Trace element geochemistry of K-rich impact spherules from howardites

The howardite–eucrite–diogenite (HED) achondrites are a group of meteorites that probably originate from the asteroid Vesta. Howardites are complex polymict breccias that sometimes contain, in addition to various rock debris, impact melt glasses which show an impressive range of compositions. In this paper we report on the geochemistry and O isotopes of a series of 6 Saharan polymict breccias (4 howardites and 2 polymict eucrites), and on the trace element abundances of high-K impact spherules found in two of them, Northwest Africa (NWA) 1664 and 1769, which are likely paired.The high-K impact spherules found in the howardites NWA 1664 and NWA 1769 display remarkable trace element patterns. Compared to eucrites or howardites, they all show prominent enrichments in Cs, Rb, K, Li and Ba, strong depletion in Na, while the REE and other refractory elements are unfractionated. These features could not have been generated during impact melting of their host howardites, nor other normal HED target materials. The involvement of Na-poor rocks, and possibly rocks of granitic composition, appears likely. Although these lithologies cannot be well constrained at present, our results demonstrate that the surface of Vesta is certainly more diverse than previously thought. Indeed, despite the large number of available HED meteorites (about 1000 different meteorites), the latter are probably not sufficient to describe the whole surface of their parent body.     

Rare Earth Elements and Yttrium (REY) Geochemistry of Reefal Limestones in the Ordovician,Tarim Basin,NW China and their Paleoenvironment Implications

This study examines the rare earth elements and yttrium (REY) concentrations of twenty-five samples from the reef outcrop exposed along the Lianglitage Mountain in the Ordovician, Tarim Basin in China. The concentration analysis provides constraints on the paleoenvironment during reef deposition. Based on the detailed sedimentology and petrographic work, we divide the reef facies into four sub-facies: the base facies, reef-core facies, reef-flank facies, and sealing facies. The geochemical data (such as major and trace elements, carbon and oxygen isotopes, and REYs) are further used to study the coeval seawater characteristics as well as potential diagenesis overprints. The result indicated that the diagenesis has little effect on the REY patterns of the reefal limestones. The REY concentrations of the reefal limestones are overall low (ranging from 3.69 to 19.60 ppm, arithmetic mean=10.22 ppm, SD=5.4). The PAAS-normalized REY patterns are consistently flat compared to the typical well-oxidized, shallow marine water patterns. However, the light REE (LREE) depletions, positive La anomalies, negative Ce anomalies and positive Y anomalies, suggest that these reefal limestones are likely an indicative of contemporaneous seawater REY signals. The seawater-like Y/Ho ratios (average at 37.51) further support that REY signals in these limestones are likely a reflection of seawater with little diagenetic modifications. The low Y/Ho ratios presented only in the reef-flank facies and sealing facies are likely a suggestion of detrital contamination. Hence, this study confirms that REY patterns of the limestones at the base facies and reef-core facies can record ancient seawater information, and reefs can be used as a potential geochemical proxy for paleoenvironment studies throughout the Earth’s history.     

Environmental controls on the development of Mississippian microbial carbonate mounds and platform limestones in southern Montagne Noire (France)

Late Mississippian carbonates in southern Montagne Noire are dominantly domical to laterally‐accreted microbial mounds in some formations, as well as stratiform microbial limestones occurring in hundreds of olistoliths within a flysch basin, constituting pieces of a giant puzzle that are used to help reconstruct a platform in a region that is no longer preserved. Petrographic data of limestone samples from 14 continuous long sections of olistoliths have been analyzed statistically, using multivariate clustering (Q‐mode) of the components/matrix/cement and canonical correspondence analysis that allow the reconstruction of the environmental parameters of carbonate microbial communities in space and time. Clustering analysis separated microbial and non‐microbial facies. The calculation of indices along the various axes from canonical correspondence analysis allows recognition of the controlling factors of the mounds and microbial growth as being turbidity, light penetration, bathymetry and storms. Turbidity and light penetration are the primary factors controlling the morphology of the microbial limestones. Representation of the light penetration and bathymetry indices on the stratigraphical sections defines two vertical environmental gradients. Light penetration can be subdivided into euphotic, euphotic–dysphotic and dysphotic‐aphotic conditions. The representation of the bathymetry allows the subdivision of samples into a deeper outer ramp, external mid‐ramp and internal mid‐ramp. The curve distance from the section base = f (index) suggests a cyclicity for the platform that cannot be compared with the onlap curve defined from other cratonic areas (Moscow Basin), and thus the cyclic succession of the Montagne Noire is interpreted to have been mostly tectonically‐controlled. Integration of the data allowed the reconstruction of the original Mississippian carbonate platform, where, up to the Mikhailovian, it appears to correspond to a platform morphology, with narrow shallow water facies and wide turbiditic systems, whereas the width of shallow‐water settings expanded during the Venevian to the Protvian, forming a ramp or distally‐steepened ramp with widespread microbial limestones.     

