全文获取类型
收费全文 | 111篇 |
免费 | 1篇 |
专业分类
大气科学 | 2篇 |
地球物理 | 6篇 |
地质学 | 77篇 |
海洋学 | 15篇 |
天文学 | 8篇 |
自然地理 | 4篇 |
出版年
2020年 | 3篇 |
2018年 | 1篇 |
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 2篇 |
2013年 | 1篇 |
2012年 | 1篇 |
2011年 | 8篇 |
2010年 | 4篇 |
2009年 | 17篇 |
2008年 | 5篇 |
2007年 | 7篇 |
2006年 | 2篇 |
2005年 | 1篇 |
2004年 | 8篇 |
2003年 | 4篇 |
2002年 | 3篇 |
2001年 | 2篇 |
2000年 | 5篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1975年 | 1篇 |
排序方式: 共有112条查询结果,搜索用时 15 毫秒
21.
22.
Diatomaceous ooze of the shelf off Walvis Bay (S.W. Africa) was analysed for lipid material. The lipids from the sediment consist of a mixture of hydrocarbons, alcohols, ketones, fatty acids, sterols, carotenoid pigments and chlorophylls. The total fatty acid mixture has been analysed by capillary gas chromatography mass spectrometry and shown to consist of straight chain, iso-, anteiso- and isoprenoid acids. The environmental setting of the S.W. African shelf (Walvis Bay) makes it possible to discuss these fatty acids as markers for the fate of organic matter. The acids in the sediment point to a generation during passage of algal lipids through levels of microbial activity either on or slightly above the burial surface. 相似文献
23.
Heather Clegg Brian Horsfield Heinz Wilkes Jaap Sinninghe Damst Martin P. Koopmans 《Organic Geochemistry》1998,29(8):1953-1960
Hydrous pyrolysis experiments were performed on the Ghareb Formation (Upper Cretaceous, Jordan), a carbonate- and organic-rich (TOC 19.6%) source rock, using a temperature range of 200 to 360°C (72 h). The original sediment contains only low amounts of carbazoles, (maximum 2.2 μg/g bitumen for 1-methylcarbazole). With increasing thermal maturation, intense generation begins at temperatures only in excess of 300°C, reaching a maximum at 360°C. Likewise, during natural maturation, generation occurs at later stages of maturity (e.g. for Tithonian source rocks at >0.81% Rr and for Posidonia Shale at >0.88% Rr). Some isomeric changes during hydrous pyrolysis do not resemble those in nature whereas others do. The relative abundances of selected C1- and C2-alkylcarbazoles on ternary diagrams reveal differences, whereas the benzo[a]carbazole/benzo[a]carbazole+benzo[c]carbazole ratio is closely similar. The latter result supports the contention that maturation plays a key role in controlling carbazole distributions in source rocks. However, the results for alkylcarbazoles, especially the C2-carbazoles, are not easy to interpret. 相似文献
24.
Anke Putschew Christine Schaeffer-Reiss Philippe Schaeffer Martin P Koopmans Jan W de Leeuw Michael D Lewan Jaap S Sinninghe Damsté James R Maxwell 《Organic Geochemistry》1998,29(8):1875-1890
An immature sulfur-rich marl from the Gessosso-solfifera Formation of the Vena del Gesso Basin (Messinian, Italy) has been subjected to hydrous pyrolysis (160 to 330°C) to simulate maturation under natural conditions. The kerogen of the unheated and heated samples was isolated and the hydrocarbons released by selective chemical degradation (Li/EtNH2 and HI/LiAlH4) were analysed to allow a study of the fate of sulfur- and oxygen-bound species with increasing temperature. The residues from the chemical treatments were also subjected to pyrolysis–GC to follow structural changes in the kerogens. In general, with increasing hydrous pyrolysis temperature, the amounts of sulfide- and ether-bound components in the kerogen decreased significantly. At the temperature at which the generation of expelled oil began (260°C), almost all of the bound components initially present in the unheated sample were released from the kerogen. Comparison with an earlier study of the extractable organic matter using a similar approach and the same samples provides molecular evidence that, with increasing maturation, solvent-soluble macromolecular material was initially released from the kerogen, notably as a result of thermal cleavage of weak carbon–heteroatom bonds (sulfide, ester, ether) even at temperatures as low as 220°C. This solvent-soluble macromolecular material then underwent thermal cleavage to generate hydrocarbons at higher temperatures. This early generation of bitumen may explain the presence of unusually high amounts of extractable organic matter of macromolecular nature in very immature S-rich sediments. 相似文献
25.
