Distance predicting functions and applied location-allocation models.

Distances between demand points and potential sites for implementing facilities are essential inputs to location-allocation models. Computing actual road distances for a given problem can be quite burdensome since it involves digitalizing a network, while approximating these distances by l _p -norms, using for instance a geographical information system, is much easier. We may then wonder how sensitive the solutions of a location-allocation model are to the choice of a particular metric. In this paper, simulations are performed on a lattice of 225 points using the k-median problem. Systematic changes in p and in the orientation of the orthogonal reference axes are used. Results suggest that the solutions of the k-median are rather insensitive to the specification of the l _p -norm. Received: 12 October 1998/Accepted: 17 September 1999     

Paleogeography of Lake Agassiz and regional post-glacial uplift history of the Flin Flon region, central Manitoba and Saskatchewan

Detailed mapping and elevation measurements of glacial lake shorelines in the Flin Flon region has permitted the reconstruction of 6 well-defined levels of Lake Agassiz formed around 8.3 ka to 7.9 ka ¹⁴C BP. The Stonewall, The Pas, Gimli, Grand Rapids, Drunken Point and Ponton paleo-water planes have been tilted upward to the northeast in the Holocene, with gradients decreasing, from the highest to the lowest level, from about 0.34 m km^-1 to 0.22 m km^-1 in the study area. The Setting level, lower than the Ponton but less well defined, is also documented here for the first time. This mapping conclusively refutes the view, entrenched in the literature from the 1890's to the 1960's, that there has been negligible differential uplift in the region following final drainage of Lake Agassiz. The finding has major consequences regarding correlation of glacial lakes across the mid-continent, the post-glacial history of large lakes in the region, and for interpretation of earth rheology and its implications for ice sheet reconstruction.     

Crude Oil Metabolites in Groundwater at Two Spill Sites

Two groundwater plumes in north central Minnesota with residual crude oil sources have 20 to 50 mg/L of nonvolatile dissolved organic carbon (NVDOC). These values are over 10 times higher than benzene and two to three times higher than Diesel Range Organics in the same wells. On the basis of previous work, most of the NVDOC consists of partial transformation products from the crude oil. Monitoring data from 1988 to 2015 at one of the sites located near Bemidji, MN show that the plume of metabolites is expanding toward a lakeshore located 335 m from the source zone. Other mass balance studies of the site have demonstrated that the plume expansion is driven by the combined effect of continued presence of the residual crude oil source and depletion of the electron accepting capacity of solid phase iron oxide and hydroxides on the aquifer sediments. These plumes of metabolites are not covered by regulatory monitoring and reporting requirements in Minnesota and other states. Yet, a review of toxicology studies indicates that polar metabolites of crude oil may pose a risk to aquatic and mammalian species. Together the results suggest that at sites where residual sources are present, monitoring of NVDOC may be warranted to evaluate the fates of plumes of hydrocarbon transformation products.     

Arsenic Cycling in Hydrocarbon Plumes: Secondary Effects of Natural Attenuation

Monitored natural attenuation is widely applied as a remediation strategy at hydrocarbon spill sites. Natural attenuation relies on biodegradation of hydrocarbons coupled with reduction of electron acceptors, including solid phase ferric iron (Fe(III)). Because arsenic (As) adsorbs to Fe‐hydroxides, a potential secondary effect of natural attenuation of hydrocarbons coupled with Fe(III) reduction is a release of naturally occurring As to groundwater. At a crude‐oil‐contaminated aquifer near Bemidji, Minnesota, anaerobic biodegradation of hydrocarbons coupled to Fe(III) reduction has been well documented. We collected groundwater samples at the site annually from 2009 to 2013 to examine if As is released to groundwater and, if so, to document relationships between As and Fe inside and outside of the dissolved hydrocarbon plume. Arsenic concentrations in groundwater in the plume reached 230 µg/L, whereas groundwater outside the plume contained less than 5 µg/L As. Combined with previous data from the Bemidji site, our results suggest that (1) naturally occurring As is associated with Fe‐hydroxides present in the glacially derived aquifer sediments; (2) introduction of hydrocarbons results in reduction of Fe‐hydroxides, releasing As and Fe to groundwater; (3) at the leading edge of the plume, As and Fe are removed from groundwater and retained on sediments; and (4) downgradient from the plume, patterns of As and Fe in groundwater are similar to background. We develop a conceptual model of secondary As release due to natural attenuation of hydrocarbons that can be applied to other sites where an influx of biodegradable organic carbon promotes Fe(III) reduction.     

