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101.
Vladica Cvetkovi? Suzana Eri? Ma?a Radivojevi? Kristina ?ari? 《Mineralogy and Petrology》2012,106(3-4):131-150
The study focuses on clinopyroxene from mantle xenolith-bearing East Serbian basanites and suggests that dissolution of mantle orthopyroxene played an important role in at least some stages of the crystallization of these alkaline magmas. Five compositional types of clinopyroxene are distinguished, some of them having different textural forms: megacrysts (Type-A), green/colourless-cored phenocrysts (Type-B), overgrowths and sieve-textured cores (Type-C), rims and matrix clinopyroxene (Type-D), and clinopyroxene from the reaction rims around orthopyroxene xenocrysts (Type-E). Type-A is high-Al diopside that probably crystallized at near-liquidus conditions either directly from the host basanite or from compositionally similar magmas in previous magmatic episodes. Type-B cores show high VIAl/IVAl≥1 and low Mg# of mostly <75 and are interpreted as typical xenocrysts. Type-C, D and E are interpreted as typical cognate clinopyroxene. Type-D has Mg#<78, Al2O3?=?6–13?wt.%, TiO2?=?1.5–4.5?wt.%, and Na2O?=?0.4–0.8?wt.% and compositionally similar clinopyroxene is calculated by MELTS as a phase in equilibrium with the last 30?% of melt starting from the average host lava composition. Type-C has Mg#?=?72–89, Al2O3?=?4.5–9.5?wt.%, TiO2?=?1–2.5?wt.%, Na2O?=?0.35–1?wt.% and Cr2O3?=?0.1–1.5?wt.%. This clinopyroxene has some compositional similarities to Type-E occurring exclusively around mantle orthopyroxene. Cr/Al vs Al/Ti and Cr/Al vs Na/Ti plots revealed that Type-C clinopyroxene can crystallize from a mixture of the host basanite magma and 2–20?wt.% mantle orthopyroxene. Sieve-textured Type-C crystals show characteristics of experimentally produced skeletal clinopyroxene formed by orthopyroxene dissolution suggesting that crystallization of Type-C was both texturally and compositionally controlled by orthopyroxene breakdown. According to FeO/MgOcpx/melt modelling the first clinopyroxene precipitating from the host basanite was Type-A (T?~?1250?°C, p?~?1.5?GPa). Dissolution of orthopyroxene produced decreasing FeO/MgOmelt and crystallization of Type-E and sieve-textured Type-C clinopyroxene (0.3–0.8?GPa and 1200–1050?°C). The melt composition gradually shifted towards higher FeO/MgOmelt ratios precipitating more evolved Type-C and Type-D approaching near-solidus conditions (<0.3?GPa; ~950?°C). 相似文献
102.
Dauphiné twinning and texture memory in polycrystalline quartz. Part 3: texture memory during phase transformation 总被引:1,自引:0,他引:1
Hans-Rudolf?WenkEmail author N.?Barton M.?Bortolotti S.?C.?Vogel M.?Voltolini G.?E.?Lloyd G.?B.?Gonzalez 《Physics and Chemistry of Minerals》2009,36(10):567-583
Samples of quartz-bearing rocks were heated above the α (trigonal)–β (hexagonal) phase transformation of quartz (625–950°C)
to explore changes in preferred orientation patterns. Textures were measured both in situ and ex situ with neutron, synchrotron
X-ray and electron backscatter diffraction. The trigonal–hexagonal phase transformation does not change the orientation of
c- and a-axes, but positive and negative rhombs become equal in the hexagonal β-phase. In naturally deformed quartzites measured by
neutron diffraction a perfect texture memory was observed, i.e. crystals returned to the same trigonal orientation they started
from, with no evidence of twin boundaries. Samples measured by electron back-scattered diffraction on surfaces show considerable
twinning and memory loss after the phase transformation. In experimentally deformed quartz rocks, where twinning was induced
mechanically before heating, the orientation memory is lost. A mechanical model can explain the memory loss but so far it
does not account for the persistence of the memory in quartzites. Stresses imposed by neighboring grains remain a likely cause
of texture memory in this mineral with a very high elastic anisotropy. If stresses are imposed experimentally the internal
stresses are released during the phase transformation and the material returns to its original state prior to deformation.
Similarly, on surfaces there are no tractions and thus texture memory is partially lost. 相似文献
103.
A 4.96-m-long sediment core from the Hanon paleo-maar in Jeju Island, Korea was studied to investigate the paleoclimatic change and East Asian monsoon variations during the latest Pleistocene to early Holocene (23,000-9000 cal yr BP). High-resolution TOC content, magnetic susceptibility, and major element composition data indicate that Jeju Island experienced the coldest climate around 18,000 cal yr BP, which corresponds to the last glacial maximum (LGM). Further, these multi-proxy data show an abrupt shift in climatic regime from cold and arid to warm and humid conditions at around 14,000 cal yr BP, which represents the commencement of the last major deglaciation. After the last major deglaciation, the TOC content decreased from 13,300 to 12,000 cal yr BP and from 11,500 to 9800 cal yr BP, thereby reflecting the weakening of the summer monsoon. The LGM in Jeju Island occurred later in comparison with the Chinese Loess Plateau. Such a disparity in climatic change events between central China and Jeju Island appears to be caused by the asynchrony between the coldest temperature event and the minimum precipitation event in central China and by the buffering effect of the Pacific Ocean. 相似文献
104.
