An application of Mie's series to soft particles

Summary The scattering of electromagnetic radiation from soft particles has been studied by a new method which allows to transform the Mie series into a simplified form through the use of some auxiliary expansions derived in the Appendix of this article. This simplified form (eq. 1) converts into the Hulst and Rayleigh-Debye-Gans' formulae if the parameters of eq. I are properly restricted. A further simplified form (eq. II), improves the well-known Hulst approximation.     

Dissolution of secondary copper sulphides using complex-forming agents (EDTA,EDA). Part II: Chalcocite dissolution in EDTA and EDA

This work is immediate continuation of Part I, using an identical method and evaluation for kinetic studies. The systems chalcocite-ethylene diamine tetra-acetic acid and chalcocite-ethylene diamine were studied. It was necessary to refine the geometrical model method for chalcocite in order to establish dissolution kinetics of polydispersions. This work confirms that chalcocite leaching proceeds through covellite even in the medium of complex-forming agents and kinetic equations for both leaching stages were evaluated with an attempt at physical interpretation.     

The Athens earthquake (7 September 1999): intensity distribution and controlling factors

The Athens earthquake, M_s=5.9, that occurred on 7th September 1999 with epicenter located at the southern flank of Mount Parnitha (Greece, Attiki) according to instrumental data, is attributed to the reactivation of an ESE–WNW south- dipping fault without surficial expression. The earthquake caused a large number of casualties and extensive damage within an extended area. Damage displayed significant differentiation from place to place, as well as a peculiar geographic distribution. Based on geological, tectonic and morphological characteristics of the affected area and on the elaboration of damage recordings for intensity evaluation, it can be safely suggested that intensity distribution was the result of the combination of a number of parameters both on macro and microscale. On the macroscale, the parameters are the strike of the seismogenic fault, seismic wave directivity effects and to an old NNE–SSW tectonic structure, and they are also responsible for the maximum intensity arrangement in two perpendicular directions ESE–WNW and NNE–SSW. On the microscale, site foundation formations, old tectonic structures buried under recent formations and morphology are the parameters that differentiated intensities within the affected area.     

Fluvial and lacustrine palaeoenvironments of the Miocene Siwalik Group, Khaur area, northern Pakistan

The Miocene Siwalik Group (upsection, the Chinji, Nagri, and Dhok Pathan Formations) in northern Pakistan records fluvial and lacustrine environments within the Himalayan foreland basin. Thick (5 m to tens of metres) sandstones are composed of channel bar and fill deposits of low-sinuousity (1·08–1·19), single-channel meandering and braided rivers which formed large, low-gradient sediment fans (or ‘megafans’). River flow was dominantly toward the south-east and likely perennial. Palaeohydraulic reconstructions indicate that Chinji and Dhok Pathan rivers were small relative to Nagri rivers. Bankfull channel depths of Chinji and Dhok Pathan rivers were generally ≤ 15 m, and up to 33 m for Nagri rivers. Widths of channel segments (including single channels of meandering rivers and individual channels around braid bars) were 320–710 m for Chinji rivers, 320–1050 m for Nagri rivers, and 270–340 m for Dhok Pathan rivers. Mean channel bed slopes were on the order of 0·000056–0·00011. Bankfull discharges of channel segments for Chinji and Dhok Pathan rivers were generally 700–800 m³s^?1, with full river discharges possibly up to 2400 m³s^?1. Bankfull discharges of channel segments for Nagri rivers were generally 1800–3500 m³s^?1, with discharges of some larger channel segments possibly on the order of 9000–32 000 m³s^?1. Full river discharges of some of the largest Nagri braided rivers may have been twice these values. Thin (decimetres to a few metres) sandstones represent deposits of levees, crevasse channels and splays, floodplain channels, and large sheet floods. Laminated mudstones represent floodplain and lacustrine deposits. Lakes were both perennial and short-lived, and likely less than 10 m deep with maximum fetches on the order of a few tens of kilometres. Trace fossils and body fossils within all facies indicate the former existence of terrestrial vertebrates, molluscs (bivalves and gastropods), arthropods (including insects), worms, aquatic fauna (e.g. fish, turtles, crocodiles), trees, bushes, grasses, and aquatic flora. Palaeoenvironmental reconstructions are consistent with previous palaeoclimatic interpretations of monsoonal conditions.     

