. Monthly sampling resulted in poorer deuterium simulations and greater uncertainty in the derived parameter sets ability to accurately represent catchment functioning, evidenced by unrealistic reductions in the volumes of water available for mixing in the saturation area causing simulated water age decreases. Reducing sampling effort and restricting data collection to 3 years caused reductions in the accuracy of deuterium simulation, though the deterioration did not occur if sampling continued for 5 years. Analysis was also undertaken to consider the effects of reduced sampling effort over the driest and wettest hydrological years to evaluate effects of more extreme conditions. This showed that the model was particularly sensitive to changes in sampling during dry conditions, when the catchment hydrological response is most non-linear. Across all dataset durations, sampling in relation to flow conditions, rather than time, revealed that samples collected at flows >Q50 could provide calibration results comparable to daily sampling. Targeting only extreme high flows resulted in poor deuterium and low flow simulations. This study suggests sufficient characterization of catchment functioning can be obtained through reduced sampling effort over longer timescales and the targeting of flows >Q50.     

Extraterrestrial organic compounds and cyanide in the CM2 carbonaceous chondrites Aguas Zarcas and Murchison

Evaluating the water‐soluble organic composition of carbonaceous chondrites is key to understanding the inventory of organic matter present at the origins of the solar system and the subsequent processes that took place inside asteroid parent bodies. Here, we present a side‐by‐side analysis and comparison of the abundance and molecular distribution of aliphatic amines, aldehydes, ketones, mono‐ and dicarboxylic acids, and free and acid‐releasable cyanide species in the CM2 chondrites Aguas Zarcas and Murchison. The Aguas Zarcas meteorite is a recent fall that occurred in central Costa Rica and constitutes the largest recovered mass of a CM‐type meteorite after Murchison. The overall content of organic species we investigated was systematically higher in Murchison than in Aguas Zarcas. Similar to previous meteoritic organic studies, carboxylic acids were one to two orders of magnitude more abundant than other soluble organic compound classes investigated in both meteorite samples. We did not identify free cyanide in Aguas Zarcas and Murchison; however, cyanide species analyzed after acid digestion of the water‐extracted meteorite mineral matrix were detected and quantified at slightly higher abundances in Aguas Zarcas compared to Murchison. Although there were differences in the total abundances of specific compound classes, these two carbonaceous chondrites showed similar isomeric distributions of aliphatic amines and carboxylic acids, with common traits such as a complete suite of structural isomers that decreases in concentration with increasing molecular weight. These observations agree with their petrologic CM type‐2 classification, suggesting that these meteorites experienced similar organic formation processes and/or conditions during parent body aqueous alteration.