Cs and Cl NMR spectroscopy and molecular dynamics modeling of Cs and Cl complexation with natural organic matter

Interaction of dissolved aqueous species with natural organic matter (NOM) is thought to be important in sequestering some species and enhancing the transport of others, but little is known about these interactions on a molecular scale. This paper describes a combined experimental ¹³³Cs and ³⁵Cl nuclear magnetic resonance (NMR) and computational molecular dynamics (MD) modeling study of the interaction of Cs⁺ and Cl⁻ with Suwannee River NOM. The results provide a detailed picture of the molecular-scale structure and dynamics of these interactions. Individual NOM molecules are typically hundreds to thousands of Daltons in weight, and on the molecular scale their interaction with small dissolved species can be investigated in ways similar to those used to study the interaction of dissolved aqueous species with mineral surfaces. As for such surface interactions, understanding both the structural environments and the dynamics over a wide range of frequencies is essential. The NMR results show that Cs⁺ is associated with NOM at pH values from 3.4 ± 0.5 (unbuffered Suwannee River NOM solution) to 9.0 ± 0.5. The extent of interaction increases with decreasing CsCl concentration at constant pH. It also decreases with increasing pH at constant CsCl concentration due to pH-dependent negative structural charge development on the NOM caused by progressive deprotonation of carboxylic and phenolic groups. The presence of NOM has little effect on the ¹³³Cs chemical shifts, demonstrating that its local coordination environment does not change significantly due to interaction with the NOM. Narrow, solution-like line widths indicate rapid exchange of Cs⁺ between the NOM and bulk solution at frequencies of >10² Hz. The MD simulations support these results and show that Cs⁺ is associated with the NOM principally as outer sphere complexes and that this interaction does not reduce the Cs⁺ diffusion coefficient sufficiently to cause NMR line broadening. The ³⁵Cl NMR data and the MD results are consistent in demonstrating that there is no significant complexation between Cl⁻ and NOM in the pH range investigated, consistent with negative structural charge on the NOM.     

欧亚大陆春季植被对同年中国西北夏季大气环流和气候的影响研究

利用1982—2006年欧亚大陆月归一化植被指数（NDVI）,NCAR/NCEP月高度场和风场以及中国西北地区248个气象台站的逐日降水、温度资料,通过SVD及合成分析等方法,分析了欧亚大陆春季植被同同年中国西北夏季大气环流乃至干湿特征的关系.结果表明：欧亚大陆春季植被覆盖状况对预测我国西北地区同年夏季的干湿特征具有较...     

南秦岭西乡—石泉地区三花石群白勉峡组中泥盆世孢子化石的发现及其地层意义

陕西汉南三花石群和西乡群的时代仍存很大争议。在陕西西乡地区三花石群白勉峡组灰色、灰黑色砂板岩中发现较丰富并具有时代特征的陆生植物孢子（spores）22属,40余种。其化石组合大致可与中国华南、西南和西秦岭中泥盆世孢子带比较,亦可以与欧洲、北美老红砂岩大陆及其邻区中泥盆世早期孢子带比较,时代为中泥盆世,并可能为中泥盆世早期,大致相当于西欧中泥盆世早期艾菲尔期。     

中国珠宝教育三十年

以中国珠宝教育三十年的发展历史为研究对象,以珠宝教育的发展时序为研究线索,以标志性的发展事件为研究依据,采用多方聆听亲历者讲述,结合文献与事件的考证,力求真实地还原中国珠宝教育过往的三十年历史。并在此基础上,提出了中国珠宝教育经历的三个主要发展阶段,即：社会通力共建的开创期,机构承担教育功能的成型期,构建专业学科的成熟期,并详细地论述了各个阶段的文化背景、发生环境、组织参与和重要成就。与此同时,就每个阶段人才需求、培养方式、教学内容、组织形式等的变化动因进行了具体分析。最后对进入发展期的中国珠宝教育所面临的五个方面的挑战做出了具体的阐述。     

测定锰矿石中低含量钒的试验

化学分析工作要求测试快速、准确,低含量钒的测定因流程长,操作复杂,不易掌握,影响了推广使用。该试验采用分光光度法针对锰矿石中钒的测定进行了改进,取得了良好的效果。该法采用过氧化钠-碳酸钠熔融、水浸取,吸取清液依次加入硝酸、磷酸、钨酸钠溶液生成可溶性的黄色磷钨钒酸络合物,测量其吸光度,大大提高了分析效率。     