Video cathodoluminescence microscopy of diagenetic cements and its applications

Diagenetic studies of sedimentary rocks using cold cathodoluminescence (CL) microscopy have been severely limited because of the very low intensity of visible luminescent emissions, which required long photographic exposure times, and because of the difficulty in obtaining quantitative data from CL observations. The solution to this problem is to fit the microscope with a high-sensitivity digital colour video camera linked to a computer with image enhancement and image analysis software. The new technique described in this paper:

• produces digital CL images of consistent high quality, both quickly and cheaply;

• controls the capture and editing of CL images, to reveal detailed textural information even from minerals exhibiting low level luminescence such as quartz;

• acquires quantitative information on pore systems and the abundance of cement zones from CL images.

Examples are presented to demonstrate the high quality of images produced in this way and the range of uses to which the new technique can be applied. The ability to image exactly the same field of view in both plane polarised light and CL is a particular advantage. Image analysis techniques have been developed to give a statistical characterisation of both pore systems and cement phases that infill them. The abundance of contrasting cement zones seen in CL can be measured and the abundance of cement phases can be mapped across a reservoir. The history of porosity occlusion can be reconstructed quantitatively and integrated with burial history and hydrocarbon migration. Porosity can be measured accurately and, since the technique obtains data on pore geometry as well as abundance, the pore system can be characterised by pore size distributions and pseudo-capillary pressure curves. This also opens the possibility of estimating permeability from thin sections.     

Methanogenesis and organic matter destruction in bottom sediments of technogenic water bodies

Traits have been revealed in the microbial processes of methane formation and organic matter destruction in bottom sediments of technogenic water bodies, in which at the abundance of C_org compounds, including toxic, dissolved oxygen deficiency, and low redox potential, organic matter decay in sediments is mostly anaerobic with the predominance of methanogenesis and sulfate reduction. Data on major microbial processes are used to calculate the total sludge destruction; it is maximal in the sediments of low-toxicity technogenic water bodies; organic matter destruction in them is mostly due to methanogenesis; it is minimal in high-toxicity water bodies, the share of sulfate reduction in them increases, and that of methanogenesis decreases.     

Subbottom acoustic and sedimentary records of past surface water–groundwater exchange through sinkhole lakes in south Georgia,U.S.A

Lake Balboa is a deep sinkhole lake in south Georgia. Subbottom acoustic profiling and long sediment cores reveal four stratigraphic units within >20 m of lacustrine fill above acoustically stratified and faulted Miocene/Pliocene overburden and basement Eocene limestone which hosts the Floridan Aquifer system (FAS). Fill consists of thin, rhythmically bedded, peaty sediments (Unit I), indicative of slow sedimentation in a shallow swamp until 13,110–12,680 cal BP, a mix of desiccated and over-consolidated clay and silty sand (Unit II) implying periodic subaerial exposure of the lake bed until 9470–9025 cal BP, and gyttja associated with a rapid 8 m rise in water level by 9120–9020 cal BP (Unit III), as well as an additional rise of 10 m to modern lake levels (Unit IV). Accumulation of nearly 4.5 m of low permeability gyttja, and higher lake levels have fundamentally changed exchange between surface water and groundwater, reducing by 40% or more the rate of vertical leakage to the FAS and increasing shallow aquifer discharge to the lake.     

Model for the formation of arsenic contamination in groundwater. 1. Datong Basin,China

Mineral equilibria were analyzed in the system As-bearing rock-meteoric water. It was shown that carbonate rocks are the most probable source of As and Sr in the waters of the Datong Basin (People's Republic of China). The reason for groundwater enrichment in As is the shift of the equilibrium FeCO₃ (siderite) + H₂O = FeOOH(goethite) + CO₂(g) + H₂(g) to the left (toward siderite formation) owing to organic matter oxidation by atmospheric oxygen and an increase in the equilibrium partial pressure of CO₂, while the Eh of the system remains below ?0.30 ± 0.06 V.     

Friedrichbeckeite, K (□0.5Na0.5)2 (Mg0.8Mn0.1Fe0.1)2 (Be0.6 Mg0.4)3 [Si12O30], a new milarite-type mineral from the Bellerberg volcano, Eifel area, Germany