Irina?ZhukovaEmail author Hugh?O’Neill Ian?H.?Campbell 《Contributions to Mineralogy and Petrology》2017,172(7):53
Diffusion of Al in synthetic forsterite was studied at atmospheric pressure from 1100 to 1500 °C in air along [100] with activities of SiO2, MgO and Al2O3 (aSiO2, aMgO and aAl2O3) buffered. At low aSiO2, the buffer was forsterite + spinel + periclase (fo + sp + per) at all temperatures, while at high aSiO2 and subsolidus conditions a variety of three-phase assemblages containing forsterite and two other phases from spinel, cordierite, protoenstatite or sapphirine were used at 1100–1350 °C. Experiments at high aSiO2 and 1400 °C used forsterite + protoenstatite + melt (fo + en + melt), and at 1500 °C, fo + melt. The resulting diffusion profiles were analysed by LA–ICP–MS in scanning mode. Diffusion profiles in the high aSiO2 experiments were generally several hundred microns in length, but diffusion at low aSiO2 was three orders of magnitude slower than in high aSiO2 experiments carried out at the same temperature, producing short profiles only a few microns in length and close to the spatial resolution of the analytical method. Interface concentrations of Al in the forsterite, obtained by extrapolating the diffusion profiles to the crystal/buffer interface, were only a fraction of those expected at equilibrium, and varied among the differing buffer assemblages according to (aAl2O3)1/2 and (aSiO2)3/4, pointing to the substitution of Al in forsterite by an octahedral-site, vacancy-coupled (OSVC) component with the stoichiometry Al 4/3 3+ vac2/3SiO4, whereas the main substitution expected from previous equilibrium studies would be the coupled substitution of 2 Al for Mg + Si, giving the stoichiometry MgAl2O4. It is proposed that this latter substitution is not seen on the length scales of the present experiments because it requires replacement of Si by Al on tetrahedral sites, and is accordingly rate-limited by the slow diffusivity of Si. Instead, diffusion of Al by the OSVC mechanism is relatively fast, and at high aSiO2, even faster than Fe–Mg interdiffusion. 相似文献
105.
Adsorption characteristics of perchloroethylene in natural sandy materials with low organic carbon content 总被引:2,自引:0,他引:2
Laboratory batch tests were conducted to investigate the sorption isotherms and sorption kinetics of the chlorinated hydrocarbon
perchloroethylene (PCE) in five natural sandy materials with an organic carbon content (f
oc) in the range 0.080–0.540%. The amended non-linear dual-mode model can describe the sorption isotherms in materials with
f
oc in the range 0.080–0.090%. For a sample with a much higher f
oc of 0.54%, the absorption isotherm was found to fit a linear model. These results may indicate that organic carbon is not
the main factor influencing the sorption isotherm. The sorption kinetics of PCE in samples with f
oc in the range 0.080–0.090% are not first-order and are different from those observed in the samples with higher f
oc. The sorption process in the materials with lower f
oc involves fast sorption, fast desorption and an equilibrium stage. The results may imply that the factors affecting sorption
kinetics of PCE in low f
oc media are pore filling and capillary condensation rather than organic carbon content. 相似文献
106.
Hydrologic modelling of the effect of snowmelt and temperature on a mountainous watershed 总被引:2,自引:0,他引:2
Snowmelt-runoff modelling in a mountainous basin is perceived as difficult due to the complexity of simulation. Theoretically, the snowmelt process should be influenced by temperature changes. It is still controversial as how to incorporate the temperature changes into the snowmelt-runoff model in a mountainous basin. This paper presents the results of a study in the North Fork American River basin where the snowmelt-runoff mechanism is modelled by relating the temperature changes to the elevation band in the basin. In this study, a distributed hydrologic model is used to explore the orographic effects on the snowmelt-runoff using the snowfall-snowmelt routine in Soil and Water Assessment Tool (SWAT). Three parameters, namely maximum snowmelt factor, minimum snowmelt factor, and snowpack temperature lag were analysed during the simulation. The model was validated using streamflow data from October 1, 1991 to September 30, 1994 with and without considering the elevation band. The result of this study suggests that the snowmelt-runoff model associated with the elevation band better represents the snowmelt-runoff mechanism in terms of Nash–Sutcliffe coefficient (E NS ), R 2, and Root Mean Square Error (RMSE). 相似文献
107.
In Europe, the Wide Wheel abrasion (WWA) test and the B?hme abrasion (BA) test are among the most widely used standard test
methods for determining abrasion resistance of natural stones, the former being the reference test method in EN 14157 Standard.
