Contribution of Secondary VOC to the Composition of Aqueous Atmospheric Particles: A Modeling Approach

Measurements show that 20–60% of the carbon mass present in fine atmospheric particulate matter consists of water soluble organic compounds (WSOC). However, only 5–20% of this WSOC has been identified, mainly as dicarboxylic acids. Because of their high solubility in water, multifunctional secondary compounds derived from the gas-phase oxidation of volatile organic compounds (VOC) are suspected to be key contributors to the WSOC. To test this assumption, an estimate of aqueous uptake of secondary VOC was included in a highly detailed gas-phase mechanism which treats explicitly the formation of the secondary VOC from a set of representative primary species. Simulations were conducted for 2 scenarios, representing typical rural and urban areas. It was observed that the uptake of secondary VOC can lead to WSOC mass concentrations in the range of a few C m^–3, in fairly good agreement with typical WSOC mass concentrations measured. Speciation of WSOC was found to be mainly as tri- or higher multifunctional hydroxy-carbonyl species and hydroxy-hydroperoxide-carbonyl species, in urban and rural environments, respectively. However, it was also found that taking into account only the absorption of secondary VOC does not bring the carboxylic acids mass concentration in agreement with measurements. An attempt was made to explain this discrepancy by introducing chemistry occurring within deliquescent aerosols.     

地震储层表征:在模拟储层的三维地震响应时考虑盖层、地震勘探布局和储层物性的敏感度

根据三维地震地质模型对地震数据进行模拟是从勘探到生产的周期内决策过程中的一个不可或缺的组成部分。虽然对于在储层内的动力过程和地震地质的模型表述已经取得很大进展,但如何从这些模型得到地震数据的精确模拟仍面临很多挑战。通常是在地球模型范围内根据物性用一维褶积方法来模拟地震数据。然而这个过程一般不考虑地震勘探布局和盖层对地震信号的影响。我们审视了为什么这些因素会制约三维地球模型的有效性,并考虑了为什么需要把盖层和地震勘探布局对三维覆盖和分辨率的影响加进模拟过程之中。我们提出了一种新方法,把建立物性模型和一种新的地震模拟技术结合起来,给出一个工作流程;利用这个流程,勘探工作者可以很快模拟出三维的PSDM数据,这些数据加进了盖层和地震勘探布局对覆盖及分辨率的影响。我们利用从远离挪威海岸的一个油田得到的数据,在考虑覆盖和分辨率效应的地震数据模拟之前,对岩石物性做了一些扰动,然后进行地震数据模拟,以此来说明如何可以用这种方法提高三维地球模型的精确性和增进我们对储层的了解。     

Local Sensitivity Analysis of a Numerical Model of Volcanic Plinian Columns through Automatic Differentiation

Numerical simulation of geological phenomena are nowadays widely used to understand them. A good example are the numerous codes developed to model mass motion in different processes. Such models are approximations to the real phenomena because the physical conditions are simplified or because the values of the parameters intervening in the modeling are known only approximately. For this reason, an obligatory step in the application of these models is the assessment of their sensitivity to changes in the parameters. Sensitivity analysis is also required to evaluate the influence of the different input variables in the outcome of the model. In general this analysis is carried out by repeated computation of the model to different sets of input variables and settings of the model. A more fruitful procedure to carry out such analysis can be achieved by automatic differentiation. In this paper we illustrate such approach through its application to the model of an eruptive plinian column. The results of the analysis allow to assess, in a systematic and efficient manner, the relevance of the different boundary values and parameters of the model. The analysis reveals the effects on velocity, temperature, gas fraction, radius and ultimately column height, by changes in their boundary value (i.e. at the vent). The effect of changes in the value of the gas constants, density of pyroclasts and specific heat of the erupted material is also evidenced. Alternatively, the results can be regarded as a mean to estimate the values of the variables for different set of boundary values without recurring to new runs of the model. Automatic differentiation is shown to be a convenient scheme to obtain derivatives of model variables. This type of analysis forms in addition the basis for further work in inversion schemes.     

Assessing green gentrification in historically disenfranchised neighborhoods: a longitudinal and spatial analysis of Barcelona

To date, little is known about the extent to which the creation of municipal green spaces over an entire city addresses social or racial inequalities in the distribution of environmental amenities – or whether such an agenda creates contributes to green gentrification. In this study, we evaluate the effects of creating 18 green spaces in socially vulnerable neighborhoods of Barcelona during the 1990s and early 2000s. We examined the evolution over time of six socio-demographic gentrification indicators in the areas close to green spaces in comparison with the entire districts. Our results indicate that new parks in the old town and formerly industrialized neighborhoods seem to have experienced green gentrification. In contrast, most economically depressed areas and working-class neighborhoods with less desirable housing stock and more isolated from the city center gained vulnerable residents as they became greener, indicating a possible redistribution and greater concentration of vulnerable residents through the city.     

