Morphology and geology of the continental shelf and upper slope of southern Central Chile (33°S–43°S)

The continental shelf and slope of southern Central Chile have been subject to a number of international as well as Chilean research campaigns over the last 30 years. This work summarizes the geologic setting of the southern Central Chilean Continental shelf (33°S–43°S) using recently published geophysical, seismological, sedimentological and bio-geochemical data. Additionally, unpublished data such as reflection seismic profiles, swath bathymetry and observations on biota that allow further insights into the evolution of this continental platform are integrated. The outcome is an overview of the current knowledge about the geology of the southern Central Chilean shelf and upper slope. We observe both patches of reduced as well as high recent sedimentation on the shelf and upper slope, due to local redistribution of fluvial input, mainly governed by bottom currents and submarine canyons and highly productive upwelling zones. Shelf basins show highly variable thickness of Oligocene-Quaternary sedimentary units that are dissected by the marine continuations of upper plate faults known from land. Seismic velocity studies indicate that a paleo-accretionary complex that is sandwiched between the present, relatively small active accretionary prism and the continental crust forms the bulk of the continental margin of southern Central Chile.     

Application of a hydrometeorological model chain to investigate the effect of global boundaries and downscaling on simulated river discharge

In the current study, two regional climate models (MM5 and REMO) driven by different global boundary conditions (the ERA40 reanalysis and the ECHAM5 model) are one-way coupled to the uncalibrated hydrological process model PROMET to analyze the impact of global boundary conditions, dynamical regionalization and subsequent statistical downscaling (bilinear interpolation, correction of subgrid-scale variability and combined correction of subgrid-scale variability and bias) on river discharge simulation. The results of 12 one-way coupled model runs, set up for the catchment of the Upper Danube (Central Europe) over the historical period 1971–2000, prove the expectation that the global boundaries applied to force the RCMs strongly influence the accuracy of simulated river discharge. It is, however, noteworthy that all efficiency criteria in case of bias corrected MM5 simulations indicate better performance under ERA40 boundaries, whereas REMO-driven hydrological simulations better correspond to measured discharge under ECHAM5 boundaries. Comparing the hydrological results achievable with MM5 and REMO, the application of bias-corrected MM5 simulations turned out to allow for a more accurate simulation of discharge, while the variance in simulated discharge in most cases was better reflected in case of REMO forcings. The correction of subgrid-scale variability within the downscaling of RCM simulations compared to a bilinear interpolation allows for a more accurate simulation of discharge for all model configurations and all discharge criteria considered (mean monthly discharge, mean monthly low-flow and peak-flow discharge). Further improvements in the hydrological simulations could be achieved by eliminating the biases (in terms of deviations from observed meteorological conditions) inherent in the driving RCM simulations, regardless of the global boundary conditions or the RCM applied. In spite of all downscaling and bias correction efforts described, the RCM-driven hydrological simulations remain less accurate than those achievable with spatially distributed meteorological observations.     

The Australia telescope 20 GHz survey: hardware, observing strategy, and scanning survey catalog

The Australia Telescope 20 GHz (AT20G) survey is a large area (2?? sr), sensitive (40 mJy), high frequency (20 GHz) survey of the southern sky. The survey was conducted in two parts: an initial fast scanning survey, and a series of more accurate follow-up observations. The follow-up survey catalog has been presented by Murphy et al. (MNRAS 402:2403, 2010). In this paper we discuss the hardware setup and scanning survey strategy as well as the production of the scanning survey catalog.     

Constraining input and output fluxes of the southern-central Chile subduction zone: water,chlorine and sulfur

In this paper, we constrain the input and output fluxes of H₂O, Cl and S into the southern-central Chilean subduction zone (31°S–46°S). We determine the input flux by calculating the amounts of water, chlorine and sulfur that are carried into the subduction zone in subducted sediments, igneous crust and hydrated lithospheric mantle. The applied models take into account that latitudinal variations in the subducting Nazca plate impact the crustal porosity and the degree of upper mantle serpentinization and thus water storage in the crust and mantle. In another step, we constrain the output fluxes of the subduction zone both to the subcontinental lithospheric mantle and to the atmosphere–geosphere–ocean by the combined use of gas flux determinations at the volcanic arc, volume calculations of volcanic rocks and the combination of mineralogical and geothermal models of the subduction zone. The calculations indicate that about 68 Tg/m/Ma of water enters the subduction zone, as averaged over its total length of 1,480 km. The volcanic output on the other hand accounts for 2 Tg/m/Ma or 3 % of that input. We presume that a large fraction of the volatiles that are captured within the subducting sediments (which accounts for roughly one-third of the input) are cycled back into the ocean through the forearc. This assumption is however questioned by the present lack of evidence for major venting systems of the submarine forearc. The largest part of the water that is carried into the subduction zone in the crust and hydrated mantle (accounting for two-thirds of the input) appears to be transported beyond the volcanic arc.     

