Dust Formation Chemistry in Carbon-Rich Wolf-Rayet Winds

Dust formation processes are investigated in the hot hydrogen-deficient wind of carbon-rich Wolf-Rayet (WC) stars. Results show that dust precursors (small linear carbon chains) form in large quantities only at high gas densities. This suggests that a clumpy wind or an equatorial disc are necessary to trigger dust formation in WC stars. This revised version was published online in September 2006 with corrections to the Cover Date.     

Contrasting conditions preceding MIS3 and MIS2 Heinrich events

This paper presents an integrated multi-tracer study performed on piston cores recovered in the glacial ice-rafted detritus belt, stretching from Newfoundland to the Irish margin across the North Atlantic (40–55°N), in order to compare in detail the internal structure of each Heinrich event (HE). These tracers are IRD counts (quartz, dolomite, volcanic grains), their Nd isotopic composition and Ar–Ar datings of individual hornblende grains. A focus on the detailed structure of HE confirms that all intervals of massive sediment flux, specifically Heinrich layers HL1-to-5 (HLs), were dominated by North American, Laurentide ice-sheet surges from Hudson Strait, that are evident as far east as the Bay of Biscay (European margin). The sequences of events leading up to the HLs, however, present significant dissimilarities. One important difference is that HL2 and HL1 were preceded by “precursor events” (increases in the number of lithic grains per gram from non-Laurentide sediment sources). Sediment debris derived from near-simultaneous iceberg releases originating from the European ice-sheet are only detectable close to the European margin. In contrast there are no comparable precursor events before HL5 and HL4. This observation implies that precursor events are unlikely to be mechanistically linked to the triggering of HEs. The similarity of the HLs, against contrasting background conditions, is a significant observation that should add constraints to their origin.     

Estimating Sensible and Latent Heat Fluxes over an Inland Water Body Using Optical and Microwave Scintillometers

Boundary-Layer Meteorology - Observations of turbulent heat fluxes over inland water bodies are scarce despite being critical to adequate lake parametrization for numerical weather forecast and...     

Automatic road change detection and GIS updating from high spatial remotely-sensed imagery

This paper presents a framework for road network change detection in order to update the Canadian National Topographic DataBase (NTDB). The methodology has been developed on the basis of road extraction from IRS-pan images (with a 5.8 m spatial resolution) by using a wavelet approach. The feature matching and conflation techniques are used to road change detection and updating. Elementary experiments have showed that the proposed framework could be used for developing an operational road database updating system.     

A model for conductive faults with non-matching grids

In this paper, we are interested in modeling single-phase flow in a porous medium with known faults seen as interfaces. We mainly focus on how to handle non-matching grids problems arising from rock displacement along the fault. We describe a model that can be extended to multi-phase flow where faults are treated as interfaces. The model is validated in an academic framework and is then extended to 3D non K-orthogonal grids, and a realistic case is presented.     

Emerging Contaminants at a Closed and an Operating Landfill in Oklahoma

Landfills are the final depositories for a wide range of solid waste from both residential and commercial sources, and therefore have the potential to produce leachate containing many organic compounds found in consumer products such as pharmaceuticals, plasticizers, disinfectants, cleaning agents, fire retardants, flavorings, and preservatives, known as emerging contaminants (ECs). Landfill leachate was sampled from landfill cells of three different age ranges from two landfills in Central Oklahoma. Samples were collected from an old cell containing solid waste greater than 25 years old, an intermediate age cell with solid waste between 16 and 3 years old, and operating cell with solid waste less than 5 years old to investigate the chemical variability and persistence of selected ECs in landfill leachate of differing age sources. Twenty‐eight of 69 analyzed ECs were detected in one or more samples from the three leachate sources. Detected ECs ranged in concentration from 0.11 to 114 μg/L and included 4 fecal and plant sterols, 13 household\industrial, 7 hydrocarbon, and 4 pesticide compounds. Four ECs were solely detected in the oldest leachate sample, two ECs were solely detected in the intermediate leachate sample, and no ECs were solely detected in the youngest leachate sample. Eleven ECs were commonly detected in all three leachate samples and are an indication of the contents of solid waste deposited over several decades and the relative resistance of some ECs to natural attenuation processes in and near landfills.     

Arctic microbial ecosystems and impacts of extreme warming during the International Polar Year

As a contribution to the International Polar Year program MERGE (Microbiological and Ecological Responses to Global Environmental change in polar regions), studies were conducted on the terrestrial and aquatic microbial ecosystems of northern Canada (details at: http://www.cen.ulaval.ca/merge/). The habitats included permafrost soils, saline coldwater springs, supraglacial lakes on ice shelves, epishelf lakes in fjords, deep meromictic lakes, and shallow lakes, ponds and streams. Microbiological samples from each habitat were analysed by HPLC pigment assays, light and fluorescence microscopy, and DNA sequencing. The results show a remarkably diverse microflora of viruses, Archaea (including ammonium oxidisers and methanotrophs), Bacteria (including filamentous sulfur-oxidisers in a saline spring and benthic mats of Cyanobacteria in many waterbodies), and protists (including microbial eukaryotes in snowbanks and ciliates in ice-dammed lakes). In summer 2008, we recorded extreme warming at Ward Hunt Island and vicinity, the northern limit of the Canadian high Arctic, with air temperatures up to 20.5 °C. This was accompanied by pronounced changes in microbial habitats: deepening of the permafrost active layer; loss of perennial lake ice and sea ice; loss of ice-dammed freshwater lakes; and 23% loss of total ice shelf area, including complete break-up and loss of the Markham Ice Shelf cryo-ecosystem. These observations underscore the vulnerability of Arctic microbial ecosystems to ongoing climate change.     

Ageing effect on the mineral and chemical composition of Opalinus Clays (Mont Terri,Switzerland) after excavation and surface storage

Samples of Opalinus Clays from Mont Terri Underground Research Laboratory in the Swiss Jura were analyzed repetitively relative to the duration of their exposure to atmosphere. The objective was the evaluation of such a progressive exposure on the chemical composition of whole-rock samples, and on the chemical and Sr isotopic compositions of leachates obtained by leaching the rock powders with dilute acetic acid. This chemical study was complemented by scanning electron microscope observations to identify the related mineral alterations. The chemical data for the rock powders remained quite constant whatever the duration of the storage, whereas significant changes were observed for the leachates. Similar changes were observed in the leachates of samples collected progressively closer to the walls of a previously excavated niche. When storage time or distance to gallery wall increases, the main variations are: (1) a progressive decrease of the element contents and of the ⁸⁷Sr/⁸⁶Sr ratio in the leachates, (2) an alteration of pyrite followed by precipitation of Ca-sulfate in the rocks, both observed by SEM, and (3) a probable precipitation of new mineral phases in the rocks, such as Fe-oxyhydroxides and/or jarosite that could not be visualized by electron microscopic observation because of their very limited amount and very small grain size. The modifications call for an oxidation of pyrite that probably induced also an oxidation of the organic matter. It could also be shown that the reactions were enhanced by temperature increase, and that they were less pronounced in the samples behind the gallery wall than in the cores stored in laboratory conditions.