Molecular and isotopic constraints on the sources of suspended particulate organic carbon on the northwestern Atlantic margin

The abundance, carbon isotopic composition (Δ¹⁴C and δ¹³C), and lipid biomarker (alkenones and saturated fatty acids) distributions of suspended particulate organic matter were investigated at three stations centered on the 2000, 3000, and 3500 m isobaths over the New England slope in order to assess particulate carbon sources and dynamics in this highly productive and energetic region. Transmissometry profiles reveal that particle abundances exhibit considerable fine structure, with several distinct layers of elevated suspended particulate matter concentration at intermediate water depths in addition to the presence of a thick bottom nepheloid layer at each station. Excluding surface water samples, the Δ¹⁴C values of particulate organic carbon (POC) indicated the presence of a pre-aged component in the suspended POC pool (Δ¹⁴C<+38‰). The Δ¹⁴C values at the 3000 m station exhibited greater variability and generally were lower than those at the other two stations where the values decreased in a more systematic matter with increasing sampling depth. These lower Δ¹⁴C values were consistent with higher relative abundances of terrigenous long-chain fatty acids at this station than at the other two stations. Two scenarios were considered regarding the potential provenances of laterally transported POC: cross-shelf transport of shelf sediment (Δ¹⁴C=?140‰) and along-slope transport of the slope sediment proximal to the sampling locations (Δ¹⁴C=?260‰). Depending on the scenario, isotopic mass balance calculations indicate allochthonous POC contributions ranging between 15% and 54% in the meso- and bathy-pelagic zone, with the highest proportions at the 3000 m station. Alkenone-derived temperatures recorded on suspended particles from surface waters closely matched in-situ temperatures at each station. However, alkenone-derived temperatures recorded on particles from the subsurface layer down to 250 m were lower than those of overlying surface waters, especially at the 3000 m station, implying supply of phytoplankton organic matter originally produced in cooler surface waters. AVHRR images and temperature profiles indicate that the stations were under the influence of a warm-core ring during the sampling period. The low alkenone-derived temperatures in the subsurface layer coupled with the lower Δ¹⁴C values for the corresponding POC suggests supply of OC on resuspended sediments underlying cooler surface waters distal to the study area, possibly further north or west. Taken together, variations in Δ¹⁴C values, terrigenous fatty acid abundances, and alkenone-derived temperatures among the stations suggest that input of laterally advected OC is a prominent feature of POC dynamics on the NW Atlantic margin, and is spatially heterogeneous on a scale smaller than the distance between the stations (<150 km).     

Patterns of spatial variation of nutrient content,epiphyte load and shoot size of Posidonia oceanica seagrass meadows (Mediterranean Sea)

Knowledge of patterns of spatial variability of vegetative development, epiphyte load and nutrient availability in seagrass meadows is essential for the adequate design of research and environmental monitoring programmes. Differences in shoot size, epiphyte load and nutrient content of leaves and epiphytes of the Mediterranean endemic seagrass Posidonia oceanica at spatial scales ranging from metres to hundreds of metres are evaluated using a hierarchical nested sampling design. The size and epiphyte load of P. oceanica shoots and the nitrogen and phosphorus content of leaves and epiphytes were different in most of the spatial scales considered. Sampling efforts concentrated at the metre scale incorporated most of the variability in size, epiphyte load and nutrient content of the leaves and epiphytes of P. oceanica shoots. Epiphyte load showed no correlation with nutrient content in the epiphytes or in the leaves. However, epiphyte load and shoot size were negatively correlated, which suggests that light penetration in the canopy may be a main determinant of epiphyte load.     

Desorption of Hydrophobic Organic Chemicals from Fragment-Type Microplastics

Microplastics provide an important medium for hydrophobic organic chemicals (HOCs), and the desorption of HOCs from microplastics is an important process for the dynamics of HOCs associated with microplastics. Although desorption kinetics has been studied for microplastics with ideal geometries, most of the microplastics isolated from the environment are irregular fragment-type microplastics. This study investigated the desorption of six model HOCs from polyethylene (PE) and polypropylene (PP) fragments to artificial seawater and compared the results with those predicted assuming ideal geometries (e.g., sphere and infinitely flat sheet) of microplastics. The experimental desorption was explained well by the model predictions with the characteristic radius for a sphere and the thickness for a plate estimated from visual imaging. The mass fraction remaining at the later stage of desorption was higher than the model simulation assuming a single characteristic length, likely due to the heterogeneity of the particle size distribution. Although there are inevitable uncertainties, it would be useful to assign a single length dimension in desorption modeling for even fragment-type microplastics, especially for the estimation of desorption half-life.     

