Hydrological system analysis and modelling of the Kara River basin (West Africa) using a lumped metric conceptual model

This paper discusses the analysis and modelling of the hydrological system of the basin of the Kara River, a transboundary river in Togo and Benin, as a necessary step towards sustainable water resources management. The methodological approach integrates the use of discharge parameters, flow duration curves and the lumped conceptual model IHACRES. A Sobol sensitivity analysis is performed and the model is calibrated by applying the shuffled complex evolution algorithm. Results show that discharge generation in three nested catchments of the basin is affected by landscape physical characteristics. The IHACRES model adequately simulates the rainfall–runoff dynamics in the basin with a mean modified Nash-Sutcliffe efficiency measure of 0.6. Modelling results indicate that parameters controlling rainfall transformation to effective rainfall are more sensitive than those routing the streamflow. This study provides insights into understanding the catchment’s hydrological system. Nevertheless, further investigations are required to better understand detailed runoff generation processes.

EDITOR M.C. Acreman; ASSOCIATE EDITOR N Verhoest     

Identification of maars and similar volcanic landforms in the West Eifel Volcanic Field through image processing of DTM data: efficiency of different methods depending on preservation state

The West Eifel Volcanic Field comprises 98 maars, tuff rings, and scoria rings of volcanoes younger than 700 ka. Digital Terrain Models (DTMs) allow to automatically measure morphologic parameters of volcanic edifices such as slope angles, diameters, elevations, floor, and slope surface areas. Based on their morphological characteristics, we subdivided the West Eifel volcanoes into five morphometric groups which reflect different stages of erosion. Group I, II, and IV comprise clear ring-shaped structures. The difference between these groups is that a tephra ring is well preserved in Group I, partially preserved in Group II and absent in Group IV. The original shapes of Group III maars have been lost more substantially than in Groups I, II, or IV, but they nevertheless retain a negative shape (a depression) and have characteristic channel systems, which can be used as search criteria. Maar-diatremes of Group V are eroded down to their feeder pipes and form hills. In order to locate potential volcanic depressions that are likely to be maar volcanoes, we defined common search criteria such as circular negative landforms or particular drainage system patterns for all groups except the least well-preserved Group V. These criteria were taken as the basis for further processing of the DTM data. The first processing step consisted of constructing a residual relief calculated as the difference between a filtered (smoothed) topographic surface and the original DTM data. This identifies local topographic features. We propose a method for regulating the degree of smoothing which is based on filtering of local maxima according to their distance from a surface constructed from local minima. The previously defined search criteria for Groups I to IV such as specific ranges of curvature, slope, circularity, density of the drainage network were then applied to the residual relief in order to extract maar shapes. Not all criteria work equally well for all morphological groups. Combinations of multiple search criteria therefore yield the best results and efficiently identify most known maars. They also separate some probable new, hitherto unrecognized maars from a large number of other local depressions. We also compared the erosional state of maars to their absolute ages. Published estimates of erosion rates for maars in the French Massif Central suggest a general trend of erosion rates decreasing with time elapsed since eruption. However, this cannot explain the strongly varying ages for maars of the same morphometric group (i.e., similar preservation state) in the West Eifel Volcanic Field. The spatial distribution of the morphometric groups shows some regularity. For example, strongly eroded maars are concentrated in the Gerolstein area (where maar density is highest), whereas most well-preserved maars are located east of the Eifel North–South Depression (ENSD). Most maars affected by fluvial erosion lie near the Kyll and Kleine Kyll streams. These observations suggest differential recent uplift of the West Eifel Volcanic Field, with stronger uplift occurring west of the ENSD.     

Light curve and O−C diagram analysis of RZ Cassiopeiae

The aim of the present paper is to analyze the light variation as well as the period changes of the eclipsing binary RZ Cas. New photometric elements are computed using the frequency-domain method. The possibility of the light-time effect and the apsidal motion is discussed.     

1958～2018年永定河流域蒸发皿蒸发量的变化特征及其影响因子分析

基于永定河流域1958～2018年14个气象站的逐日观测数据,采用气候倾向率、Mann–Kendall趋势检验法分析蒸发皿蒸发量时空变化特征,并通过完全相关系数和多元回归分析识别气候因子与蒸发量的相关程度并定量计算其贡献率.结果表明:在全球气候变暖的背景下,60年来永定河流域气温以0.29°C/10 a的速率上升,而蒸...     

Platinum-group element distribution in base-metal sulfides of the Merensky Reef from the eastern and western Bushveld Complex, South Africa