Friedrichbeckeite is a new milarite-type mineral. It was found in a single silicate-rich xenolith from a quarry at the Bellerberg volcano near Ettringen, eastern Eifel volcanic area, Germany. It forms thin tabular crystals flattened on {0001}, with a maximum diameter of 0.6 mm and a maximum thickness of 0.1 mm. It is associated with quartz, tridymite, augite, sanidine, magnesiohornblende, enstatite, pyrope, fluorapatite, hematite, braunite and roedderite. Friedrichbeckeite is light yellow, with white to light cream streak and vitreous lustre. It is brittle with irregular fracture and no cleavage, Mohs hardness of 6, calculated density is 2.686 gcm^?3. Optically, it is uniaxial positive with n_ω = 1.552(2) and n_ε = 1.561(2) at 589.3 nm and a distinct pleochroism from yellow (//ω) to light blue (//ε). Electron microprobe analyses yielded (wt.%): Na₂O 2.73, K₂O 4.16, BeO 4.67, MgO 11.24, MnO 2.05, FeO 1.76, Al₂O₃ 0.15, SiO₂ 73.51, (Σ CaO, TiO₂ = 0.06) sum 100.33 (BeO determined by LA-ICP-MS). The empirical formula based on Si = 12 is K_0.87 Na_0.86 (Mg_1.57Mn_0.28Fe_0.24)_Σ2.09 (Be_1.83?Mg_1.17)_Σ3.00 [Si₁₂O₃₀], and the simplified formula can be given as K (□_0.5Na_0.5)₂ (Mg_0.8Mn_0.1Fe_0.1)₂ (Be_0.6?Mg_0.4)₃ [Si₁₂O₃₀]. Friedrichbeckeite is hexagonal, space-group P6/mcc, with a = 9.970(1), c = 14.130(3) Å, V = 1216.4(3) ų, and Z = 2. The strongest lines in the X-ray powder diffraction pattern are (d in Å / I _obs / hkl): 3.180 / 100 / 121, 2.885 / 70 / 114, 4.993 / 30 / 110, 4.081 / 30 / 112, 3.690 / 30 / 022. A single-crystal structure refinement (R1 = 3.62 %) confirmed that the structure is isotypic with milarite and related ^[12] C ^[9] B ₂ ^[6] A ₂ ^[4] T2₃ [^[4] T1₁₂O₃₀] compounds. The C-site is dominated by potassium, the B-site is almost half occupied by sodium, and the A-site is dominated by Mg. The site-scattering at the T2-site can be refined to a Be/(Be?+?Mg) value close to 0.61; the T1-site is occupied by Si. Micro-Raman spectroscopy reveals an increasing splitting of scattering bands around 550 cm^?1 for friedrichbeckeite. The mineral can be classified as an unbranched ring silicate or as a beryllo-magnesiosilicate. With respect to the end-member formula K (□0.5Na0.5)₂ Mg₂ Be₃ [Si₁₂O₃₀] friedrichbeckeite represents the Mg-dominant analogue of almarudite, milarite or oftedalite. The mineral and its paragenesis were formed during pyrometamorphic modifications of the silicate-rich xenoliths enclosed in Quaternary leucite-tephritic lava of the Bellerberg volcano. Holotype material of friedrichbeckeite has been deposited at the mineral collection of the Naturhistorisches Museum Wien, Austria. The mineral is named friedrichbeckeite in honour of the Austrian mineralogist and petrographer Friedrich Johann Karl Becke (1855–1931).     

Fe and O isotope composition of meteorite fusion crusts: Possible natural analogues to chondrule formation?

Meteorite fusion crust formation is a brief event in a high‐temperature (2000–12,000 K) and high‐pressure (2–5 MPa) regime. We studied fusion crusts and bulk samples of 10 ordinary chondrite falls and 10 ordinary chondrite finds. The fusion crusts show a typical layering and most contain vesicles. All fusion crusts are enriched in heavy Fe isotopes, with δ⁵⁶Fe values up to +0.35‰ relative to the solar system mean. On average, the δ⁵⁶Fe of fusion crusts from finds is +0.23‰, which is 0.08‰ higher than the average from falls (+0.15‰). Higher δ⁵⁶Fe in fusion crusts of finds correlate with bulk chondrite enrichments in mobile elements such as Ba and Sr. The δ⁵⁶Fe signature of meteorite fusion crusts was produced by two processes (1) evaporation during atmospheric entry and (2) terrestrial weathering. Fusion crusts have either the same or higher δ¹⁸O (0.9–1.5‰) than their host chondrites, and the same is true for Δ¹⁷O. The differences in bulk chondrite and fusion crust oxygen isotope composition are explained by exchange of oxygen between the molten surface of the meteorites with the atmosphere and weathering. Meteorite fusion crust formation is qualitatively similar to conditions of chondrule formation. Therefore, fusion crusts may, at least to some extent, serve as a natural analogue to chondrule formation processes. Meteorite fusion crust and chondrules exhibit a similar extent of Fe isotope fractionation, supporting the idea that the Fe isotope signature of chondrules was established in a high‐pressure environment that prevented large isotope fractionations. The exchange of O between a chondrule melt and an ¹⁶O‐poor nebula as the cause for the observed nonmass dependent O isotope compositions in chondrules is supported by the same process, although to a much lower extent, in meteorite fusion crusts.