Evaluating Cenozoic equatorial sediment deposition anomalies for potential paleoceanographic and Pacific plate motion applications

If equatorial sediments form characteristic deposits around the equator, they may help to resolve the amount of northwards drift of the Pacific tectonic plate. Relevant to this issue, it has been shown that ²³⁰Th has been accumulating on the equatorial seabed faster than its production from radioactive decay in the overlying water column during the Holocene (Marcantonio et al. in Paleoceanography 16:260–267, 2001). Some researchers have argued that this reflects the deposition of particles with adsorbed ²³⁰Th carried by bottom currents towards the equator (“focusing”). If correct, this effect may combine with high pelagic productivity, which is also centered on the equator, to yield a characteristic signature of high accumulation rates marking the paleoequator in older deposits. Here we evaluate potential evidence that such an equatorial feature existed in the geological past. Seismic reflection data from seven meridional transects suggest that a band of equatorially enhanced accumulation of restricted latitude was variably developed, both spatially and temporally. It is absent in the interval 14.25–20.1 Ma but is well developed for the interval 8.55–14.25 Ma. We also examined eolian dust accumulation rate histories generated from scientific drilling data. A dust accumulation rate anomaly near the modern equator, which is not obviously related to the inter-tropical convergence zone, is interpreted as caused by focusing. Accumulation rates of Ba and P₂O₅ (proxies of export production) reveal a static equatorial signature, which suggests that the movement of the Pacific plate over the period 10–25 Ma was modest. The general transition from missing to well-developed focusing signatures around 14.25 Ma in the seismic data coincides with the mid-Miocene development of the western boundary current off New Zealand. This current supplies the Pacific with deep water from Antarctica, and could therefore imply a potential paleoceanographic or paleoclimatic origin. At 10.05–14.25 Ma, the latitudes of the seismic anomalies are up to ~2° different from the paleoequator predicted by Pacific plate-hotspot models, suggesting potentially a small change in the hotspot latitudes relative to the present day (although this inference depends on the precise form of the deposition around the equator). The Ba and P₂O₅ anomalies, on the other hand, are broadly compatible with plate models predicting slow northward plate movement over 10–25 Ma.     

Dynamic recrystallization and fabric development during the simple shear deformation of ice

In situ observations of polycrystalline ice deformed in simple shear between −10 and −1°C are presented. This study illustrates the processes responsible for the deformation, the development of a preferred crystallographic orientation and the formation of a preferred dimensional orientation. Intracrystalline glide on the basal plane, accompanying grain rotations and dynamic recrystallization, helps to accommodate the large intragranular strains. These are the most important mechanisms for crystallographic reorientation and produce a stable fabric that favours glide on the basal plane. Localized kinks, developed in grains unfavourably oriented for easy glide, are unstable and are overprinted by dynamic recrystallization. Dynamic recrystallization is a strain softening process with nucleation occurring in the form of equiaxed grains that grow subparallel to pre-existing grain anisotropies and become elongate during deformation. Plots of grain axial ratio against orientation ( ) indicate a weak shape fabric which does not correspond to the theoretical foliation and elongation for the appropriate increment of shear strain. We argue that estimates of the strain magnitude made from orientation of elongate grains are unreliable in high temperature shear zones. These results are applicable to both geological and glacial shear environments.     

Garnet lherzolites from Somerset Island,Canada and aspects of the nature of perturbed geotherms

Garnet lherzolite xenoliths of similar petrography and mineralogy are found in the Elwin Bay, Nanorluk, and Amayersuk kimberlites. The xenoliths are either coarse equant to coarse tabular or porphyroclastic in texture. Compositions of coexisting pyroxenes indicates equilibration at 1000–1270° C at 34–41 kb (Wood-Banno/Wood method) or 865–1200° C at 29–36 kb (Wells/Wood method). No simple correlation exists between textural types and equilibration temperature. A primary spinel-bearing garnet lherzolite has equilibrated at 840° C at 21 kb (Wells/Wood) and provides the only known example of a xenolith with relatively high Cr/Cr+Al which has equilibrated at the spinel to garnet lherzolite transition along the continental geotherm. The pressure and temperature estimates for the xenoliths lie above those of the steady state geotherm and indicate that a perturbed geotherm existed in this region at the time of kimberlite intrusion. The formation of perturbed geotherms is discussed and it is considered that the upper high temperature limbs of inflected geotherms are transient pseudogeotherms generated in response to a thermal aureole about a rising mantle diapir and that the lherzolites which define such a geotherm represent a telescoped section of the mantle and include xenoliths derived from above and below the point of kimberlite liquid segregation. The lower temperature limbs of inflected geotherms are considered to be representative of the steady state geotherm and are sampled by the kimberlite which after segregation from the diapir rises at a much faster rate than the parent diapir and passes through material which is unaffected by the diapir thermal aureole.     

Sub-Micrometre Resolution FIB-SEM-based ToF-SIMS Used to Map Geochemical Zoning in Four Zircon Reference Materials

Zircon geochemistry can vary over micrometre scales; therefore, natural reference materials need to be well characterised before being used to calculate trace element mass fractions in unmeasured samples. Moreover, reference material homogeneity needs to be ensured with the accelerating rate of geoanalytical developments to map mineral chemistry at increasingly finer scales. Here, we investigate trace element zoning in four widely used zircon reference materials: 91500, Mud Tank, Temora and Plešovice, as well as zircon crystals from the Mount Dromedary/Gulaga Igneous Complex, Australia. Sub-micrometre resolution focused ion beam scanning electron microscope (FIB-SEM) based time-of-flight secondary ion mass spectrometry (ToF-SIMS) and 5 μm resolution LA-ICP-MS mapping show that trace elements are zoned in all reference materials, though 91500 exhibited the least zonation. We demonstrate that FIB-SEM-based ToF-SIMS can rapidly resolve variations in trace elements (e.g., U, Th, Sc, Y, Gd, Dy, Yb and Li) at sensitivities down to the μg g^-1 level with a spatial resolution of 195 nm for areas 100 × 85 μm to 959 × 828 μm. Zircon 91500 is recommended for future quantitative analyses provided that (1) the spatial distribution of elements is imaged before analysis of unknown samples and (2) it is used in conjunction with a doped glass as the primary reference material.