Asymmetrically zoned reaction rims: assessment of grain boundary diffusivities and growth rates related to natural diffusion-controlled mineral reactions

This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe²⁺, Fe³⁺ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe²⁺ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～10³–10⁴ years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 10⁵–10⁶ and 10⁶–10⁷ years respectively.     

Quick-look assessments to identify optimal CO2 EOR storage sites

A newly developed, multistage quick-look methodology allows for the efficient screening of an unmanageably large number of reservoirs to generate a workable set of sites that closely match the requirements for optimal CO₂ enhanced oil recovery (EOR) storage. The objective of the study is to quickly identify miscible CO₂ EOR candidates in areas that contain thousands of reservoirs and to estimate additional oil recovery and sequestration capacities of selected top options through dimensionless modeling and reservoir characterization. Quick-look assessments indicate that the CO₂ EOR resource potential along the US Gulf Coast is 4.7 billion barrels, and CO₂ sequestration capacity is 2.6 billion metric tons. In the first stage, oil reservoirs are screened and ranked in terms of technical and practical feasibility for miscible CO₂ EOR. The second stage provides quick estimates of CO₂ EOR potential and sequestration capacities. In the third stage, a dimensionless group model is applied to a selected set of sites to improve the estimates of oil recovery and storage potential using appropriate inputs for rock and fluid properties, disregarding reservoir architecture and sweep design. The fourth stage validates and refines the results by simulating flow in a model that describes the internal architecture and fluid distribution in the reservoir. The stated approach both saves time and allows more resources to be applied to the best candidate sites.     

Large and giant hydrocarbon accumulations in the transitional continent-ocean zone

The petroleum resource potential is considered for the Atlantic, West Pacific, and East Pacific types of deepwater continental margins. The most considerable energy resources are concentrated at the Atlantic-type passive margins in the zone transitional to the ocean. The less studied continental slope of backarc seas of the generally active margins of the West Pacific type is currently not so rich in discoveries as the Atlantic-type margin, but is not devoid of certain expectations. In some of their parameters, the margins bounded by continental slopes may be regarded as analogs of classical passive margins. At the margins of the East Pacific type, the petroleum potential is solely confined to transform segments. In the shelf-continental-slope basins of the rift and pull-apart nature, petroleum fields occur largely in the upper fan complex, and to a lesser extent in the lower graben (rift) complex. In light of world experience, the shelf-continental-slope basins of the Arctic and Pacific margins of Russia are evaluated as highly promising.     

THE LAUSANNE CONGRESS

The International Society for Photogrammetry held the Xlth International Congress at Lausanne during July 1968. The authors review the activities of five of the seven I.S.P. Commissions.     

THE ANALYTICAL ORIENTATION OF A LUNAR MODEL

An analytical relative orientation of a stereo-pair of photographs was computed in an unusual system of co-ordinates. The disparity in the widely mismatched photographs, their tilts and narrow angles subtended resulted in a rather weak solution from which sections of the lunar surface have been plotted. The results were not good but were better than expected. The main outcome of the work is a, probably unique, demonstration of the versatility of analytical photogrammetry.     

Models of the Southern Oscillation in the 300–100 mb layer and the basis of seasonal forecasting

Summary The geometry of the principal Upper High (near the Indian Occean) in the 300–100 mb layer appears to account for the Southern Oscillation (S.O.), and models of its behaviour are presented. Significant features of these models include the equatorial points of upper convergence (C) and divergence (D), a pressure discontinuity (CNDS) forming «arcs» and an «enclosure» around the high, and, lastly, encircling «crescents» both outside and inside the enclosure. The geography of the seasonal sucession can thus—in a qualitative manner—be interpreted in the light of known wind and contour patterns near the tropopause. With a few general principles, the established empirical rules of long-range forecasting then follow by deduction. The models and the terminology are useful likewise in the interpretation of solar-terrestrial relations and of climatic fluctuations.     

A Lagrangian model for wind- and wave-induced near-surface currents

A theory is outlined for time-dependent currents induced near the sea surface in deep water, away from coastal boundaries, by a variable wind stress and deep-water wave field. It is based on the theory of Weber (1983) which uses a second-order perturbation expansion of the Navier-Stokes equations in Lagrangian coordinates and includes the Coriolis effect. It uses an eddy viscosity formulation for both wave dissipation and momentum transfer within the current field: the eddy viscosity ν may be allowed to vary with depth. The wind stress may be time-varying and the wave field may vary in both space and time.For the case of a constant ν, the results agree with those of Ursell (1950), Hasselmann (1970) and Pollard (1970) in the limit ν→0, and the steady-state results agree with those of Weber. For a particular case of depth-varying ν, results (obtained from numerical simulations) are in better general agreement with observations of wind-induced surface drift than when a constant ν is used.An outline is given of the application of the theory to the case of a random sea state. There are good prospects for using output data from numerical wave prediction models to drive the equations of this near-surface current model.