Inclusive approaches to urban climate adaptation planning and implementation in the Global South

As cities increasingly engage in climate adaptation planning, many are seeking to promote public participation and facilitate the engagement of different civil society actors. Still, the variations that exist among participatory approaches and the merits and tradeoffs associated with each are not well understood. This article examines the experiences of Quito (Ecuador) and Surat (India) to assess how civil society actors contribute to adaptation planning and implementation. The results showcase two distinct approaches to public engagement. The first emphasizes participation of experts, affected communities, and a wide array of citizens to sustain broadly inclusive programmes that incorporate local needs and concerns into adaptation processes and outcomes. The second approach focuses on building targeted partnerships between key government, private, and civil society actors to institutionalize robust decision-making structures, enhance abilities to raise funds, and increase means to directly engage with local community and international actors. A critical analysis of these approaches suggests more inclusive planning processes correspond to higher climate equity and justice outcomes in the short term, but the results also indicate that an emphasis on building dedicated multi-sector governance institutions may enhance long-term programme stability, while ensuring that diverse civil society actors have an ongoing voice in climate adaptation planning and implementation.

Policy relevance

Many local governments in the Global South experience severe capacity and resource constraints. Cities are often required to devolve large-scale planning and decision-making responsibilities, such as those critical to climate adaptation, to different civil society actors. As a result, there needs to be more rigorous assessments of how civil society participation contributes to the adaptation policy and planning process and what local social, political, and economic factors dictate the way cities select different approaches to public engagement. Also, since social equity and justice are key indicators for determining the effectiveness and sustainability of adaptation interventions, urban adaptation plans and policies must also be designed according to local institutional strengths and civic capacities in order to account for the needs of the poor and most vulnerable. Inclusivity, therefore, is critical for ensuring equitable planning processes and just adaptation outcomes.     

Model reduction and discretization using hybrid finite volumes for flow in porous media containing faults

In this paper, we study two different model reduction strategies for solving problems involving single phase flow in a porous medium containing faults or fractures whose location and properties are known. These faults are represented as interfaces of dimension N ? 1 immersed in an N dimensional domain. Both approaches can handle various configurations of position and permeability of the faults, and one can handle different fracture permeabilities on the two inner sides of the fracture. For the numerical discretization, we use the hybrid finite volume scheme as it is known to be well suited to simulating subsurface flow. Some results, which may be of use in the implementation of the proposed methods in industrial codes, are demonstrated.     

Spatio-temporal evolution of the Choisille River (southern Parisian Basin,France) during the Weichselian and the Holocene as a record of climate trend and human activity in north-western Europe

The morpho-sedimentary evolution of the Choisille floodplain (lowland river, catchment: 288 km²), a tributary of the River Loire in the south-western Parisian Basin, was studied through 61 core drillings along eight transects and a geophysical survey located in four stretches of the river: stretches A and B correspond to two sub-catchments, and stretches C and D are in the main valley. Sixty ¹⁴C and four OSL datings were obtained, and sediments were analysed on seven reference cores. Eight phases of evolution differing markedly from the evolution of more northern areas in the Parisian Basin and north-western Europe were identified from spatio-temporal distribution of nine lithological facies. The deepest incision phase (1) occurred during the first part of the Weichselian, followed by the deposition of a gravelly-sandy unit (phase 2) during the Middle Pleniglacial, which was deeply incised (phase 3), probably during the Bölling. From the Allerød up to the last third of the Boreal (phase 4), sedimentation was continuously dominated by peaty deposits, with no evidence of either increased hydraulic energy during the Younger Dryas, or of incision during the LateGlacial–Holocene transition. This trend seems to reflect the specificity of the south-western Parisian Basin climate from the Late Weichselian up to the end of the Boreal, due to the influence of the Atlantic Ocean, compared to more northern areas where the climate was more continental. The downstream incision trend during the last third of the Boreal up to the Subatlantic (phases 5 and 6) indicates a sharp increase in precipitation and vegetation cover; the lack of peaty sediments, widespread in north-western Europe, and also of precipitated carbonates frequent in the Parisian Basin, seems to be due to local physiographic characteristics. The main part of the sediment filling, which is principally silty and retrograde, began during the Subatlantic (phase 7 and 8) as a result of deforestation of the plateaux for crop farming. High human-induced sediment yield and storage concealed the possible impacts of climate change on fluvial dynamics: lithological facies change from phase 7 to 8 can only indicate the autogenic morphological evolution of the floodplain in accretion. The non-univocal upstream–downstream variation in the start of phase 7 shows that sediment yield varied in space and time in the catchment, particularly in relation to the agricultural potential of the different areas; this observation could be used to testify human-induced sedimentation in other catchments.     

The role of rift‐inherited hyper‐extension in Alpine‐type orogens

Alpine‐type orogens are interpreted to result from the collision of former rifted margins. As many present‐day rifted margins consist of hyper‐extended domains floored by thinned continental crust (<10 km) and/or exhumed mantle, this study explores the influence of rift inheritance on the architecture and final evolution of Alpine‐type orogens. We propose that rift‐related necking zones, separating weakly thinned 25‐ to 30‐km‐thick crust from hyper‐extended domains, may act as buttresses during the transition from subduction to collision. As a result, former necking zones may now be found at the boundary between a highly deformed and overthickened nappe stack, made of relics of hyper‐extended domains, and an external, weakly deformed fold‐and‐thrust belt, which largely escaped significant rift‐related crustal thinning and orogeny‐related thickening. Therefore, the role of rift inheritance is of critical importance and is largely underestimated in controlling the architecture and evolution of Alpine‐type orogens.