Jaap S. Sinninghe Damst Math E. L. Kohnen Brian Horsfield 《Organic Geochemistry》1998,29(8):1891-1903
Micro-scale sealed vessel (MSSV) pyrolysis experiments have been conducted at temperatures of 150, 200, 250, 300, 330 and 350°C for various times on a thermally immature Type II-S kerogen from the Maastrichtian Jurf ed Darawish Oil Shale (Jordan) in order to study the origin of low-molecular-weight (LMW) alkylthiophenes. These experiments indicated that the LMW alkylthiophenes usually encountered in the flash pyrolysates of sulphur-rich kerogens are also produced at much lower pyrolysis temperatures (i.e. as low as 150°C) as the major (apart from hydrogen sulfide) sulphur-containing pyrolysis products. MSSV pyrolysis of a long-chain alkylthiophene and an alkylbenzene indicated that at 300°C for 72 h no β-cleavage leading to generation of LMW alkylated thiophenes and benzene occurs. In combination with the substantial production of LMW alkylthiophenes with a linear carbon skeleton at these conditions, this indicated that these thiophenes are predominantly formed by thermal degradation of multiple (poly)sulfide-bound linear C5–C7 skeletons, which probably mainly originate from sulphurisation of carbohydrates during early diagenesis. LMW alkylthiophenes with linear carbon skeletons seem to be unstable at MSSV pyrolysis temperatures of ≥330°C either due to thermal degradation or to methyl transfer reactions. LMW alkylthiophenes with a branched carbon skeleton most likely derive from both multiple (poly)sulfide-bound branched C5–C7 skeletons and alkylthiophene units present in the kerogen. 相似文献
26.
Marcel J.L. HoefsW.Irene C. Rijpstra Jaap S. Sinninghe Damsté 《Geochimica et cosmochimica acta》2002,66(15):2719-2735
Free and ester-bound lipid biomarkers were analysed in oxidised and unoxidised parts of four distinct turbidites from the Madeira Abyssal Plain (MAP), which contained 1 to 2% organic carbon homogeneously distributed throughout the turbidites at the time they were deposited. These turbidites are well suited to study the effects of oxic degradation on lipid biomarkers without the complicating influence of varying organic matter sources, sedimentation rates, or bioturbation. One sample from the oxidised turbidite was compared with two samples from the unoxidised part of each turbidite. Postdepositional oxic degradation decreased concentrations of biomarkers by several orders of magnitude. The ester-bound lipids were degraded to a far lesser extent than their free counterparts were. The extent of degradation of different compounds differed substantially. Within a specific class of biomarkers, degradation also took place to a different extent, altering their distributions. This study shows that oxic degradation of the organic matter may have a profound effect on the biomarker fingerprint and may result in a severe bias in, for example, the interpretation of organic matter sources and the estimation of the palaeoproductivity of specific groups of phytoplankton. 相似文献
27.
