Dehydration kinetics of antigorite using in situ high-temperature infrared microspectroscopy

The dehydration kinetics of serpentine was investigated using in situ high-temperature infrared microspectroscopy. The analyzed antigorite samples at room temperature show relatively sharp bands at around 3,655–3,660 cm^?1 (band 1), 3,570–3,595 cm^?1 (band 2), and 3,450–3,510 cm^?1 (band 3). Band 1 corresponds to the Mg–OH bond, and bands 2 and 3 correspond to OH associated with the substitution of Al for Si. Isothermal kinetic heating experiments at temperatures ranging from 625 to 700 °C showed a systematic decrease of the OH band absorbance with heating duration. The one-dimensional diffusion was found to provide the best fit to the experimental data, and diffusion coefficients were determined with activation energies of 219 ± 37 kJ mol^?1 for the total water band area, 245 ± 46 kJ mol^?1 for band 1, 243 ± 57 kJ mol^?1 for band 2, and 256 ± 53 kJ mol^?1 for band 3. The results indicate that the dehydration process is controlled by one-dimensional diffusion through the tetrahedral geometry of serpentine. Fluid production rates during antigorite dehydration were calculated from kinetic data and range from 3 × 10^?4 to 3 × 10^?5  $ {\text{m}}_{\text{fluid}}^{ 3} \,{\text{m}}_{\text{rock}}^{ - 3} \,{\text{s}}^{ - 1} $ . The rates are high enough to provoke hydraulic rupture, since the relaxation rates of rocks are much lower than these values. The results suggest that the rapid dehydration of antigorite can trigger an intermediate-depth earthquake associated with a subducting slab.     

Estimation of ground response and local site effects for Vishakhapatnam,India

Natural Hazards - Ground motion intensity due to an earthquake changes as it disseminates through the soil media from bedrock to the surface. As the ground motion intensity and damage levels mainly...     

Relationship between growth of albite porphyroblasts and deformation in a sambagawa schist, Central Shikoku, Japan

Albite porphyroblasts in a basic schist of the Sambagawa metamorphic belt (Besshi—Bashi, Central Shikoku) show zonal variation of inclusions defined by inclusion-free mantles and inclusion-rich cores, though matrix minerals are partly incorporated in the outer zones of the mantles. From comparison of the crystallographic and dimensional fabrics of inclusion and matrix epidote, it has been concluded that the orientation of the principal axes of strain was different for the deformation of matrix fabrics and inclusion fabrics (fabrics produced before formation of cores). Inclusion amphibole in the cores belongs to the actinolite—common hornblende group, with Si content more than 7.0, whereas amphibole in the matrix and outer zones of mantles belongs to the common hornblende group, with Si content less than 7.1. This shows that the metamorphic temperature was higher during the phase of formation of the outer zones of the mantles than during that of the cores. The average direction of maximum growth of the mantles, which has been estimated from differences between the average shapes of porphyroblasts and those of cores, is parallel to the linear orientation of amphibole and epidote in the matrix. The average direction of minimum growth of the mantles coincides with the normal to the schistosity of the matrix. The mantles appear to be of the same generation as the matrix fabrics.     

Some clinopyroxenes from ultramafic inclusions in Dreiser Weiher,Eifel

Eight clinopyroxenes from wehrlites and clinopyroxenites and three clinopyroxenes of crystal lapilli in tuff of Dreiser Weiher in Eifel, Germany, have been separated and chemically analysed. One hornblende and two phlogopites from a wehrlite and clinopyroxenites have also been analysed. The rocks enclosing these inclusions are alkali basalts of basanite composition. The analysed clinopyroxenes contain considerable amounts of Al₂O₃ (3.87–10.84 wt%). The calculated Tschermak's component ranges from 5.9 to 18.4 mol per cent. All of the analysed clinopyroxenes are clearly different from chromian diopsides in lherzolite inclusions in basaltic rocks in Dreiser Weiher and other localities; the former has higher contents of total FeO, CaO and TiO₂ and lower contents of MgO and Cr₂O₃ than the latter. Two clinopyroxenes separated from apatite-bearing clinopyroxenites show high contents of Fe₂O₃ with about 2 per cent of Na₂O, indicating the presence of considerable amounts of acmite component in addition to Tschermak's component. The relative proportions of Al in the tetrahedral site and that in the octahedral site in the analysed clinopyroxenes are clearly different from those of the common igneous clinopyroxenes and eclogites, and similar to those of the clinopyroxenes from other inclusions in basaltic rocks and granulites. It is suggested that all the analysed clinopyroxenes and their host inclusions have crystallized from alkali basalt magmas in relatively deep levels of the continental crust.     

An assessment of uncertainties in VS profiles obtained from microtremor observations in the phased 2018 COSMOS blind trials

Journal of Seismology - Site response is a critical consideration when assessing earthquake hazards. Site characterization is key to understanding site effects as influenced by seismic site...     

A study on particle breakage behavior during pile penetration process using acoustic emission source location

Particle breakage is a common occurrence in granular systems when the external stress exceeds the individual particle strength.A large number of experimental evidences suggested that particle breakage may significantly influence the soil behavior.In the case of pile foundations,the subsoil below the pile tip experiences considerable high stress and consequently prone to break.Due to the lack of sufficient understanding on particle breakage mechanism,there is currently no consentaneous theoretical background for particle breakage analysis during the pile penetration process.This study aims to clarify the location of particle breakage and its evolving characteristics with the aid of acoustic emission(AE)source location method.The spatial distribution of AE hypocenters is interpreted to be associated with the mechanism of particle breakage.Results showed that the AE sources were not uniformly distributed,but concentrated within certain zones below the pile tip.This AE concentration zone was pushed downward with the advancing pile tip,and its distance from the real time pile tip position decreased after certain depth of pile penetration.The location of particle breakage interpreted from AE source location was verified with posttest excavations and the insights on the particle breakage evolution zone were further discussed.     

Stability of the Courses of the Warm Coastal Currents along the Kyushu Island Suggested by the Population Structure of the Japanese Turban Shell, Turbo (Batillus) Cornutus

The genetic structure of a population of the Japanese turban shell, Turbo (Batillus) cornutus at Sata-Misaki Point, on the southern coast of Kyushu Island, was determined on the basis of nucleotide sequences of mitochondrial DNA and compared with that of a population of the western coast of Kyushu Island. The significant genetic differentiation between these two populations suggests that the courses of the warm currents along the coast of the Kyushu Island have been relatively stable after the divergence between the two genetically distant groups of the Japanese turban shell, which was estimated to have occurred during some period in Pleistocene.     

Large areal extent of ultrahigh-pressure metamorphism in the Sulu ultrahigh-pressure terrane of East China: new implications from coesite and omphacite inclusions in zircon of granitic gneiss

Coesite and omphacite inclusions have been identified for the first time as minute inclusions in zircon from amphibolite-facies granitic orthogneiss in the Sulu ultrahigh-pressure (UHP) metamorphic terrane of eastern China by Raman spectroscopy and microprobe analyses. The occurrences of these minerals in the voluminous granitic gneiss of Sulu support a regional and pervasive UHP metamorphic event that predated regional amphibolitic retrogression. Taking into account the widespread discoveries of coesite in other lithologies, we thus conclude that a substantial crustal component in the Sulu UHP metamorphic terrane appears to have shared a common history of Triassic subduction to mantle depths and later exhumation.