Sediment Yield During Late Glacial and Holocene periods in the Lac Chambon Watershed,Massif Central,France

A sediment budget for the Late Glacial and Holocene periods was calculated for the Lac Chambon watershed which is located in a formerly glaciated temperate crystalline mountain area. It appears that over 15 500 years: (1) 69 per cent of eroded particles have been displaced by gravity processes and then stored within the watershed, compared to 31 per cent that have been displaced by running water and evacuated outward; (2) the mean mechanical erosion due to gravity processes on the slopes amounted to 16·1 ±6 m and only developed on a quarter of the watershed surface, whereas the mean mechanical erosion due to running water amounted 1·24 ± 0·37 m and involved the whole watershed surface. The mean sediment yields due to gravity processes on slopes were 2300 ± 1360, 1770 ± 960 and 380 ± 100 m³ km⁻³ a⁻¹, respectively, for basalts, and basic and acidic trachyandesites. Values of sediment yield due to running water were 49±15, 120±36 and 79±24 m³ km⁻² a⁻¹, respectively, during the Bôlling–Allerôd, the Younger Dryas and the Pre-Boreal–Boreal periods. They were 56±17 and 166±50 m³ km⁻² a⁻¹ during the Sub-Atlantic period before and after 1360 a BP , respectively. These values reflect variations in the natural environment and the impact of human-induced deforestation. © 1997 by John Wiley & Sons, Ltd.     

Characterization of site conditions (soil class,V<Subscript>S30</Subscript>, velocity profiles) for 33 stations from the French permanent accelerometric network (RAP) using surface-wave methods

Data provided by accelerometric networks are important for seismic hazard assessment. The correct use of accelerometric signals is conditioned by the station site metadata quality (i.e., soil class, V_S30, velocity profiles, and other relevant information that can help to quantify site effects). In France, the permanent accelerometric network consists of about 150 stations. Thirty-three of these stations in the southern half of France have been characterized, using surface-wave-based methods that allow derivation of velocity profiles from dispersion curves of surface waves. The computation of dispersion curves and their subsequent inversion in terms of shear-wave velocity profiles has allowed estimation of V_S30 values and designation of soil classes, which include the corresponding uncertainties. From a methodological point of view, this survey leads to the following recommendations: (1) perform both active (multi-analysis surface waves) and passive (ambient vibration arrays) measurements to derive dispersion curves in a broadband frequency range; (2) perform active acquisitions for both vertical (Rayleigh wave) and horizontal (Love wave) polarities. Even when the logistic contexts are sometimes difficult, the use of surface-wave-based methods is suitable for station-site characterization, even on rock sites. In comparison with previous studies that have mainly estimated V_S30 indirectly, the new values here are globally lower, but the EC8-A class sites remain numerous. However, even on rock sites, high frequency amplifications may affect accelerometric records, due to the shallow relatively softer layers.     

