High-resolution acoustic mapping of shallow gas in unconsolidated sediments beneath the strait of Georgia,British Columbia

Gassy sediments are detectable acoustically in subbottom profiles of Canada's Fraser Delta slope and prodelta areas. Interstitial gas is typically represented by zones of acoustic turbidity on high-resolution seismic profiles and by gas brightening on air-gun profiles. The top of the acoustically turbid zone is generally highest within the sediment column closest to the river mouths and lies within 10 ms (two-way travel time) of the sea floor in a nearly continuous area that covers over 530 km². Most of the gas is believed to be biogenic in origin, although thermogenic gas derived from underlying Tertiary sedimentary rocks may be present in places.     

Secondary flow caused by differential roughness,Langmuir circulations,and their effect on the development of sand ribbons

The process of Differential Roughness Secondary Flow (DRSF), hitherto little recognized, recently was demonstrated in a wind tunnel and in a flume. It is suggested here the DRSF may, in the natural environment, play an important part in the persistence and sharp definition of sand ribbons, previously initiated by other processes. In 1980 Karl described a series of sand ribbons, alternating with exposed substrate, which he attributed to the effect of Langmuir circulations. Although Langmuir Circulation Secondary Flow (LCSF) may indeed, in some cases, initiate sand ribbons, the sharply-defined edges typical of these features are explained better by DRSF.     

Distributions of dissolved and particulate biogenic thiols in the subartic Pacific Ocean

Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation.     

Gravity field analysis of Sio Guyot: An isostatically compensated seamount in the Mid-Pacific Mountains

Positive gravity anomalies indicate two dense conduits or eruptive centers beneath the northern summit of Sio Guyot, western Mid-Pacific Mountains. The low amplitude of the positive anomalies and the gravity lows flanking the guyot can be explained by crust 2.5 times the normal Pacific Ocean crustal thickness extending to a depth of 22 ± 2 km. The excess mass of the seamount is 100% locally isostatically compensated by the mass deficit below; this compensation may result from flexural loading and voluminous sill injection near a former ridge-crest transform fault system trending roughly ENE and NNW.     

Thermodynamic characterization of the partitioning of iron between soluble and colloidal species in the Atlantic Ocean

Recent electrochemical measurements have shown that iron (Fe) speciation in seawater is dominated by complexation with strong organic ligands throughout the water column and have provided important thermodynamic information about these compounds. Independent work has shown that iron exists in both soluble and colloidal fractions in the Atlantic Ocean. Here we have combined these approaches in samples collected from a variety of regimes within the Atlantic Ocean. We measured the partitioning of Fe between soluble (< 0.02 μm) and colloidal (0.02 to 0.4 μm) size classes and characterized the concentrations and conditional stability constants of Fe ligands within these size classes. Results suggest that equilibrium partitioning of Fe between soluble and colloidal ligands is partially responsible for the distribution of Fe between soluble and colloidal size classes. However, a significant fraction of the colloidal Fe was inert to ligand exchange as soluble Fe concentrations were generally lower than values predicted by a simple equilibrium partitioning model.In surface waters, strong ligands with conditional stability constants of 10¹³ relative to total inorganic Fe appeared to dominate speciation in both the soluble and colloidal fractions. In deep waters these ligands were absent, and instead we found ligands with stability constants 12–15 fold smaller that were predominantly in the soluble pool. Nevertheless, significant levels of colloidal Fe were found in these samples, which we inferred must be inert to coordination exchange.     

Ghost fishing in European waters: Impacts and management responses

In this paper we review levels of net loss, what happens to the gear once it has been lost, and the resulting levels of ‘ghost catches’ made in passive net fisheries in the EU. We also consider ghost catches resulting from lost gear in other types of fisheries, and the extent to which the value of ghost catches has been quantified. We consider why fishing gear is lost, and profile common management responses. We present a cost benefit model to assess the relative cost effectiveness of different management measures, and suggest that gear retrieval programmes may provide less value for money than other management responses.