3d transition metal L-edge X-ray absorption studies of the dichalcogenides of Fe, Co and Ni

The X-ray absorption spectra of the transition metal L_3,2-edges of the dichalcogenides FeS₂ (pyrite), FeSe₂, FeTe₂, CoS₂, CoSe₂, CoTe₂, NiS₂, NiSe₂ and NiTe₂ have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.     

Impact of quarrying gypsum in a semidesert karstic area (Sorbas,SE Spain)

The Messinian gypsum of Sorbas is intensively karstified, with hundreds of dolines and numerous, highly unusual exo- and endokarstic forms. Amongst these the tumuli are especially spectacular, as are the large caverns, adorned with numerous speleothems, some of which have not been described anywhere else in the World. The extraction of the gypsum has impacted practically all the elements of the environment (landscape, water, soil, subsoil, flora, fauna, etc.) and, in particular, all of the karstic forms. In addition to endangering the caves and the natural treasures that they contain, it affects the surface waters, markedly modifying the hydrographic network. Groundwaters, which now occur in the bottom of a quarry, are also affected.     

Characterization of permineralized kerogen from an Eocene fossil fern

The processes of organic maturation that occur during the permineralization of fossils and the detailed chemistry of the resulting products are incompletely understood. Primary among such processes is the geochemical alteration of biological matter to produce kerogen, such as that which comprises the cell walls of the fossils studied here: essentially unmetamorphosed, Eocene plant axes (specimens of the fossil fern Dennstaedtiopsis aerenchymata cellularly permineralized in cherts of the Clarno Formation of Oregon and the Allenby Formation of British Columbia). The composition and molecular structure of the kerogen that comprises the cell walls of such axes were analyzed using ultraviolet Raman spectroscopy (UV–Raman), solid state ¹³C nuclear magnetic resonance spectroscopy (¹³C NMR) and pyrolysis–gas chromatography–mass spectrometry (py–GC–MS).Cellularly well-preserved fern axes from both geologic units exhibit similar overall molecular structure, being composed primarily of networks of aromatic rings and polyene chains that, unlike more mature kerogens, lack large polycyclic aromatic hydrocarbon (PAH) constituents. The cell walls of the Allenby Formation specimens are, however, less altered than those of the Clarno chert, exhibiting more prevalent oxygen-containing and alkyl functional groups and comprising a greater fraction of rock mass.The study represents the first demonstration of the effectiveness (and limitations) of the combined use of UV–Raman, ¹³C NMR and py–GC–MS for the analysis of the kerogenous cell walls of chert-permineralized vascular plants.     

Forward-Modeling of Doppler Shifts in EUV Spectral Lines

The interpretation of red- and blueshifts in EUV spectral observations remains a challenge that could provide important clues to the heating processes in the solar atmosphere. Hinode/EUV Imaging Spectrometer (EIS) observations near the footpoints of coronal loops show blueshifts for emission lines with temperatures above 1 MK and redshifts for lines below 1 MK. The implications are addressed through numerical modeling of loop dynamics. The simulation results are converted into synthetic EIS observations. A single one-dimensional loop cannot reproduce the observed behavior. However, persistent red- and blueshifts can be understood as a collective spectral signature of a bundle of 10 or more loops that have an average temperature of around 1 MK and evolve in a similar way: small-scale heating events occur randomly along each loop on a timescale of several minutes. Strong blueshifts are accompanied by low intensities. The power-law index of the energy distribution has a minor role in determining the average Doppler shifts.     

3XMM J185246.6+003317 as transient neutron star

We performed an X‐ray timing and spectral analysis of the variable source 3XMM J185246.6+003317 to investigate its physical nature. The data from all observations of 3XMMJ185246.6+003317 conducted by XMM‐Newton EPIC MOS1 and MOS2 with the same instrumental setup in 2004–2009 were reprocessed to form a homogenous data set of solar barycenter corrected photon arrival times and high S/N spectra of 3XMM J185246.6+003317. A Bayesian method for the search, detection, and estimation of the parameters of a periodic signal of unknown shape was employed, as developed by Gregory & Loredo (1992, 1993). The results show that 3XMM J185246.6+003317 is a transient neutron star with the genuine spin‐period of 23.11722 (23.11711–23.11727) s and its derivative of 5.3(0.3–5.5)×10^–11 s s^–1, implying a characteristic age of 7 (6–104) kyr, if the period derivative can be ascribed to the genuine spin‐down rate of the neutron star. The rotational‐phase averaged X‐ray spectra at the different brightness periods can be fitted with a highly absorbed blackbody model with different temperatures. The phase‐folded light curves in different energy bands with high S/N ratio show a double‐peaked profile; the variations depend on time and energy, indicating that radiation emerges from at least two emitting areas. The spectra at the phases corresponding to the maxima in the phase‐folded light curve show different spectral parameters of absorbed blackbody radiation, i.e. the hotter one has a smaller size. The source is detected only from September 2008 to April 2009 with persistently decreasing brightness, but not before, even though it was observed by XMM. Hence, it is a transient neutron star or a binary system hosting it. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)