Climatic regime shift and decadal anomalous events in China

Climatic time series from historical documents and instrumental records from China showed temporal and regional patterns in the last two to three centuries, including two multidecadal oscillations at quasi-20-year and quasi-70-year timescales revealed by signal analysis from wavelet transform. Climatic anomalous events on the decadal timescale were identified based on the two oscillations when their positive (or negative) phases coincide with each other to amplify amplitude. The coldest event occurred in the decade of 1965–1975 in eastern China, while the periods of 1920–1930, 1940–1950, and 1988–2000 appeared to be warmer in most parts of China. For the precipitation series in northern China, the dry anomalous event was found in the late 1920s, while the wet anomalous event occurred in the 1950s. A severe drought in 1927–1929 in northern China coincided with the anomalous warm and dry decade, caused large-scale famine in nine provinces over northern China. Climatic anomalous events with a warm-dry or cold-wet association in the physical climate system would potentially cause severe negative impacts on natural ecosystem in the key vulnerable region over northern China. The spatial pattern of summer rainfall anomalies in the eastern China monsoon region showed an opposite variations in phase between the Yellow River Valley (North China) and the mid-low Yangtze River Valley as well as accompanied the shift of the northernmost monsoon boundary. Climatic regime shifts for different time points in the last 200 years were identified. In North China, transitions from dry to wet periods occurred around 1800, 1875, and 1940 while the transitions from wet to dry periods appeared around 1840, 1910, and the late 1970s. The reversal transition in these time points can also be found in the lower Yangtze River. Climatic regime shifts in China were linked to the interaction of mid- and low latitude atmospheric circulations (the westerly flow and the monsoon flow) when they cross the Tibetan Plateau in East Asia.     

巴楚-伽师6.8级地震地质灾害及未来地震地质灾害

2003年2月24日新疆巴楚—伽师交界地区发生了MS6.8地震。地震的发生除了对建筑物及构筑物与水利、交通、电力、电信设施造成了不同程度的破坏外,在地震烈度Ⅶ度以上(包括Ⅶ度)地区产生了不同程度的地震地质灾害。地震地质灾害主要为场地砂土液化、地裂缝与河流陡岸滑塌等类型。随后在新疆巴楚—伽师6.8级地震灾区开展了地震小区划工作,对Ⅶ、Ⅷ、Ⅸ度区进行了场地工程地质条件勘测与综合评价,判定该地区未来可能产生的主要地震地质灾害为场地砂土液化、河流陡岸滑塌。     

锢囚气旋钩状云区暴雪过程的水汽源地及输送分析

利用常规高空、地面观测资料、FY-2E卫星云图和NCEP再分析场,分析了2013年11月25日发生在中国东北东部的暴雪天气过程,并用HYSPLIT模式模拟了暴雪区上空气块的轨迹。结果表明:卫星云图显示暴雪发生在锢囚气旋的钩状云区中,且具有中尺度特征。钩状云区不同代表点、不同层次25日08时120 h气块的后向轨迹计算结果表明,在每个代表点的6条轨迹中,只有1条轨迹来自新疆以西地区的对流层上层,其他5条轨迹均来自蒙古国或我国北方地区的对流层中低层。几乎每条轨迹对应的气块在东移或南移时先以水平运动为主,伴有弱的下沉;中低层气块在72～24 h经过渤海湾和日本海;而中上层气块则主要经过黄海或东海,到达降雪区前几小时气块移速快并有明显的上升运动。对钩状云区不同代表点1500和3000 m上空120 h后向轨迹中气块湿度分析表明,来自东亚大陆的气块水汽含量并不大、相对湿度也小于60%,但在经过渤海湾和日本海时,海气交换使得气块的含水量和相对湿度均呈增加的趋势;特别是气块途径日本海的时间和距离越长,水汽含量越多。因此暴雪区的水汽主要来自日本海,其次是渤海湾。在降雪发生前几小时,气块随偏南风或东南风快速北移,相对湿度接近饱和并伴有上升运动,从而引起降雪。     

海盐气溶胶影响酸碱气体及无机盐气溶胶的敏感性试验

利用热力学平衡模式ISORROPIA及与之耦合的气相化学模式,通过两类敏感性试验,探讨了海盐气溶胶、相对湿度、温度对3种无机盐（硫酸盐、硝酸盐、铵盐,包括液态和固态）和3种酸碱气体（氨气、气态硝酸、氯化氢）浓度的影响,以及不同海盐气溶胶浓度对热力学平衡的影响。试验结果表明,海盐浓度相对较低、相对湿度达到0．4～0．5以上、温度在-10～15℃之间时对各物种的平衡浓度影响比较显著。温度升高抑制硝酸盐、铵盐的生成,同时引起气态硝酸、氨气和氯化氢浓度的增加。而湿度升高时对硝酸盐、铵盐的生成有促进作用,反而造成气态硝酸、氨气和氯化氢浓度的降低。海盐气溶胶、相对湿度及温度的变化对硫酸盐气溶胶没有影响。在热力学平衡中如果考虑海盐气溶胶（主要成分NaGl）的作用会使得硝酸盐气溶胶、氨气浓度增加,而硝酸气体、铵盐气溶胶浓度减小,其中硝酸盐和气态硝酸的改变最为明显。由于海盐气溶胶和硫酸、硝酸的反应,产生了氯化氢气体,造成海盐气溶胶的氯亏损现象。     

一种基于微博语义的天气情感地图设计

天气情感地图是一种表达情感相关的专题地图。本文提出了一种基于微博语义的天气情感地图设计方法,基于程序获取了合肥市区2016年6月20日至2016年7月10日暴雨期间带有地理位置的新浪微博数据,通过数据清洗及标准化处理,利用情感词库,结合人工判读,将暴雨天气过程相关情感微博文本数据分为8种情感类别,设计了8种情感着色,结合GIS格网技术与核密度分析方法,制成暴雨天气过程前、中后期情感地图,并分析了暴雨天气过程3个阶段中微博用户多维情感变化。该研究可为政府相关部门在突发性天气灾害过程中制定救助与决策提供参考。