Carbon flux in the northwest Mediterranean estimated from microbial production

Spring profiles of microbial production derived from the dark incorporation of tritiated leucine and tritiated thymidine in the northwest Mediterranean show an exponential decline with depth. Assuming this to represent a steady-state balance between microbial respiration and the downward flux of carbon, the downward flux is estimated as (1−/)p/b, where p is the microbial production, their gross growth efficiency and b the coefficient of exponential decline with depth. Summer profiles, ranging over about 3° of latitude and 4° of longitude, were well fitted by a two-component exponential decline, suggesting two distinct microbial substrates. Values of b for the more rapidly declining component varied between 0.01 and 0.06 m⁻¹ according to location. In the case of the slower component, b was estimated as 0.002 m⁻¹, and did not vary significantly over the region. Estimated fluxes of carbon at the surface are 123–335 mg m⁻² d⁻¹ for the fast and 95 mg m⁻² d⁻¹ for the slow component. Below about 200 m, carbon flux is dominated by the slow component. Flux estimates are compatible with flux estimates from sediment traps in the same region. The observed changes between the spring and summer profiles, combined with the horizontal homogeneity of the summer profiles below 200 m, are consistent with a downward transport of about 5–10 m d^–1, implying a significant dispersive component to the observed fluxes.     

Black material on mineral inclusions and in internal fracture planes in diamond

The black material observed on the surface of crystalline inclusions in diamond and also in adjacent internal fracture planes has been classified as a result of a preliminary examination of several hundred diamonds from Sierra Leone, Ghana, and South Africa (particularly the Premier Mine), as well as diamond slices of unknown origin, followed by a detailed examination of some 100 diamonds. X-ray, electron diffraction, and qualitative electron microprobe techniques were used in identifying this material as graphite, pyrrhotite and pentlandite. The possible origins of these minerals are discussed.     

Origins of strandline duricrusts around the Makgadikgadi Pans (Botswana Kalahari) as deduced from their chemical and isotope composition

Trace elements together with some O and C isotope analysis were undertaken on duricrust strandline deposits in the palaeo-Makgadikgadi sub-basin (PMSB) to provide insight into palaeo-climatic conditions through the interpretation of calcrete, silcrete–calcrete intergrade and silcrete deposits. Trace element content and relative abundance suggest that the duricrust origins are associated with the long-term weathering of the Karoo Large Igneous Province which underlies the PMSB. This work shows that duricrust origins are related to Ca²⁺ and Si (and associated trace elements) being transported mainly through the groundwater and then subsequently precipitated at different strandline elevations over time. Local groundwater feeding in towards the pan margin and accumulating in near-neutral pan-marginal pools, appears to facilitate Si concentration and permeation of pre-existing calcretes. The silica precipitates as the pH drops when renewed freshwater enters the pools. Hence the inferred palaeo-climatic regime for silcretisation may be similar to that occurring in Botswana at present being dry semi-arid with low seasonal rainfall. In contrast the extensive calcrete precipitation in the strandlines results from abundant Ca²⁺ in adjacent waters which appear to be derived from both local and regional sources. The arrival of Ca²⁺ from regional sources (shown by trace element evidence) infers heavy rainfall in the upper catchment suggesting a major humid event followed by regional drying. Palaeo-climatic inferences suggest the juxtaposition of major humid events interspersed with more normal semi-arid palaeo-climates with an exception obtained from isotope data, of drier and cooler conditions than usual for the region around 80–90 000 years ago. Whereas trace element data can greatly assist in the interpretation of complex deposits such as duricrusts, care should be taken over the use of particular ratios (such as Yb/Gd ratio) which may produce spurious results.     

