Rutile inclusions in garnet from a dissolution‐reprecipitation mechanism

Metamorphic garnet commonly contains needle‐like rutile inclusions as well as equant rutile inclusions that surround quartz inclusions and range in size from submicrometer to nanometer. Although the origin of these equant rutile inclusions, that is, exsolution or non‐exsolution, has important implications for petrological and tectonic processes, the crystallographic characteristics of these inclusions have rarely been studied because of the small sizes and analytical difficulties involved. Here, we report the crystallographic characteristics pertinent to the genetic origin of minute equant rutile inclusions in cloudy, nearly spherically shaped garnet domains with Ti‐depleted compositions surrounding quartz inclusions in ultrahigh‐pressure garnet from several diamondiferous Erzgebirge quartzofeldspathic gneissic rock samples. TEM analyses show that the equant rutile crystals in cloudy garnet domains are partially bounded by the low‐energy {100}_rt ± {110}_rt ± {101}_rt facets and have rather random crystallographic orientation relationships (CORs) with the garnet host, with preferential alignment of low‐energy lattice planes, for example, {100}_rt//{112}_grt, for some rutile crystals. Although the rather random CORs are unlikely to be attributed to solid‐state exsolution subjected to the stringent topotactic garnet lattice constraints, the characteristic subhedral {100}_rt ± {110}_rt ± {101}_rt crystal forms of rutile can be rationalized by a metasomatic dissolution‐reprecipitation mechanism via a fluid phase. In this scenario, the quartz+fluid inclusions in garnet were first subjected to decompression microcracking during rock exhumation, followed by dissolution of Ti‐bearing garnet matrix at the crack tips or along the crack surfaces and subsequent reprecipitation of rutile, apatite, gahnite, akdalaite, and Ti‐depleted garnet. The rapid coalescence between rutile and garnet crystals in fluid or direct attachment of rutile crystals onto the dissolving crack surfaces would then yield the rather random CORs as reported here. These results, along with previous work on rutile needles, indicate rather diverse genesis of rutile inclusions in various crystal forms, thus shedding light on the controversial exsolution origin for other inclusion suite/microstructure in minerals.     

The influence of tectonic subsidence on volcaniclastic sedimentation: The Cretaceous upper Daeri Member,Wido Island,Korea

The Daeri Member, a Cretaceous volcanic–sedimentary succession, can be divided into lower, middle, and upper parts based on vertical changes in its lithologic characters. The lower Daeri Member is composed of siliciclastic deposits formed in a semi‐arid floodplain environment, which is overlain by the middle Daeri Member consisting mainly of andesite lava flow. After the emplacement of the andesite, activities of intrabasinal normal faults created accommodation on hanging wall blocks together with the development of intrabasinal topographic relief. The upper Daeri Member occurs only in hanging wall blocks and is composed of rhyolitic volcaniclastic sediments formed during an explosive volcanic eruption. Following the eruption, owing to semi‐arid climatic conditions and the destruction of vegetation, the eruptive materials were easily remobilized and deposited by episodic sediment gravity flows, resulting in deposition of the resedimented volcaniclastic deposits with sheet‐like geometry. Away from the intrabasinal normal faults, the resedimented volcaniclastic deposits show a decrease in grain size together with changes in inferred depositional processes from debris flows to hyperconcentrated flows and supercritical sheetfloods. This suggests that the resedimented volcaniclastic deposits were stacked on alluvial fan environments induced by intrabasinal topographic relief associated with normal fault activities. In addition, episodic movement of the faults gave rise to periodic fluctuation of the accommodation and an increase in gradient of the alluvial fan surface, resulting in the development of coarsening‐upward trends in the resedimented volcaniclastic deposits. The development of the alluvial fan and the coarsening‐upward trends indicate that dynamic tectonic subsidence and concomitant changes in the intrabasinal physiographic relief influenced the depositional processes and sizes of the transported volcaniclastic sediments of the upper Daeri Member. Thus, it is necessary to carefully observe tectonic signatures in volcaniclastic successions, particularly the syneruptive lithofacies, in order to reconstruct the tectonic and volcanic histories of receiving basins.     

Improving gravity anomalies over China marginal sea from retracked Geosat and ERS-1 data

The quality of altimeter data and ocean tide model is critical to the recovery of coastal gravity anomalies. In this contribution, three retracking methods (threshold, improved threshold and Beta-5) are investigated with the aim of improving the altimeter data over a shallow water area. Comparison indicates that the improved threshold is the best retracking method over China Sea. Two ocean tide models, NAO99b and CSR4.0, are analyzed. Results show that different tide models used in the processing of altimeter data may result in differences more than 10 mGal in recovered coastal gravity anomalies. Also, NAO99b is more suitable than CSR4.0 over the shallow water area of China Sea. Finally, gravity anomalies over China Sea are calculated from retracked Geosat/GM and ERS-1/GM data by least squares collocation. Comparison with shipborne gravimetry data demonstrates that gravity anomalies from retracked data are significantly superior to those from non-retracked data. Our results have the same order as the other two altimeter-derived gravity models: Sandwell&Smith(V16) and DNSC08.     

Quantitative assessment of inundation risks from physical contributors associated with future storm surges: a case study of Typhoon Maemi (2003)

Natural Hazards - Future storm-induced inundation risks were assessed by performing storm surge modeling based on Typhoon Maemi (2003) under the generic climate change scenarios proposed by IPCC...     