Dissolution of cinnabar (HgS) in the presence of natural organic matter

Cinnabar (HgS) dissolution rates were measured in the presence of 12 different natural dissolved organic matter (DOM) isolates including humic, fulvic, and hydrophobic acid fractions. Initial dissolution rates varied by 1.3 orders of magnitude, from 2.31 × 10⁻¹³ to 7.16 × 10⁻¹² mol Hg (mg C)⁻¹ m⁻²s⁻¹. Rates correlate positively with three DOM characteristics: specific ultraviolet absorbance (R² = 0.88), aromaticity (R² = 0.80), and molecular weight (R² = 0.76). Three experimental observations demonstrate that dissolution was controlled by the interaction of DOM with the cinnabar surface: (1) linear rates of Hg release with time, (2) significantly reduced rates when DOM was physically separated from the surface by dialysis membranes, and (3) rates that approached constant values at a specific ratio of DOM concentration to cinnabar surface area, suggesting a maximum surface coverage by dissolution-reactive DOM. Dissolution rates for the hydrophobic acid fractions correlate negatively with sorbed DOM concentrations, indicating the presence of a DOM component that reduced the surface area of cinnabar that can be dissolved. When two hydrophobic acid isolates that enhanced dissolution to different extents were mixed equally, a 20% reduction in rate occurred compared to the rate with the more dissolution-enhancing isolate alone. Rates in the presence of the more dissolution-enhancing isolate were reduced by as much as 60% when cinnabar was prereacted with the isolate that enhanced dissolution to a lesser extent. The data, taken together, imply that the property of DOM that enhances cinnabar dissolution is distinct from the property that causes it to sorb irreversibly to the cinnabar surface.     

Improved regional scale processes reflected in projected hydrological changes over large European catchments

For the fourth assessment report of the Intergovernmental Panel on Climate Change (IPCC), the recent version of the coupled atmosphere/ocean general circulation model (GCM) of the Max Planck Institute for Meteorology has been used to conduct an ensemble of transient climate simulations These simulations comprise three control simulations for the past century covering the period 1860–2000, and nine simulations for the future climate (2001–2100) using greenhouse gas (GHG) and aerosol concentrations according to the three IPCC scenarios B1, A1B and A2. For each scenario three simulations were performed. The global simulations were dynamically downscaled over Europe using the regional climate model (RCM) REMO at 0.44° horizontal resolution (about 50 km), whereas the physics packages of the GCM and RCM largely agree. The regional simulations comprise the three control simulations (1950–2000), the three A1B simulations and one simulation for B1 as well as for A2 (2001–2100). In our study we concentrate on the climate change signals in the hydrological cycle and the 2 m temperature by comparing the mean projected climate at the end of the twenty-first century (2071–2100) to a control period representing current climate (1961–1990). The robustness of the climate change signal projected by the GCM and RCM is analysed focussing on the large European catchments of Baltic Sea (land only), Danube and Rhine. In this respect, a robust climate change signal designates a projected change that sticks out of the noise of natural climate variability. Catchments and seasons are identified where the climate change signal in the components of the hydrological cycle is robust, and where this signal has a larger uncertainty. Notable differences in the robustness of the climate change signals between the GCM and RCM simulations are related to a stronger warming projected by the GCM in the winter over the Baltic Sea catchment and in the summer over the Danube and Rhine catchments. Our results indicate that the main explanation for these differences is that the finer resolution of the RCM leads to a better representation of local scale processes at the surface that feed back to the atmosphere, i.e. an improved representation of the land sea contrast and related moisture transport processes over the Baltic Sea catchment, and an improved representation of soil moisture feedbacks to the atmosphere over the Danube and Rhine catchments.     

