内蒙古巴林右旗晚二叠世埃达克质火山岩特征及其地质意义

内蒙古东南部巴林右旗地区发育晚二叠世埃达克质火山岩,岩石组合为安山岩、粗安岩、英安岩及辉石安山岩,其LA-ICP-MS锆石U-Pb测年结果为256.7±2.7Ma,指示其形成于晚二叠世。地球化学特征显示,该套火山岩属准铝质-弱铝质中钾钙碱性岩石系列,具富Si(SiO_256%)、高Al(Al_2O_315%)、富Na、贫K、高Sr、低Yb和Y等特征,Na_2O/K_2O值为2.33~3.90,Mg~#值为35.3~60.8;稀土元素总量为96.69×10~(-6)~192.4×10~(-6)、轻重稀土元素分馏较明显((La/Yb)_N值为6.27~13.82),具正的Eu(δEu=1~1.67)异常,在原始地幔标准化蛛网图中,富集大离子亲石元素Rb、Ba、U,亏损高场强元素Nb、Ta,为O型(大洋型)埃达克质火山岩地球化学特征。综合区域资料,巴林右旗埃达克质火山岩是残留在地幔中的古亚洲洋残余洋壳部分熔融并受到地幔橄榄岩混染形成的,暗示晚二叠世存在古亚洲洋向华北板块俯冲消亡事件。     

Transport behavior of nZnO in geosynthetic clay liner used in municipal solid waste landfills under temperature effect

The transport process of nZnO in geosynthetic clay liner (GCL), an anti-seepage material used in municipal solid waste (MSW) landfills, under different seepage temperature conditions was conducted. The transport behavior of nZnO in GCL was analyzed. Results showed that the retardation performance of current GCL used in MSW landfills anti-seepage system against nZnO pollutants was poor. nZnO successfully permeated the GCL and entered external soil–groundwater environment, posing health threats to the life of organisms. Although seepage temperature exerted a small effect on nZnO suspension leakage volume, change in seepage temperature affects the mass of transported nZnO in GCL by redispersion of nZnO in suspension. As the seepage temperature increases, the mass of nZnO that permeated the GCL increases, reaching a maximum at 50 °C, and then decreases.     

Hydro-thermal coupled analysis for health monitoring of embankment dams

Measuring and analyzing internal dam temperature may provide insight into evaluating the integrity of earthen dams. Temperature in a dam, with the advent of modern distributed temperature sensing (DTS) technique, is conveniently measured. The analysis of the temperature is conducted based on a hydro-thermal coupled analysis technique. In this study, DTS-based temperature data and VS2DHI (a finite difference code for analyzing two-dimensional heat transport in porous media) were used to analyze the hydro-thermal coupled behavior in a dam. The results of this analysis show that the temperature variation in an earthen dam is closely related to seepage conditions. Additionally, a localized high-temperature (26 °C) zone found in the measured data of the dam, which raised concern to engineers on site, is explained through either hot water infiltration into the foundation layer or lower permeability of the foundation layer than the magnitude that appeared in the design document. These findings demonstrate that hydro-thermal coupled analysis has the potential for evaluating the integrity of earthen dams.     

Characterizing groundwater recharge using oxygen and hydrogen isotopes: a case study in a temperate forested region,South Korea

In the cool temperate region of South Korea, oxygen and hydrogen isotopes of groundwater, lake water, and precipitation were studied to determine the season of groundwater recharge. All the groundwater samples, irrespective of season, on δ¹⁸O–δ²H scale plotted along the summer precipitation, suggesting summer precipitation largely modulates recharge. The deuterium excess values of groundwater (d-excess) show clear seasonal difference, higher in winter (> 18‰) and lower in summer (< 10‰). And its resemblance to the summer precipitation d-excess value further suggests dominant role of summer precipitation in groundwater recharge. Based on the mass balance equation, with end-member d-excess values of seasonal precipitation and groundwater as input variables, groundwater is composed of 66% summer and 34% winter precipitation. Despite the study area being heavily forested, summer rainfall contribution higher than winter suggests that evapotranspiration effect is minimal in the region; may be due to thin sand–gravel-based porous soil overlying highly weathered granitic rock system.     

Comparison between the TOPMODEL and the Xin’anjiang model and their application to rainfall runoff simulation in semi-humid regions

To study the application of the TOPMODEL and the Xin’anjiang model to rainfall runoff simulation in semi-humid regions, the Holtan excess infiltration runoff module was added to the TOPMODEL structure. The basin of the Heihe Jinpen Reservoir in Shaanxi Province, China, was selected as the study area. Rainfall and runoff data and digital elevation models were collected. The watershed topographic parameters and 21 floods that occurred from 2005 to 2013 were obtained to simulate rainfall runoff. Results show that the improved TOPMODEL and the Xin’anjiang model can effectively stimulate rainfall runoff. The average values of their Nash coefficient are 0.84 and 0.83, respectively, upon calibration, and 0.78 and 0.80, respectively, upon validation. The Xin’anjiang model performs slightly better than the improved TOPMODEL. The results of large flood peaks are better than those of ordinary floods. Both results can be used to simulate the rainfall runoff of a watershed.     