Assessment of occupational risks from human health and environmental perspectives: a new integrated approach and its application using fuzzy BWM and fuzzy MAIRCA

Stochastic Environmental Research and Risk Assessment - Occupational safety issues encountered in the worksite environment are the issues that companies should consider in improving their...     

How much does an extreme rainfall event cost? Material damage and relationships between insurance,rainfall, land cover and urban flooding

This research aims to understand how insurance, rainfall, land cover and urban flooding are related and how these variables influenced the material damage in the Lisbon Metropolitan Area (LMA) during the 2000–2011 period. Correlation coefficients show strong relationships between built-up areas and claims (0.94) and payouts (0.88). Despite no significant relationships being found between rainfall and the amount of material damage per event, three likelihood levels of flooding were determined for hourly rainfall. Unlike the studied period, the number of claims and their spatial distribution during the 2008 extreme rainfall event were strongly dependent on rainfall. Flooding related to the old watercourses assumed greater importance during this extreme event, recovering a more natural/ancient hydrological behaviour. In the LMA, the greatest material damage was the result of high-magnitude/low-probability rainfall events. Lower magnitude events can trigger numerous claims in heavily built-up areas, but they are hardly capable of producing large material damage.     

On the mechanism of resorption zoning in metamorphic garnet

Abstract An analytical electron microscope study of almandine garnet from a metamorphosed Al–Fe‐rich rock revealed detailed composition profiles and defect microstructures of resorption zoning along fluid‐infiltrated veins and even into the garnet/ilmenite (inclusion) interface. This indicates a limited volume diffusion for the cations in substitution (mainly Ca and Fe) and an interface‐controlled partition for the extension of a composition‐invariant margin. A corrugated interface between the Ca‐rich margin/zone and the almandine garnet core is characterized by dislocation arrays and recovery texture further suggesting a resorption process facilitated by diffusion‐induced recrystallization, diffusion‐induced dislocation migration and diffusion–induced grain boundary migration. Integrated microstructural and chemical studies are essential for understanding the underlying mechanisms of processes such as garnet zoning and its modification. Without this understanding, it will not be possible to reliably use garnet compositions for thermobarometry and other applications that rely on garnet chemical information.     

Fugacity analysis of polycyclic aromatic hydrocarbons between microplastics and seawater

Recently, the accumulation of plastic debris in the marine environment has become a great concern worldwide. Although plastics are biologically and chemically inert, plastic debris has been suspected of causing adverse effects on ecosystems due to the increase in reactivity by size reduction and/or micropollutants associated with plastics. Because of the high sorption capacity of microplastics toward organic micropollutants, it is suspected that microplastics may play roles in the distribution and fate of micropollutants. In order to quantitatively evaluate the “net flow” of environmental contaminants in water-plastic-organism systems, a fugacity analysis was conducted using concentrations of polycyclic aromatic hydrocarbons (PAHs) in open oceans and in polyethylene as a representative material of plastic debris. Ratio of fugacity in polyethylene to that in seawater showed a decreasing trend with increasing partition coefficient between polyethylene and seawater (K_PE/sw). This indicates that phase equilibrium between polyethylene and seawater is not attained for higher molecular weight PAHs. Disequilibrium of high molecular weight PAHs suggests that transfer from seawater to plastic debris is thermodynamically driven and the role of plastic debris as a vector to transfer them to living organisms would be minimal. However, additives may slowly migrate from plastics into the environment causing potentially serious effects on ecosystems.     

Identification of the principal patterns of summer moisture transport in South America and their representation by WCRP/CMIP3 global climate models

The goal of this study is to assess the ability of a set of global climate models (GCMs) to represent the main regional spatial patterns of austral summer moisture transport in South America in order to evaluate if one of the possible causes of GCMs misestimating summer precipitation in this region could be associated with an erroneous representation of these patterns. For this purpose, NCEP/NCAR reanalysis and 20 GCMs from the WCRP/CMIP3 multi-model dataset for the period 1960–1999 were considered. Extreme cases of moisture transport patterns were selected to assess their association with rainfall anomalies. Results obtained indicate that only some aspects of water vapor transport and convergence in South America as well as the associated precipitation anomalies can be reproduced adequately by GCMs. Finally, a case study is presented showing that one of the moisture transport patterns identified was observed during December 2008–February 2009.     

Effect of urbanization on runoff characteristics of the On-Cheon Stream watershed in Pusan,Korea

This study investigated the effect of urbanization on runoff from the On-Cheon Stream watershed in Pusan, Korea. This watershed has been experiencing considerable urbanization since the 1960s. There are two gauging stations in the watershed. For one of the stations there are recent flow data and for the other flow data were observed in the past. A linear reservoir model was chosen and runoff was analysed for several flood events. The linear reservoir model has been found to generate flood hydrographs accurately for both gauging stations, and its applicability to the study area has also been established. Using two methods of computing effective rainfall or rainfall excess (ϕ-index and constant percentage method), the results of runoff analyses were investigated. The ϕ-index method yielded better results than the constant percentage method. A comparison of hydrographs observed in the past with the simulation results at the Ie-Sup bridge site revealed that the peak discharge increased and the mean lag time of the study area decreased owing to urbanization over the past two decades. It is also possible to evaluate the effect of urbanization quantitatively. © 1998 John Wiley & Sons, Ltd.