The potential for rapid coastline modification in the face of sea-level rise or other stressors is alarming, since coasts are often densely populated and support valuable infrastructure. In addition to coastal submergence, nutrient-related water pollution is a growing concern for coastal wetlands. Previous studies found that the Suspended Sediment Concentration (SSC) of coastal wetlands acts as a first-order control of their sustainability, but SSC dynamics are poorly understood. Our study focuses on the Virginia Coast Reserve (VCR) Long Term Ecological Research (LTER) site, a shallow multiple tidal inlet system in the USA. We apply numerical modelling (Delft3D-SWAN) and subsequent analyses to determine SSC dynamics within the VCR. In particular, we consider two important controls on SSC in the system: vegetation (seagrass and salt marsh) and offshore waves. Our results show that vegetation colonies and increased wave energy lengthen water residence time. The reduction in the tidal prism decreases SSC export from the bay via tidal inlets, leading to increased sediment retention in the bay. We found that alongshore currents can enhance lagoon SSC by importing fine sediments from an adjacent inlet along the coastline. Our numerical experiments on vegetation seasonality can improve the understanding of wave climate impact on coastal bay sediment budget. Offshore waves increase sediment export from coastal bays, particularly during winter seasons with low vegetation density. Therefore, our study can help managers and stakeholders to understand how to implement restoration strategies for the VCR. © 2020 John Wiley & Sons, Ltd. 相似文献
28.
Zorigt Munkhtsetseg Myagmar Khulan Orkhonselenge Alexander van Beek Eelco Kwadijk Jaap Tsogtbayar Jargaltulga Yamkhin Jambaljav Dechinlkhundev Dorjsuren 《Environmental Earth Sciences》2020,79(12):1-1
The Editors-in-Chief of Environmental Earth Sciences are issuing an editorial expression of concern to alert readers that this article. 相似文献
29.
Vassilis Karakitsios Harilaos Tsikos Yvonne van Breugel Lyda Koletti Jaap S. Sinninghe Damsté Hugh C. Jenkyns 《International Journal of Earth Sciences》2007,96(2):343-352
Integrated biostratigraphic (planktonic foraminifera, calcareous nannofossils), chemostratigraphic (bulk C and O isotopes)
and compound-specific organic geochemical studies of a mid-Cretaceous pelagic carbonate—black shale succession of the Ionian
Zone (western Greece), provide the first evidence for the Cenomanian–Turonian oceanic anoxic event (OAE2, ‘Bonarelli’ event)
in mainland Greece. The event is manifested by the occurrence of a relatively thin (35 cm), yet exceptionally organic carbon-rich
(44.5 wt% TOC), carbonate-free black shale, near the Cenomanian–Turonian boundary within the Vigla limestone formation (Berriasian–Turonian).
Compared to the ‘Bonarelli’ black-shale interval from the type locality of OAE2 in Marche–Umbria, Italy, this black shale
exhibits greatly reduced stratigraphic thickness, coupled with a considerable relative enrichment in TOC. Isotopically, enriched
δ13C values for both bulk organic matter (−22.2‰) and specific organic compounds are up to 5‰ higher than those of underlying
organic-rich strata of the Aptian-lower Albian Vigla Shale member, and thus compare very well with similar values of Cenomanian–Turonian
black shale occurrences elsewhere. The relative predominance of bacterial hopanoids in the saturated, apolar lipid fraction
of the OAE2 black shale of the Ionian Zone supports recent findings suggesting the abundance of N2-fixing cyanobacteria in Cretaceous oceans during the Cenomanian–Turonian and early Aptian oceanic anoxic events. 相似文献
30.
Bioerosion by Cliona delitrix and Cliona lampa was assessed at 43 sites along the Florida Reef Tract, USA, in the summer of 2001. Sponge abundances were estimated using rapid visual assessment. Tissue samples of sponges were taken for analysis of delta15N. Comparison samples were taken from Belize. Annual trends in sponge abundance were estimated from archived videos covering the period from 1996 to 2001. Sites with the greatest boring sponge size and cover were in the Backcountry and Lower Keys, where total nitrogen, ammonium, and delta15N levels were highest. The sites with the largest relative increase of C. delitrix and C. lampa over the 5 year period were in the Upper Keys, where the greatest relative decline in stony coral cover has occurred. Florida sponge delta15N values were 5.2(+/-0.1)%, suggesting the influence of human waste; in comparison, offshore Belize samples were 2.1(+/-0.1)%. These results suggest sewage contamination of the Florida Reef Tract, shifting the carbonate balance from construction to destruction. 相似文献