Nitrate contamination in a shallow urban aquifer in East Ukraine: evidence from hydrochemical,stable isotopes of nitrate and land use analysis

A combined hydrochemical and stable isotope approach was used to investigate the origin of nitrate in the shallow unconfined groundwater of Kharkiv city, Eastern Ukraine. The contamination was investigated in the context of land use within the catchment area. The observed enrichment of sulfate, chloride and nitrate suggests significant groundwater contamination in the shallow urban aquifer, which is widely used as drinking water source for the urban population. Characteristic nitrate/chloride ratios as well as stable isotope ratios (N and O) of nitrate in the most contaminated springs confirmed that septic waste from leaky sewer systems was the main source of nitrate contamination in the groundwater. Nitrate contamination is linked to the type of land use and sewage treatment regime in the catchment area. It is also modulated by the regional hydrogeology, which determines the susceptibility of a given aquifer toward groundwater pollution. A more quantitative assessment of nitrate sources based on the nitrate isotope analysis alone is rather difficult. However, our study confirms that the combination of hydrochemical tracers, robust land-use analysis and nitrate stable isotope measurements represents a valuable approach to identify the origin of the nitrate contamination.     

Isotopic variation of fishes in freshwater and estuarine zones of a large subtropical coastal lagoon

We used stable C and N isotope ratios of tissues from 29 fish species from a large subtropical lagoon in southern Brazil to examine spatial variability in isotopic composition and vertical trophic structure across freshwater and estuarine habitats. Nitrogen isotope ratios indicated a smooth gradation in trophic positions among species, with most fishes occupying the secondary and tertiary consumer level. Fish assemblages showed a significant shift in their carbon isotopic signatures between freshwater and estuarine sites. Depleted carbon signatures (from −24.7‰ to −17.8‰) were found in freshwater, whereas more enriched signatures (from −19.1‰ to −12.3‰) were obtained within the estuarine zone downstream. Based on our survey of the C₃ and C₄ plants and isotopic values for phytoplankton and benthic microalgae reported for ecosystems elsewhere, we hypothesized that the observed δ¹³C differences in the fish assemblage between freshwater and estuarine sites is due to a shift from assimilating organic matter ultimately derived from C₃ freshwater marsh vegetation and phytoplankton at the freshwater site (δ¹³C ranging from −25‰ to −19‰), to C₄ salt-marsh (e.g. Spartina) and widgeon grass (Ruppia maritima), benthic microalgae and marine phytoplankton at the estuarine sites (from −18‰ to −12‰). Our results suggested that fish assemblages are generally supported by autochthonous primary production. Freshwater fishes that likely were displaced downstream into the estuary during periods of high freshwater discharge had depleted δ¹³C values that were characteristic of the upper lagoon. These results suggest that spatial foodweb subsidies can occur within the lagoon.     

RC jacketing parameters to retrofit highway bridges

Highway bridges are essential structures in the transportation system of any country in the world. Many highway bridges are reinforced concrete (RC) bridges that were constructed before the 1980s, prior to current seismic regulation codes. The continuous modification of regulation codes makes it necessary to evaluate structures, and in many cases, existing bridges require interventions to increase their seismic capacity. Among the different techniques used to improve bridge capacity, encasing the columns with RC jackets increases the strength and stiffness of the substructure. RC jacketing increases the column cross sections, improves the seismic capacity and reduces the seismic vulnerability of the bridge substructures. This work presents a parametric study to assess the expected demands of seismically deficient medium length highway bridges retrofitted with RC jacketing aimed at determining the best jacket parameters. A suite of twenty strong ground motions, recorded from a subduction seismic source close to the Pacific Coast in Mexico, was selected to characterize the seismic demand. The bridge superstructures are simply supported with five 30 m long spans for a total length of 150 m. The bridge models have five possible pier heights of 5, 10, 15 20 and 25 m and three different jacket thicknesses and steel ratios. Pushover analyses and capacity spectra of the family of accelerograms allow for the determination of the pier demands by obtaining the performance point as the intersection of the capacity and demand curves. The results allow for the determination of the influence of each parameter on the expected seismic behavior of the bridge models, with the aim of selecting the most suitable jacket characteristics to improve the seismic bridge performance.     

Evaluation of the potential for gas leakage along wellbores in the St. Lawrence Lowlands basin,Quebec, Canada

Wellbore attributes (i.e., deviation, casings and plugging characteristics) for 85 wells in the St. Lawrence Lowlands basin of southern Quebec were compiled from drilling reports and abandonment programs to provide an overview of the abandoned well characteristics and to establish a diagnosis on the long-term reliability of the completion and abandonment practices carried out by the companies since the beginning of oil and gas exploration. Using these data, the conventional and unconventional wells were divided into four categories: (1) conventional wells drilled before 1950, (2) conventional wells drilled between 1950 and 1970, (3) conventional wells drilled after 1970 and shale gas wells (all drilled after 2000). Very little information was available for wells drilled before 1950. More information was available for the wells drilled from 1950 to 1970 which is considered a transition period between old and modern technology. Conventional and unconventional wells drilled after 1970 were generally well documented and their attributes corresponded to API standards. A decision tree, inspired from the methodology proposed by Watson and Bachu (SPE Drill Complet 24(1):115–126, 2009.  https://doi.org/10.2118/106817-PA), was then created to assess the potential of leakage of each of the conventional and unconventional wells using the compiled attributes. The factors defining the probability of well leakage were wellbore deviation, height of cement in casing annuli (partially or fully cemented), type of abandonment plugs (cement or mechanical plugs) and drilling date (before or after 1970). Among the 85 wells assessed by this tree, the probability of leakage was higher than 50% for 55 wells (65% of wells). Wellbore deviation and lack of information on the construction and abandonment methods were respectively the primary and secondary causes of high probability of leakage of these wells.     

Late Pleistocene and early Holocene ecological response of Lake El Trébol (Patagonia, Argentina) to environmental changes

Stratigraphy of Lake El Trébol (41°S 71°W, 758 m a.s.l.) described from an 11 m long sediment core provided a continuous record of patecenvironmental changes occurred during the last 14,000 years in southern South America east of the Andes. Located in an ecotonal area within a strong humidity gradient, this lake offers a unique opportunity to develop paleolimnological studies. Using a geochemical approach that includes elemental analysis, bulk organic matter, major nutrients and pigments combined with chironomids and pollen analysis, three zones were identified in the sedimentary record of this take. The oldest one (between 680 and 1,100 cm) corresponds to the late Glacial period. During that time, clayish laminated sediments were formed in a proglacial environment. Low organic matter, biogenic silica and nitrogen contents and the absence of pigments, pollen and chironomids characterise this period. At the end of this period, ca. 14,000 yr BP, a sharp increase in phosphorus concentrations predates major changes in limnological parameters. The transition zone (between 560 and 680 cm) is related to major changes in the drainage system that started soon after ca. 14,000 yr BP and continued to ca. 10,500 yr BP. The chemical composition of the sediments was affected by an increase in physical weathering mechanisms almost coincident with the increase in the regional volcanic activity that produced suspended volcanic detritus. The increase of mainly coarser detritical components may indicate a reorganisation of the fluvial system by that time. Simultaneously, an increase in the productivity of the lake accompanied by a gradual replacement of open vegetation with Nothofagus, Poaceae and Ericaceae, by Nothofagusforest, was observed. In the last zone (between 0 and 560 cm) the productivity of Lake El Trébol achieves maximum values. The trends in geochemical and biological indicators observed at Lake El Trébol can be up to some extent, correlated to those registered in Lake Mascardi. The results support earlier paleoctimatic scenarios from southern South America.