Base-metal sulfides in magmatic Ni-Cu-PGE deposits are important carriers of platinum-group elements (PGE). The distribution and concentrations of PGE in pentlandite, pyrrhotite, chalcopyrite, and pyrite were determined in samples from the mineralized portion of four Merensky Reef intersections from the eastern and western Bushveld Complex. Electron microprobe analysis was used for major elements, and in situ laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) for trace elements (PGE, Ag, and Au). Whole rock trace element analyses were performed on representative samples to obtain mineralogical balances. In Merensky Reef samples from the western Bushveld, both Pt and Pd are mainly concentrated in the upper chromitite stringer and its immediate vicinity. Samples from the eastern Bushveld reveal more complex distribution patterns. In situ LA-ICP-MS analyses of PGE in sulfides reveal that pentlandite carries distinctly elevated PGE contents, whereas pyrrhotite and chalcopyrite only contain very low PGE concentrations. Pentlandite is the principal host of Pd and Rh in the ores. Palladium and Rh concentrations in pentlandite reach up to 700 and 130 ppm, respectively, in the samples from the eastern Bushveld, and up to 1,750 ppm Pd and up to 1,000 ppm Rh in samples from the western Bushveld. Only traces of Pt are present in the base-metal sulfides (BMS). Pyrrhotite contains significant though generally low amounts of Ru, Os, and Ir, but hardly any Pd or Rh. Chalcopyrite contains most of the Ag but carries only extremely low PGE concentrations. Mass balance calculations performed on the Merensky Reef samples reveal that in general, pentlandite in the feldspathic pyroxenite and the pegmatoidal feldspathic pyroxenite hosts up to 100 % of the Pd and Rh and smaller amounts (10–40 %) of the Os, Ir, and Ru. Chalcopyrite and pyrrhotite usually contain less than 10 % of the whole rock PGE. The remaining PGE concentrations, and especially most of the Pt (up to 100 %), are present in the form of discrete platinum-group minerals such as cooperite/braggite, sperrylite, moncheite, and isoferroplatinum. Distribution patterns of whole rock Cu, Ni, and S versus whole rock Pd and Pt show commonly distinct offsets. The general sequence of “offset patterns” of PGE and BMS maxima, in the order from bottom to top, is Pd in pentlandite?→?Pd in whole rock?→?(Cu, Ni, and S). The relationship is not that straightforward in general; some of the reef sequences studied only partially show similar trends or are more complex. In general, however, the highest Pd concentrations in pentlandite appear to be related to the earliest, volumetrically rather small sulfide liquids at the base of the Merensky Reef sequence. A possible explanation for the offset patterns may be Rayleigh fractionation.     

序贯一维型边缘检测新算法

本文提出一种既可用于从图象上提取具有某种用途的一维边缘,又可用于提取具有多种用途的二维边缘的序贯一维型边缘检测新算法。由于构成该算法重要组成部分的基础算子的作用,以及将二维问题化为一维问题求解而使其明显具有简单,快速、有效的特点。该算法还具有Abdou ^[1] 等所建议的边缘检测算子应具有的两个特性。     

The impact of hydrological changes on travertine deposits related to thermal springs in the Pamukkale area (SW Turkey)

Pamukkale thermal waters (35 °C), exhibiting calcium-bicarbonate-sulfate composition and high carbon dioxide concentration, are of a predominantly meteoric origin. The meteoric fluid, circulating through faults and fractures, is heated by magmatic intrusions at great depth, and ascends from deep reservoirs to the surface. Mixing with relatively cold groundwater in the near surface zone promotes different saturation conditions with respect to calcium carbonate that later precipitates at depth and/or the surface. Dissolution-deposition processes of calcium carbonate both at surface and depth environments may help to reconstruct past climate direction in the field. During wet climate conditions a high-rate of calcium carbonate accumulation would be expected to occur at the surface because thermal fluid would be under-saturated with respect to calcium carbonate at depth because of a relatively higher mixing ratio with cold groundwater. During dry climate conditions the thermal fluid would be super-saturated at depth because of the highly acidic environment. Hydrometeorological studies reveal that the annual precipitation at the Pamukkale hydrothermal field tends to decrease with time. This climatic change in the area was also detected from geological records. While humid climate conditions prevailed during the late Quaternary, the area has recently been affected by arid/semi-arid climate conditions, followed by some episodic transitions. This study has shown how the system has possibly reacted to different climate conditions since antiquity.     

Geochemistry of Pliocene/Pleistocene basalts along the Central Anatolian Fault Zone (CAFZ), Turkey

Abstract

Pliocene-Pleistocene volcanism accompanied strike-slip-related transtensional deformation along the K?z?l?rmak fault segment of the Central Anatolian fault zone (CAFZ) in the west of ?ark??la (Sivas-central Turkey). These volcanic rocks are represented by alkali olivine basalts. They can be divided into four different sub-groups on the basis of their Zr, Nb, TiO₂ contents. A primitive mantle-normalized incompatible trace element diagram for four subgroups shows close similarity to typical OIB pattern. Some of the incompatible trace element ratios (Ce/Y, Zr/Nb, La/Ba, La/Nb) are also akin to OIB values. Highly fractionated REE patterns (La/Yb_N=24.7–9.2) with no Eu anomaly are the main features of the alkali basalts and are comparable to alkaline volcanism in continental rift zones. On the basis of Al₂O₃/TiO₂, Nb/Y, Zr/Y Zr/Nb ratios, the geochemical differences among four sub-groups can be explained by variable degrees of partial melting of compositionally similar mantle source. Th/Nb, Th/Y, Nb/Y ratios and the primitive mantle-normalized trace element diagram suggests significant amount of crustal involvement for most of the alkali olivine basalts erupted along the CAFZ. Rupture of the continental lithosphere by strike-slip-related transtensional deformation might have caused decompressional partial melting of the asthenospheric mantle and generating alkali olivine basalts in this region. © 2001 Éditions scientifiques et médicales Elsevier SAS.     

Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in sediments from Hong Kong

Concentrations of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were determined in 14 sediment samples collected from four sites in the Mai Po Marshes Nature Reserve (within a RAMSAR Site) and from another six sites in Victoria Harbour and along the Hong Kong coastline. Elevated levels of PCDDs, and particularly OCDD, were detectable in all samples collected from the Mai Po Marshes and five of the six sites. In contrast to PCDDs, PCDFs were mainly found in sediment samples collected from industrial areas (Kwun Tong and To Kwa Wan) in Victoria Harbour. PCDD/F levels and congener profiles in the samples from the Mai Po Marshes Nature Reserve in particular show strong similarities to those reported in studies which have attributed similar elevated PCDD concentrations to nonanthropogenic PCDD sources.