However, it is stated in the Annex-A (Informative) of EN 14157 Standard that very limited data are available to provide correlations
between these two test methods. To be able to fill this gap, in this study, 25 different natural stones belonging to sedimentary,
metamorphic and igneous groups were tested for their abrasion resistance as well as physico-mechanical properties. Also, for
a better interpretation of abrasion resistance characteristics of the tested stone materials, relationships between abrasion
resistance and physico-mechanical properties were statistically examined. A statistically significant linear correlation (R
2 = 0.85; P value = 0.000) was established between the WWA test and the BA test, which could be used in practice for converting the measured
abrasion resistance values from one testing method to another. It was also found that the correlation between these two test
methods improved significantly (R
2 = 0.93; P value = 0.001) when relatively high-porosity stone materials (porosity ≥1%) were separately evaluated. Both methods of abrasion
resistance employed in the present study showed statistically significant linear correlations with uniaxial compressive strength
and Brazilian tensile strength, the former proving to be a more influencing parameter on resistance to abrasion. Also, from
the point view of representing actual abrasion mechanism of stone materials in practice, the necessity of simulating multi-directional
foot traffic in abrasion testing methods was discussed. In this respect, the reference test method in the EN 14157 Standard
was criticized for not fully meeting this requirement. It was also pointed out that the reference method could have some drawbacks
when applied to coarse-grained granitic rocks having cleavable minerals such as plagioclase and orthoclase feldspars. 相似文献
108.
该种方法利用离子色谱仪的电导检测器与电化学检测器串联 ,十几分钟即可连续完成水中S2 - 、SO2 - 3 、SO2 - 4、S2 O2 - 3 的测定 ,方法具有快速、高效、方便、灵敏、选择性好等特点。方法的检出限分别为 :S2 - 12 5 μg/L ;SO2 - 3 2 2 4 μg/L ;SO2 - 45 0 μg/L ;S2 O2 - 35 0 μg/L。相对标准偏差在 1 5 %~ 6 9%之间 ,能够满足水中S2 - 、SO2 - 3 、SO2 - 4、S2 O2 - 3四种阴离子分析测试的需要。 相似文献
109.
The structures of sodium silicate and aluminosilicate glasses quenched from melts at high pressure (6-10 GPa) with varying degrees of polymerization (fractions of nonbridging oxygen) were explored using solid-state NMR [17O and 27Al triple-quantum magic-angle spinning (3QMAS) NMR]. The bond connectivity in melts among four and highly coordinated network polyhedra, such as [4]Al, [5,6]Al, [4]Si, and [5,6]Si, at high pressure is shown to be significantly different from that at ambient pressure. In particular, in the silicate and aluminosilicate melts, the proportion of nonbridging oxygen (NBO) generally decreases with increasing pressure, leading to the formation of new oxygen clusters that include 5- and 6-coordinated Si and Al in addition to 4-coordinated Al and Si, such as [4]Si-O-[5,6]Si, [4]Si-O-[5,6]Al and Na-O-[5,6]Si. While the fractions of [5,6]Al increase with pressure, the magnitude of this increase diminishes with increasing degrees of ambient-pressure polymerization under isobaric conditions. Incorporating the above structural information into models of melt properties reproduces the anomalous pressure-dependence of O2− diffusivity and viscosity often observed in silicate melts. 相似文献
110.
Sequential extraction and leaching characteristics of heavy metals in abandoned tungsten mine tailings sediments 总被引:1,自引:0,他引:1
Pyeong-Koo Lee Min-Ju Kang Ho Young Jo Sang-Hoon Choi 《Environmental Earth Sciences》2012,66(7):1909-1923
The chemical speciation of potentially toxic elements (As, Cd, Cu, Pb, and Zn) in the contaminated soils and sulfides-rich tailings sediments of an abandoned tungsten mine in Korea was evaluated by conducting modified BCR sequential extraction tests. Kinetic and static batch leaching tests were also conducted to evaluate the potential release of As and other heavy metals by acidic rain water and the leaching behaviors of these heavy metals. The major sources of the elements were As-, Zn- and Pb-bearing sulfides, Pb carbonates (i.e., cerussite), and Pb sulfates (i.e., anglesite). The biggest pollutant fraction in these soil and tailing samples consists of metals bound to the oxidizable host phase, which can be released into the environment if conditions become oxidative, and/or to residual fractions. No significant difference in total element concentrations was observed between the tailings sediments and contaminated soils. For both sample types, almost no changes occurred in the mobility of As and the other heavy metals at 7 days, but the mobility increased afterwards until the end of the tests at 30 days, regardless of the initial pH. However, the mobility was approximately 5–10 times higher at initial pH 1.0 than at initial pHs of 3.0 and 5.0. The leached amounts of all the heavy metal contents were higher from tailings sediments than from contaminated soils at pH > 3.0, but were lower at pH < 3.0 except for As. Results of this study suggest that further dissolution of heavy metals from soil and tailing samples may occur during extended rainfall, resulting in a serious threat to surface and groundwater in the mine area. 相似文献