Experimental and numerical investigation on coal drawing from thick steep seam with longwall top coal caving mining

Steep coal seam mining activities will frequently occur during the next few decades in China. In this study, both experimental and numerical methods are employed to investigate the coal drawing from thick steep seam with longwall top coal caving mining. A series of analyses is performed to investigate the features of the drawing body, the distribution of top coal recovery ratio and the shape of the rock flow under steep conditions. The results indicate that the drawing body of top coal develops prior to upper side of the panel face obviously, and the top coal in the central part of the panel has a higher recovery ratio than that in the lower and upper parts in steep coal seam with caving mining method. The flow paths of the fragmented top coal are nearly straight lines moving towards the drawing window, and the fastest path maintains a constant angle with the plumb line. The spatial shape of the rock flow indicates “bidirectional asymmetry,” which results from the presence of the shield beam and dip angle of the coal seam; thus, this is the root cause of the appearance of the drawing body’s prior development towards the upper side of the panel. The field observation data indicates the same distribution of top coal recovery as that in the physical experiment and numerical simulation. Furthermore, suggested measurements are proposed to improve top coal recovery in steep seam mining based on the engineering practice of Dayuan coal mine.     

重力方法在祁连山地区构造特征与岩体解释中的应用

依据地质、航磁等资料,结合实测岩石物性资料,以1∶250 000重力资料为基础对祁连山地区(张掖、刚察地区)进行综合研究。研究地质构造与地球物理特征,划分了大地构造单元,探讨了隐伏与半隐伏岩体分布。该区域经多年的重力工作,勘探面积已近3万多km²,根据重力资料研究布格重力场特征并进行分区; 对地质构造单元重新划分,对主要断裂进行探讨; 圈定隐伏与半隐伏岩体,推断其空间展布特征,并对其解释。结果表明: 祁连山地区地壳密度结构横向分区、纵向分层明显,布格重力异常场的分区特征与地质构造分区特征基本一致。结合2.5D重力剖面反演印证了新的推测结果,为综合地质、地球物理找矿提供参考。     

陕西略阳张家山金矿成矿作用及Au-Se矿物形成物理化学条件研究

陕西略阳煎茶岭金矿矿集区中的张家山金矿主要由破碎蚀变岩型、角砾岩型和含金石英黄铁矿脉型矿石组成。含金石英-黄铁矿脉型矿石产于断层下盘的石英菱镁岩中。黄铁矿发育富As黄铁矿边,环边受As含量的变化呈现一定的韵律变化,自然金赋存在富As黄铁矿中。在断裂发育形成断层角砾岩的过程中,流体充填破碎石英菱镁岩的裂隙中形成热液矿物,包括硫化物、硒化物以及自然金。石英菱镁岩发生破碎形成的网状裂隙被含金石英-方解石-黄铁矿脉充填。破碎蚀变岩型矿石中,自然金主要分布在含金石英-黄铁矿脉的石英之中或靠近热液脉的菱镁矿或石英间隙。随着大量方解石脉沿裂隙贯入,进一步促进石英菱镁岩的破碎及岩石角砾的分离,形成由石英菱镁岩碎屑、石英和褐铁矿组成的复成分角砾岩,自然金和硒化物呈浸染状分布在角砾岩中。笔者在角砾岩型矿石中发现了灰硒汞矿、直硒镍矿、硒铅矿等硒化物,这些硒化物往往与自然金密切共生。结合矿物组合以及相关化学反应关系,通过热力学计算,构建了该矿床在不同温度条件下的热力学相平衡关系图,限定了硒化物与其他相关矿物稳定存在的物理化学条件。硒化物一般与自然金和石英共生,高的f(Se2)值和f(Se2)/f(S2)比值是控制硒化物形成的关键因素。     

沁水盆地原始水动力场类型及其对煤层气排采的影响

水动力场研究在煤层气勘探开发中具有重要作用。本文首先讨论了基于煤层气井排采资料的水动力场研究方法,在分析沁水盆地柿庄区块原始水动力场特点的基础上,结合前人在盆地其他区块水动力场的研究成果,分析了沁水盆地原始水动力场的类型,进而探讨了水动力场类型对煤层气排采的控制作用。研究表明:沁水盆地自边缘向腹部依次存在重力驱动型、滞流型和压实驱动型三种类型的区域原始水动力场;重力驱动型和滞流型水动力场具备煤层气保存条件,含气量高,煤层气排采效果相对较好,而压实驱动型水动力场虽具备一定的保存条件,但因地层压力较高,煤层气井排水降压困难,产气效果较差;无论是在重力驱动型还是滞流型的区域水动力场中,局部的低势汇聚区具备煤层气保存和排采的有利条件,煤层气开发效果一般较好。在未来煤层气勘探开发过程中,应将重力流驱型或滞流型水动力场所在区域中的局部低势汇聚区作为煤层气开发的甜点区。     

贵州省复杂地层地热深井钻探工艺

贵州省地矿局组织实施了“贵州省地热深井钻探技术攻关”项目,研究了喀斯特地区复杂地层情况下地热深井钻探中螺杆钻井工艺和空气钻井工艺的适应性,攻克了两种工艺在该地区应用受地层特性限制的相关技术难题。螺杆马达平均寿命达到200小时以上,螺杆钻井工艺较常规钻井工艺钻进机械钻速提高2～3倍;空气潜孔锤单井应用深度超过1500m,空气潜孔锤钻井工艺较常规钻井工艺机械钻速提高10～29.5倍。同时研究了单井多工艺转换接力钻进技术,以及与上述工艺配套使用的钻井液体系。最终形成了一套适合贵州省地质条件地热深井钻探施工并能显著提高钻井效率和经济效益的组合工艺技术体系。该成果能将1口2000m以上地热深井施工周期由原来的8~12个月缩短至4~6个月,将单井平均施工成本由450万元降低至410万元以下。