The changing morphology of an open lava channel on Mt. Etna

An open channel lava flow on Mt. Etna (Sicily) was observed during May 30–31, 2001. Data collected using a forward looking infrared (FLIR) thermal camera and a Minolta-Land Cyclops 300 thermal infrared thermometer showed that the bulk volume flux of lava flowing in the channel varied greatly over time. Cyclic changes in the channel's volumetric flow rate occurred over several hours, with cycle durations of 113–190 min, and discharges peaking at 0.7 m³ s⁻¹ and waning to 0.1 m³ s⁻¹. Each cycle was characterized by a relatively short, high-volume flux phase during which a pulse of lava, with a well-defined flow front, would propagate down-channel, followed by a period of waning flow during which volume flux lowered. Pulses involved lava moving at relatively high velocities (up to 0.29 m s⁻¹) and were related to some change in the flow conditions occurring up-channel, possibly at the vent. They implied either a change in the dense rock effusion rate at the source vent and/or cyclic-variation in the vesicle content of the lava changing its bulk volume flux. Pulses would generally overspill the channel to emplace pāhoehoe overflows. During periods of waning flow, velocities fell to 0.05 m s^–1. Blockages forming during such phases caused lava to back up. Occasionally backup resulted in overflows of slow moving ‘a‘ā that would advance a few tens of meters down the levee flank. Compound levees were thus a symptom of unsteady flow, where overflow levees were emplaced as relatively fast moving pāhoehoe sheets during pulses, and as slow-moving ‘a‘ā units during backup. Small, localized fluctuations in channel volume flux also occurred on timescales of minutes. Volumes of lava backed up behind blockages that formed at constrictions in the channel. Blockage collapse and/or enhanced flow under/around the blockage would then feed short-lived, wave-like, down-channel surges. Real fluctuations in channel volume flux, due to pulses and surges, can lead to significant errors in effusion rate calculations. Editorial responsibility: A. Woods     

Multiphase models of flotation machine behaviour

Models in which the cell contents are partitioned into distinct pulp and froth phases are reviewed critically. The nature of the mixing within the phases is discussed. Multiphase models describing froth column concentration gradients and pulp residence time effects are mentioned. It is shown that at steady state multiphase models can be reduced to the two-phase case. Deficiencies in the models and topics requiring further development are outlined.     

Stable isotope and fluid inclusion evidence for the origin of the Brandberg West area Sn–W vein deposits, NW Namibia

The Brandberg West region of NW Namibia is dominated by poly-deformed turbidites and carbonate rocks of the Neoproterozoic Damara Supergoup, which have been regionally metamorphosed to greenschist facies and thermally metamorphosed up to mid-amphibolite facies by Neoproterozoic granite plutons. The meta-sedimentary rocks host Damaran-age hydrothermal quartz vein-hosted Sn–W mineralization at Brandberg West and numerous nearby smaller deposits. Fluid inclusion microthermometric studies of the vein quartz suggests that the ore-forming fluids at the Brandberg West mine were CO₂-bearing aqueous fluids represented by the NaCl–CaCl₂–H₂O–CO₂ system with moderate salinity (mean=8.6 wt% NaCl_equivalent).Temperatures determined using oxygen isotope thermometry are 415–521°C (quartz–muscovite), 392–447°C (quartz–cassiterite), and 444–490°C (quartz–hematite). At Brandberg West, the oxygen isotope ratios of quartz veins and siliciclastic host rocks in the mineralized area are lower than those in the rocks and veins of the surrounding areas suggesting that pervasive fluid–rock interaction occurred during mineralization. The O- and H-isotope data of quartz–muscovite veins and fluid inclusions indicate that the ore fluids were dominantly of magmatic origin, implying that mineralization occurred above a shallow granite pluton. Simple mass balance calculations suggest water/rock ratios of 1.88 (closed system) and 1.01 (open system). The CO₂ component of the fluid inclusions had similar δ ¹³C to the carbonate rocks intercalated with the turbidites. It is most likely that mineralization at Brandberg West was caused by a combination of an impermeable marble barrier and interaction of the fluids with the marble. The minor deposits in the area have quartz veins with higher δ ¹⁸O values, which is consistent with these deposits being similar geological environments exposed at higher erosion levels.     