Influence of the warm pool and cold tongue El Niños on the following Caribbean rainy season rainfall

Caribbean rainfall and associated regional-scale ocean–atmosphere anomalies are analyzed during and after warm pool (WP) and cold tongue (CT) El Niño (EN) events (i.e. from the usual peak of EN events in boreal winter to next summer from 1950 to 2011). During and after a CT event, a north–south dipolar pattern with positive (negative) rainfall anomalies over the northern (southern) Caribbean during the boreal winter tends to reverse in spring, and then to vanish in summer. On the contrary, during and after a WP event, weak rainfall anomalies during the boreal winter intensify themselves from spring, with anomalous wet conditions over most of the Caribbean basin observed during summer, except over the eastern coast of Nicaragua and Costa Rica. The Caribbean rainfall anomalies associated with WP and CT events are shaped by competition between at least four different, but interrelated, mechanisms; (1) the near-equatorial large-scale subsidence anomaly over the equatorial Atlantic linked to the zonal adjustment of the Walker circulation; (2) the extra-tropical wave-like train combining positive phase of the Pacific/North American mode and negative phase of the North Atlantic Oscillation; (3) the wind-evaporation-sea surface temperature (SST) positive feedback coupling warmer-than-normal SST with weaker-than-normal low level easterlies over the tropical North Atlantic; and (4) the air-sea coupling between the speed of low level easterlies, including the Caribbean low level jet, and the SST anomaly (SSTA) gradient between the Caribbean basin and the eastern equatorial Pacific. It seems that Caribbean rainfall anomalies are shaped mostly by mechanisms (1–3) during CT events from the boreal winter to spring. These mechanisms seem less efficient during WP events when the atmospheric response seems driven mostly by mechanism (4), coupling positive west-east SSTA gradient with weaker-than-normal low level easterlies, and secondary by mechanism (3), from the boreal spring to summer.     

High-pressure behaviour of serpentine minerals: a Raman spectroscopic study

Four main serpentine varieties can be distinguished on the basis of their microstructures, i.e. lizardite, antigorite, chrysotile and polygonal serpentine. Among these, antigorite is the variety stable under high pressure. In order to understand the structural response of these varieties to pressure, we studied well-characterized serpentine samples by in situ Raman spectroscopy up to 10 GPa, in a diamond-anvil cell. All serpentine varieties can be metastably compressed up to 10 GPa at room temperature without the occurrence of phase transition or amorphization. All spectroscopic pressure-induced changes are fully reversible upon decompression. The vibrational frequencies of antigorite have a slightly larger pressure dependence than those of the other varieties. The O–H-stretching modes of the four varieties have a positive pressure dependence, which indicates that there is no enhancement of hydrogen bonding in serpentine minerals at high pressure. Serpentine minerals display two types of hydroxyl groups in the structure: inner OH groups lie at the centre of each six-fold ring while outer OH groups are considered to link the octahedral sheet of a given 1:1 layer to the tetrahedral sheet of the adjacent 1:1 layer. On the basis of the contrasting behaviour of the Raman bands as a function of pressure, we propose a new assignment of the OH-stretching bands. The strongly pressure-dependent modes are assigned to the vibrations of the outer hydroxyl groups, the less pressure-sensitive peaks to the inner ones.     

Urban hydrologic trend analysis based on rainfall and runoff data analysis and conceptual model calibration

Urban stormwater is a major cause of urban flooding and natural water pollution. It is therefore important to assess any hydrologic trends in urban catchments for stormwater management and planning. This study addresses urban hydrological trend analysis by examining trends in variables that characterize hydrological processes. The original and modified Mann‐Kendall methods are applied to trend detection in two French catchments, that is, Chassieu and La Lechere, based on approximately 1 decade of data from local monitoring programs. In both catchments, no trend is found in the major hydrological process driver (i.e., rainfall variables), whereas increasing trends are detected in runoff flow rates. As a consequence, the runoff coefficients tend to increase during the study period, probably due to growing imperviousness with the local urbanization process. In addition, conceptual urban rainfall‐runoff model parameters, which are identified via model calibration with an event based approach, are examined. Trend detection results indicate that there is no trend in the time of concentration in Chassieu, whereas a decreasing trend is present in La Lechere, which, however, needs to be validated with additional data. Sensitivity analysis indicates that the original Mann‐Kendall method is not sensitive to a few noisy values in the data series.