Assessment of groundwater chemistry in a coastal region (Kunsan, Korea) having complex contaminant sources: a stoichiometric approach

Groundwater chemistry in a coastal region (Kunsan, Korea) having complex contaminant sources was investigated. Water analysis data for 197 groundwater samples collected from the uniformly distributed sixty-six wells were used. Chemical analysis results indicate that groundwaters show wide concentration ranges in major inorganic ions, reflecting complex hydrochemical processes. Due to the complexity of groundwater chemistry, the samples were classified into four groups based on Cl and NO₃ concentrations and the processes controlling water chemistry were evaluated based on the reaction stoichiometry. The results explained the importance of mineral weathering, anthropogenic activities (nitrification and oxidation of organic matters), and Cl-salt inputs (seawater, deicer, NaCl, etc.) on groundwater chemistry. It was revealed that mineral dissolution is the major process controlling the water chemistry of the low Cl and NO₃ group (Group 1). Groundwaters high in NO₃ (Groups 2 and 4) are acidic in nature, and their chemistry is largely influenced by nitrification, oxidation of organic matters and mineral dissolution. In the case of chloride rich waters (Group 3), groundwater chemistry is highly influenced by mineral weathering and seawater intrusion associated with cation-exchange reactions.     

Phytoplankton response to pH rise in a N-limited floodplain lake: relevance of N2-fixing heterocystous cyanobacteria

Phosphorus has been traditionally regarded as the controlling nutrient for phytoplankton growth, however, N-limitation is likely to occur in several environments. For example, nitrogen is considered the main nutrient limiting phytoplankton in floodplain lakes of the Paraná River basin. However, N₂-fixing heterocystous cyanobacteria (N₂-cyano) are usually absent in these water bodies. The low pH values frequently found may limit the development of these algae. We hypothesise that long-term lake isolation allows conspicuous phytoplankton growth during summer, resulting in high photosynthetic rates and pH. This scenario combined with low DIN (dissolved inorganic nitrogen) would favour the development of N₂-cyano. Phytoplankton composition was studied during 16 months in a vegetated and isolated floodplain lake in the Paraná basin. Additionally, pH was artificially increased in in situ mesocosms to test effects on phytoplankton structure. Lake phytoplankton was dominated by flagellates (cryptophytes and euglenophytes) and small coccoid algae (chlorophytes and colonial cyanobacteria). Algal biomass was highest during warm periods. Although pH increased up to 8.8 during the second summer period, N₂-cyano remained rare, most likely because of the high DIN concentration recorded. The alkalophilic diatom Cyclotella meneghiniana dominated and was positively correlated with pH. Conversely, PO₄⁼ concentrations in the mesocosm experiment were high and DIN remained relatively low. pH enhancement in the treated mesocosms (avg. pH = 8.2) promoted the development of N₂-cyano (Anabaena spp.) and C. meneghiniana, which after 1 month of incubation accounted together for 50% of the biomass in contrast to less than 1.6% in control containers. Our results support the hypothesis that during the warm season and under low DIN concentration, high pH favours N₂-cyano growth in these lakes. We provide new evidence supporting the idea that even under optimal nutrient conditions, N₂-cyano do not thrive unless other requirements are satisfied.     