Thermal, seismic and infrasonic evidences of variable degassing rates at Stromboli volcano

During June 1999, we measured the amplitude and rate (number of events per second) at which gas exited the vent at Stromboli volcano as discrete gas bursts or puffs. This allowed us to identify two styles of gas burst (puffing) activity. The first is characterized by frequent, rapidly rising puffs, the second by less frequent, slowly rising puffs. Each style persisted over 5–40-min-long durations and was associated with a high and low number of strombolian explosions per hour, respectively. Each period was also associated with characteristic delay times between the arrival of the infrasonic and thermal signals during strombolian explosions; the delays were longer during vigorous puffing periods. To explain our observations, we propose a model in which the degassing process cycles between vigorous and weak degassing phases. During vigorous degassing phases, bubble layers ascend the conduit at a frequency of 0.5–1.0 s⁻¹. This high degassing level reflects a gas-rich magma column and leads to an increased rate in the formation of shallow foams and, hence, an increase in puffing and explosive activity, as well as a higher free surface level and/or gas jet velocity. During weak phases, bubble layers ascend the conduit at a reduced frequency of 0.2–0.3 s⁻¹. During such times the magma column is poor in gas. This leads to a decreased rate of foam layer formation and hence a reduction in puffing and explosive activity, as well as a lower free surface level and/or gas jet velocity. Variations in puffing activity can thus be used to track changes in the rate at which the shallow system is supplied by fresh, gas-rich magma. Our observations indicate that the two degassing styles last from 5 to 40 min and that the switch from one to the other occurs over a matter of minutes.     

Stable isotope and C study of biogenic calcrete in a termite mound, Western Cape, South Africa, and its palaeoenvironmental significance

Late Quaternary terrestrial climate records from the semi-arid zone of the Western Cape of South Africa are rare. However, palaeoenvironmental information may be inferred from ancient termite mounds of the region. Calcrete lenses in these mounds have δ¹³C and δ¹⁸O values that show systematic changes with radiocarbon dates, which range from 33,629–36,709 to 21,676–23,256 cal yr BP. These dates confirm that these heuweltjies had been present in the landscape since the last glacial period. The decrease in δ¹³C and δ¹⁸O from 33,629–36,709 to 21,676–23,256 cal yr BP indicates that climate information is recorded by the calcretes. It is suggested that a progressive decline in air temperature and an increase in moisture availability, and a decline in abundance of C₄ or CAM plants, occurred in the region during the time heuweltjie calcite precipitated.     

The spatial structure of local surficial sediment characteristics on Georges Bank,USA

Georges Bank is one of the world’s most productive marine ecosystems, but the lack of accurate broad-scale sediment maps presently limits habitat assessments and spatial fisheries management. From 1999 to 2009 we surveyed 36,669 km² of Georges Bank using 2.8 and 0.6 m² quadrats viewed with live underwater video (video quadrats). The sediment types observed in 61,604 quadrats were used to map and evaluate spatial structure of local surficial sediment coarseness, dominance, heterogeneity, and maximum size characteristics at a 1 km² spatial resolution. Sand dominated sediment covered 62% of the study area, and there was a logarithmic decline in coverage by larger, coarser and more heterogeneous sediments. Gravel dominated sediments covered 38% of the study area and were more than twice as abundant as previously estimated. A 12,890 km² swath of gravel dominated seabed stretched from Cape Cod to northeastern Georges Bank consistent with estimates of prehistoric glacial extent. Within the swath there were 14 large gravel outcrops (15–2743 km²) . This work increases the spatial resolution of sediment information available for habitat assessments and spatial fisheries management on Georges Bank by two orders of magnitude. The four sediment characteristics we evaluated support further detailed investigations of the Bank’s benthos, including the influences of surficial sediment characteristics on species and community distributions, and more spatially accurate estimates of seabed roughness. Finally, this work demonstrates the use of video quadrats as an alternative to traditional grab sampling and modern acoustic sampling for continental shelf-scale mapping.     

Characteristics of southern California atmospheric rivers

Theoretical and Applied Climatology - Atmospheric rivers (ARs) are channels of high water vapor flux that transport moisture from low to higher latitudes on synoptic timescales. In areas of...