Rare gases in a phlogopite nodule and a phlogopite-bearing peridotite in South African kimberlites

Rare gas isotopes in a phlogopite nodule and a phlogopite-bearing peridotite nodule in South African kimberlites were studied to examine the state of rare gases in the deep interior of the kimberlite region.Within the experimental error of 1 ～ 2%, rare gas isotopic compositions are atmospheric except for radiogenic⁴He and⁴⁰Ar. No excess¹²⁹Xe was observed.In phlogopite, Ne is more depleted, whereas the heavier rare gases are more enriched than the atmospheric rare gases relative to³⁶Ar.Together with other data these results suggest that the state of rare gases in the upper mantle of the South African kimberlite region might have been changed from the typical primitive mantle by a process such as mixing of crustal materials.     

A tidal front in winter influenced by river discharge

Water quality of Osaka Bay is greatly influenced by freshwater discharge from rivers, to the effect of salinity playing a major role in forming the stratification. The tidal front is expected to appear in such an area even in winter considering the theory of the formation of a tidal front. From the field observation, we recognized a tidal front in winter for the first time in Osaka Bay. The critical value of a parameter log(H/U ³) for generation of a tidal front is obtained as a function of river discharge and cooling effect through sea surface. Differences of nutrients (NH₄–N, PO₄–P) concentration across the front are not clear, probably because they are utilized by phytoplankton easily. But in (NO₂–N)+(NO₃–N), DIN, PP and T–P, there is a discontinuity structure across the front, even if the absolute value of concentration difference is small.     

Evolution and decay of a warm-core ring within the western subarctic gyre of the North Pacific,as observed by profiling floats

This study investigated temporal variations in the vertical structure and water properties of a warm-core ring that migrated into the western subarctic gyre of the North Pacific, based on analyses of temperature and salinity data derived from two profiling floats, together with shipboard and satellite observation data. The floats were initially deployed into cold and fresh Oyashio water in September 2003, and were entrained into a warm-core ring in October 2003, remaining within the ring until detrainment in December 2004. Drastic cooling and freshening of the upper core water of the ring were observed during the above entrainment of the floats with cold and fresh water into the ring, whereas moderate variations in structure and water properties were observed during a quasi-isolated phase from November 2003 to November 2004 when the ring did not experience major interactions with ambient hydrographic features. The upper part of the core water (upper core), with relatively warm/saline water above 26.6 σ _θ , was under the influence of the atmosphere in winter via the formation of a deep mixed layer exceeding 300 dB, and had a prominent pycnostad below the seasonal pycnocline from spring to autumn. In contrast, the lower core, with relatively cold and fresh water below 26.6 σ _θ , was not ventilated throughout the observation period. Isopycnal surfaces showed a shoaling trend of about 50 dB/year during the quasi-isolated phase, suggesting viscous decay over a timescale of several years. Markedly cold and thick water was also frequently observed within the ring, indicating the intrusion of water from the Sea of Okhotsk.     

Trace element concentrations in barramundi (Lates calcarifer) collected along the coast of Vietnam

We determined concentrations of 23 trace elements (TEs), and stable carbon and nitrogen isotope (δ¹³C and δ¹⁵N) signatures in barramundi (Lates calcarifer) specimens collected along the coast of Vietnam in the Northern (NCZ), Central (CCZ) and Southern (SCZ) zones in the period 2007–2010. A combination of δ¹³C and δ¹⁵N signatures provided insight into ontogenetic shifts in barramundi foraging choices. There were clear zone-dependent differences in Mn, As, Sr and Tl concentrations; levels of Tl were highest in the NCZ, As in the CCZ, and Mn and Sr in the SCZ. Lowest concentrations of Rb occurred in the NCZ, Bi was lowest in the CCZ, and Cd and Cs were lowest in the SCZ. δ¹⁵N values significantly increased with increasing Zn, Se, Sn and Cs. Concentrations of TEs in barramundi from Vietnam were below worldwide guidelines for human consumption.     

Assimilation of TOPEX/POSEIDON Altimeter Data with a Reduced Gravity Model of the Japan Sea

Sea level data measured by TOPEX/POSEIDON over the Japan Sea from 1993 to 1994 is analyzed by assimilation using an approximate Kalman filter with a 1.5 layer (reduced-gravity) shallow water model. The study aims to extract signals associated with the first baroclinic mode and to determine the extent of its significance. The assimilation dramatically improves the model south of the Polar Front where as much as 20 cm² of the observed sea level variance can be accounted for. In comparison, little variability in the northern cold water region is found consistent with the model dynamics, possibly due to significant differences in stratification.     

Re-Estimation of Annual Anthropogenic Carbon Input from Oyashio into North Pacific Intermediate Water

The annual transport of anthropogenic carbon (C_anth) to the North Pacific Intermediate Water (NPIW) from the Western Subarctic Gyre (WSG) has been re-estimated by using newly estimated Oyashio transport and C_anth concentration, the latter calculated by the recently-established “ΔC*” method with some modifications. Estimated annual C_anth transport through the nearshore Oyashio west of 146°E was 0.020 ± 0.010 GtC y⁻¹, closely approximating the previous estimation based on a 1-D model calibrated with the CFC vertical distribution. The present study, however, found that an additional 0.025 ± 0.010 GtC y⁻¹ of C_anth was transported into NPIW in the region east of 146°E. Total C_anth transport, 0.045 GtC y⁻¹, contributes about 35% of annual C_anth accumulation of the whole temperate North Pacific. This revised version was published online in July 2006 with corrections to the Cover Date.     

Food sources of the pearl oyster in coastal ecosystems of Japan: Evidence from diet and stable isotope analysis

We estimated the composition of two food sources for the cultured pearl oyster Pinctada fucata martensii using stable isotopes and stomach content analysis in the coastal areas of the Uwa Sea, Japan. The δ¹³C values of oysters (−17.5 to −16.8‰) were intermediate between that of particulate organic matter (POM, −20.2 to −19.1‰) and attached microalgae on pearl cages (−13.0‰). An isotope mixing model suggested that oysters were consuming 78% POM (mainly phytoplankton) and 22% attached microalgae. The attached microalgal composition of the stomach content showed a strong resemblance to the composition of that estimated through the isotope mixing model, suggesting preferential utilization of specific components is unlikely in this species. These results indicate that P. fucata martensii feed on a mixture of phytoplankton and attached microalgae, and that the attached microalgae on pearl cages can serve as an important additional food source.     

Polychlorinated biphenyl (PCB) concentrations and congener composition in masu salmon from Japan: A study of all 209 PCB congeners by high-resolution gas chromatography/high-resolution mass spectrometry (HRGC/HRMS)

We collected two subspecies of masu salmon: Oncorhynchus masou masou from four localities (southern Sea of Japan northward to Hokkaido) and O. masou ishikawae from upstream from Ise Bay close to a heavy industrial area. All 209 PCB congeners were analyzed using HRGC/HRMS. PCA ordination of congener concentrations divided data into three groups: (i) ssp. masou from Hokkaido, (ii) ssp. masou from the other regions and (iii) ssp. ishikawae. The highest ∑ PCB concentration (40.39 ng/wet wt) was in ssp. ishikawae followed by ssp. masou from southern waters; however the TEQ_{dioxin-like PCBs} was highest in ssp. masou from southern water (1.96 pg-TEQ_{dioxin-like PCBs}/g wet wt.) due to the high proportion of congener #126 in its complement (#126 has the highest toxic equivalency factor among congeners). There is likely a contamination source offshore in the southern Sea of Japan and/or along the migratory route of ssp. masou.