Parameterization of snow-free land surface albedo as a function of vegetation phenology based on MODIS data and applied in climate modelling

The aim of this study was to develop an advanced parameterization of the snow-free land surface albedo for climate modelling describing the temporal variation of surface albedo as a function of vegetation phenology on a monthly time scale. To estimate the effect of vegetation phenology on snow-free land surface albedo, remotely sensed data products from the Moderate-Resolution Imaging Spectroradiometer (MODIS) on board the NASA Terra platform measured during 2001 to 2004 are used. The snow-free surface albedo variability is determined by the optical contrast between the vegetation canopy and the underlying soil surface. The MODIS products of the white-sky albedo for total shortwave broad bands and the fraction of absorbed photosynthetically active radiation (FPAR) are analysed to separate the vegetation canopy albedo from the underlying soil albedo. Global maps of pure soil albedo and pure vegetation albedo are derived on a 0.5° regular latitude/longitude grid, re-sampling the high-resolution information from remote sensing-measured pixel level to the model grid scale and filling up gaps from the satellite data. These global maps show that in the northern and mid-latitudes soils are mostly darker than vegetation, whereas in the lower latitudes, especially in semi-deserts, soil albedo is mostly higher than vegetation albedo. The separated soil and vegetation albedo can be applied to compute the annual surface albedo cycle from monthly varying leaf area index. This parameterization is especially designed for the land surface scheme of the regional climate model REMO and the global climate model ECHAM5, but can easily be integrated into the land surface schemes of other regional and global climate models.     

The partitioning of seawater cations during the transformation of gypsum to anhydrite

The coprecipitation of Sr, Mg, Na and K with anhydrite during the dehydration of gypsum was studied in laboratory experiments. The partition coefficients of Mg and Sr between anhydrite and solution decrease with increasing temperature. The partition coefficients of the alkali-ions do not depend upon temperature, but are affected by the brine composition.The mechanism of the phase transformation gypsum → anhydrite occurs via dissolution and precipitation, when the coprecipitated-ions are repartitioned between the new phase and the solution. The partition coefficients established in this study are applicable also for primary anhydrite.During the dehydration of gypsum at elevated temperatures metastable bassanite may form as an intermediate stage. The amount of cations coprecipitated with bassanite is much larger than the amount coprecipitated with anhydrite or gypsum. This phenomenon may have an influence on the partitioning of cations during the dehydration of gypsum, particularly on Sr.The partition coefficients of seawater cations between anhydrite and the brine are similar to those between gypsum and the brine. For this reason the coprecipitated-ions are not expected to be good indicators to distinguish between primary and secondary calcium sulfate minerals.The temperature effect on the coprecipitation of Mg and Sr with anhydrite makes these ions possible indicators for the temperature at which the phase transformation occurred. This temperature corresponds to the depth of burial of the gypsum at the stage of dehydration.The coprecipitation of seawater cations with anhydrite in the natural environment was studied in two systems: A small Pleistocene evaporite lens from the Sinai Peninsula and the Triassic anhydrite of the Mohilla Formation, Israel. The coprecipitated-ion composition of these samples was used to derive the conditions under which the anhydrite was formed.     

New Reference Materials,Analytical Procedures and Data Reduction Strategies for Sr Isotope Measurements in Geological Materials by LA-MC-ICP-MS

Laser ablation multi-collector mass spectrometry (LA-MC-ICP-MS) has emerged as the technique of choice for in situ measurements of Sr isotopes in geological minerals. However, the method poses analytical challenges and there is no widely adopted standardised approach to collecting these data or correcting the numerous potential isobaric inferences. Here, we outline practical analytical procedures and data reduction strategies to help establish a consistent framework for collecting and correcting Sr isotope measurements in geological materials by LA-MC-ICP-MS. We characterise a new set of plagioclase reference materials, which are available for distribution to the community, and present a new data reduction scheme for the Iolite software package to correct isobaric interferences for different materials and analytical conditions. Our tests show that a combination of Kr-baseline subtraction, Rb-peak-stripping using βRb derived from a bracketing glass reference material, and a CaCa or CaAr correction for plagioclase and CaCa or CaAr + REE²⁺ correction for rock glasses, yields the most accurate and precise ⁸⁷Sr/⁸⁶Sr measurements for these materials. Using the analytical and correction procedures outlined herein, spot analyses using a beam diameter of 100 μm or rastering with a 50–65 μm diameter beam can readily achieve < 100 ppm 2SE repeatability ("internal") precision for ⁸⁷Sr/⁸⁶Sr measurements for materials with < 1000 μg g^-1 Sr.