Arsenic incorporation in a salt marsh ecosystem

Replicate portions of a Delaware salt marsh were enclosed in cylindrical microcosms and exposed to elevated levels of inorganic arsenic (arsenate). All biotic and abiotic components in dosed cylinders rapidly incorporated arsenic. Spartina blades showed the greatest arsenic enrichment, with dosed plants incorporating arsenic concentrations an order of magnitude higher than controls. Spartina detritus and sediments also exhibited greatly elevated arsenic concentrations. Virtually all of the arsenic was incorporated into plant tissue or strongly sorbed to cell surfaces. Thus, elevated arsenic concentrations in estuarine waters will be reflected in living and non-living components of a salt marsh ecosystem, implying that increased arsenic will be available to organisms within the marsh ecosystem.     

Screening of polymers on selected Hawaii soils for erosion reduction and particle settling

In recent years, high‐molecular‐weight anionic polyacrylamides (PAMs) have been tested on a variety of soils, primarily in temperate climates. However, little information is available regarding the effectiveness of PAM for preventing soil loss through runoff in tropical settings. Screening tests were performed using three negatively charged PAMs and one positively charged PAM on five Hawaii soils (two Oxisols, one Vertisol, and two Aridisols) to determine erosion loss, sediment settling, and aggregate stability. A laboratory‐scale rainfall simulator was used to apply erosive rainfall at intensities from 5 to 8·5 cm h^?1 at various PAM doses applied in both dry and solution forms. Soil detachment due to splash and runoff, as well as the runoff and percolate water volumes, were measured for initial and successive storms. The impact of PAM on particle settling and aggregate stability was also evaluated for selected soil‐treatment combinations. Among the PAMs, Superfloc A‐836 was most effective, and significantly reduced runoff and splash sediment loss for the Wahiawa Oxisol and Pakini Andisol at rates varying between 10 and 50 kg ha^?1. Reduced runoff and splash sediment loss were also noted for PAM Aerotil‐D when applied in solution form to the Wahiawa Oxisol. Significant reductions in soil loss were not noted for either the Lualualei Vertisol or the Holomua Oxisol. It is believed that the high montmorillonite content of the Lualualei Vertisol and the low cation‐exchange capacity of the Holomua Oxisol diminished the effectiveness of the various PAMs tested. The polymers were also found to enhance sediment settling of all soils and helped improve their aggregate stability. This screening study shows the potential use of PAM for tropical soils for applications such as infiltration enhancement, runoff reduction, and enhanced sedimentation of detention ponds. Copyright © 2005 John Wiley & Sons, Ltd.     

The origin of polygonal troughs on the Northern Plains of Mars

Viking photographs have revealed extraordinary systems of crudely polygonal troughs in three different areas of the northern plains of Mars. Trough widths average 200–800 m and average trough spacing is 5–10 km. The widest troughs have flat floors and steep sides which suggest that they are either grabens or tension cracks which have been partially filled. The following three arguments support the garben interpretation: (1) Two clear examples of vertical offsets along trough walls indicate that the troughs formed by downdropping of the floors. (2) Troughs similar in scale and morphology to those of the Martian northern plains form concentric and radial patterns in the Caloris Basin on Mercury. Most likely, they are extensional fractures or grabens resulting from uplift of the basin floor (Strom et al., 1975). The Caloris analogy suggests that the troughs on Mars are similar tectonic features related either to uplift or expansion of the planet. Fourteen rose diagrams of trough azimuths in southeastern Acidalia Planita show that locally they exhibit preferred orientations roughly parallel to the topographic contours, but overall there is no strong regional pattern. (3) The scale of tension crack systems is limited by the depth of fracturing because the extent of stress relief perpendicular to a crack is proportional to the crack depth. Observations of terrestrial tension cracks suggest a lower limit on crack depths of about one-tenth of the average spacing. Thus, if the Martian troughs are tension cracks, they would be expected to have depths of at least 500–1000 m. Mechanical considerations indicate that it is difficult to generate such deep cracks by surficial tension due to thermal cooling and contraction in permafrost, desiccation, or cooling of lava flows. Deep-seated tension of tectonic origin generally results in normal faults and not tension cracks.     

Seismic response of light internal equipment in base-isolated structures

The seismic response of light secondary systems in a building is dependent on the response of the primary structural system to the seismic ground motion with the result that very high accelerations can be induced in such secondary systems. This response can be reduced through the use of aseismic base isolation which is a design strategy whereby the entire building can be decoupled from the damaging horizontal components of seismic ground motion by the use of some form of isolation system. The paper presents a theoretical analysis of the response of light equipment in isolated structures and a parallel experimental programme both of which show that the use of base isolation can not only attenuate the response of the primary structural system but also reduce the response of secondary systems. Thus, the design of equipment and piping in a base-isolated building is very much simpler than that for a conventionally founded structure: inelastic response and equipment-structure interaction need not be considered and multiple support response analysis is rendered unnecessary. Although an isolation system with linear elastic bearings can reduce the acceleration of the structure, it may be accompanied by large relative displacements between the structure and the ground. A system using lead-rubber hysteretic bearings, having a force-displacement relation which is approximately a bilinear loop, can reduce these displacements. A parallel experimental programme was carried out to investigate the response of light equipment in structures isolated using lead-rubber bearings. The experimental results show that these bearings can dissipate energy and limit the displacement and acceleration of the structure but are less effective in reducing the accelerations in the internal equipment. The results of both the analysis and the tests show that base isolation is a very effective method for the seismic protection of light equipment items in buildings.     

The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350°C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.