Stratification and salt-wedge in the Seomjin river estuary under the idealized tidal influence

Advection, straining, and vertical mixing play primary roles in the process of estuarine stratification. Estuaries can be classified as salt-wedge, partially-mixed or well-mixed depending on the vertical density structure determined by the balancing of advection, mixing and straining. In particular, straining plays a major role in the stratification of the estuarine water body along the estuarine channel. Also, the behavior of a salt wedge with a halocline shape in a stratified channel can be controlled by the competition between straining and mixing induced by buoyancy from the riverine source and tidal forcing. The present study uses Finite Volume Coastal Ocean Model (FVCOM) to show that straining and vertical mixing play major roles in controlling along-channel flow and stratification structures in the Seomjin river estuary (SRE) under idealized conditions. The Potential Energy Anomaly (PEA) dynamic equation quantifies the governing processes thereby enabling the determination of the stratification type. By comparing terms in the equation, we examined how the relative strengths of straining and mixing alter the stratification types in the SRE due to changes in river discharge and the depth resulting from dredging activities. SRE under idealized tidal forcing tends to be partially-mixed based on an analysis of the balance between terms and the vertical structure of salinity, and the morphological and hydrological change in SRE results in the shift of stratification type. While the depth affects the mixing, the freshwater discharge mainly controls the straining, and the balance between mixing and straining determines the final state of the stratification in an estuarine channel. As a result, the development and location of a salt wedge along the channel in a partially mixed and highly stratified condition is also determined by the ratio of straining to mixing. Finally, our findings confirm that the contributions of mixing and straining can be assessed by using the conventional non-dimensional parameters with respect to salt-wedge behavior.     

西南极利文斯顿岛百耳斯半岛中生代火山岩地球化学特征

西南极利文斯顿岛百耳斯半岛中生代火山岩是晚侏罗纪至晚白垩纪三期火山活动的产物。岩石普遍贫钾,轻稀土元素略为富集,但轻重稀土分馏不强烈;Ｓｒ、Ｋ、Ｒｂ、Ｂａ、Ｔｈ等大离子亲石元素（ＬＩＬ）明显富集,Ｎｂ和Ｔａ明显亏损,过渡金属族元素Ｃｒ和Ｎｉ强烈亏损,表明它们属于火山弧环境中生成的钙碱性系列岩石。白垩纪中期和白垩纪晚期岩石的８７Ｓｒ／８６Ｓｒ比值主要在０．７０３９～０．７０５３之间变化,εＮｄ＞０,８７Ｓｒ／８６Ｓｒ相对１／Ｓｒ、Ｒｂ、Ｋ和ＳｉＯ２等的变化不大,表明其源区岩浆可能直接来自上地幔,很少受到壳源物质的混染。而晚侏罗纪火山岩的Ｓｒ同位素比值较高,说明早期岩浆可能受到少量地壳物质的混染。但在Ｔｈ／Ｔａ－Ｔｈ和Ｔｈ／Ｓｍ－Ｔｈ图解上所有岩石的投影点分布趋势相同,趋势线的斜率＞０。百耳斯半岛中生代火山岩是上地幔部分熔融生成的同源岩浆不同期的产物     

软件实现的数字视频积分处理器

木文从分析气象回波涨落的原因入手,讨论了视频积分处理器参数的选择。从现有硬件实现的数字视频积分器,引导出以全软件实现数字视频积分器的方案。实践证明,软件数字视频积分器与硬件数字视频积分器具有同样的功能,并且具有开发灵活、适用性强的特。点该处理器已经应用在713天气雷达数字化系统中。     

High Temporal Resolution Spectroscopic Observations of the Flare Star V1054 Oph

We present the results of a high temporal resolution spectroscopic monitoring of the flare (UV Cet type) star V1054 Oph (Wolf 630AB), classified as a dM3.5e visual binary system. Intermediate resolution spectra have been taken during four nights (2–5 April 2001) using the IDS spectrograph of the 2.5 m Isaac Newton Telescope (INT) (La Palma, Canary Islands, Spain). The V1054 Oph spectra show very strong emission lines even in its quiescent state. The analysis of the temporal evolution of the observed emission lines (from H_β to H₁₁ and the Ca II H and K lines) reveals four strong flares and several weak flares. We have studied in detail the behaviour of the chromospheric lines during the different phases (pre-flare, impulsive and gradual decay) of these flares. The observed flares last from ～25 to 95 min. The equivalent width of the H_β line changes by a factor up to ～2.3. Broad wings and asymmetric (red-shifted) lines are observed as well.