Auklet (Charadriiformes: Alcidae, Aethia spp.) chick meals from the Aleutian Islands, Alaska, have a very low incidence of plastic marine debris

The ingestion of plastic marine debris is a chronic problem for some of the world’s seabird species, contributing to reduced chick survival, population declines, and deposition of contaminants via absorption in birds’ gastrointestinal tract. We analysed the frequency of ingested plastic in chick meals delivered by adults in four species of auklet - Crested (Aethia cristatella), Least (A. pusilla), Parakeet (A. psittacula), and Whiskered (A. pygmaea) - from three breeding colonies in the Aleutian Islands, Alaska, USA over a 14-year period from 1993 to 2006. Among 2541 chick meals, we found plastic in only one - from a Whiskered Auklet on Buldir Island in 1993. While adult Parakeet Auklets have a high frequency of plastic ingestion (over 90%), no chick meals contained plastic. Unlike other seabirds, the planktivorous auklets do not appear to offload plastic to their chicks, and we conclude that auklet chicks are probably at a low risk of contamination from plastic debris.     

Cristobalite in the 2011–2012 Cordón Caulle eruption (Chile)

Cristobalite is a low-pressure high-temperature polymorph of SiO₂ found in many volcanic rocks. Its volcanogenic formation has received attention because (1) pure particulate cristobalite can be toxic when inhaled, and its dispersal in volcanic ash is therefore a potential hazard; and (2) its nominal stability field is at temperatures higher than those of magmatic systems, making it an interesting example of metastable crystallization. We present analyses (by XRD, SEM, EPMA, Laser Raman, and synchrotron μ-cT) of representative rhyolitic pyroclasts and of samples from different facies of the compound lava flow from the 2011–2012 eruption of Cordón Caulle (Chile). Cristobalite was not detected in pyroclasts, negating any concern for respiratory hazards, but it makes up 0–23 wt% of lava samples, occurring as prismatic vapour-deposited crystals in vesicles and/or as a groundmass phase in microcrystalline samples. Textures of lava collected near the vent, which best represent those generated in the conduit, indicate that pore isolation promotes vapour deposition of cristobalite. Mass balance shows that the SiO₂ deposited in isolated pore space can have originated from corrosion of the adjacent groundmass. Textures of lava collected down-flow were modified during transport in the insulated interior of the flow, where protracted cooling, additional vesiculation events, and shearing overprint original textures. In the most slowly cooled and intensely sheared samples from the core of the flow, nearly all original pore space is lost, and vapour-deposited cristobalite crystals are crushed and incorporated into the groundmass as the vesicles in which they formed collapse by strain and compaction of the surrounding matrix. Holocrystalline lava from the core of the flow achieves high mass concentrations of cristobalite as slow cooling allows extensive microlite crystallization and devitrification to form groundmass cristobalite. Vapour deposition and devitrification act concurrently but semi-independently. Both are promoted by slow cooling, and it is ultimately devitrification that most strongly contributes to total cristobalite content in a given flow facies. Our findings provide a new field context in which to address questions that have arisen from the study of cristobalite in dome eruptions, with insight afforded by the fundamentally different emplacement geometries of flows and domes.     

Sediment transport in ice-covered channels

The existence of ice cover has important effects on sediment transport and channel morphology for rivers in areas with an annual occurrence of an ice season. The interaction of sediment transport and s...     

Post-glacial climate change and its effect on a shallow dimictic lake in Nova Scotia,Canada

A high-resolution, multi-proxy lake sediment record was used to establish the timing of Holocene environmental change in Canoran Lake, southwest Nova Scotia, Canada. Proxies include %C, δ¹⁵N, δ¹³C, HI, magnetic susceptibility, and pollen. Canoran Lake is a small, shallow (11 m) lake with two ephemeral inlets and an outlet. The site was deglaciated at ca. 15,300 cal (calibrated) year BP and elevated %C values indicate the establishment of a productive aquatic environment that is consistent with Allerød warming. The Allerød was interrupted by rapid air temperature cooling during the Younger Dryas (ca. 12,900–11,600 cal year BP). The Early Hypsithermal (ca. 11,600–8,500 cal year BP) was relatively warm and wet. A slight increase in clastic input occurred between 9,100 and 8,500 cal year BP but δ¹⁵N, δ¹³C, and HI values imply that the lithostratigraphic response may not be indicative of climate-induced change. The strong proxy response between 8,500 and 8,000 cal year BP was likely due to cooling and drying coincident with the 8.2 k year event. The climate was relatively warm and dry during the Late Hypsithermal (ca. 8,000–3,500 cal year BP). None of the proxies’ exhibit notable change during the 5,500 cal year BP hemlock decline, indicating that ecological change was likely due to a pathogen attack. Post-Hypsithermal (modern) climate was characterized by an increase in precipitation and a decrease in air temperatures from ca. 3,500 to 700 cal year BP (top of core).     

On the Impact of Permeability Heterogeneity on SAGD Steam Chamber Growth

Evolution of steam assisted gravity drainage (SAGD) steam chambers in heavy oil and bitumen reservoirs is tied to uniformity of steam pressure and quality along the length of the perforated interval of the well and reservoir geology and fluid properties adjacent to the well. If the reservoir geology has poor permeability at an interval along the wellpair, then steam delivery to and fluids production from the reservoir is not uniform. If the steam is well distributed throughout the injection well, then the key factor for a uniform steam chamber along the wellpair is reservoir geology. This is especially important in highly heterogeneous, variable thickness reservoirs where geology and reservoir oil composition may vary significantly over the length of a wellpair. Heterogeneity of a growing SAGD steam chamber is related to heterogeneity of the underlying geology. In this study the oil sands models are geostatistically populated to model spatial heterogeneity of permeability. The temperature profile (chamber growth), steam chamber height, conductive, convective, and total heat fluxes have been examined in each case. The results reveal that the length scales of steam chamber growth depend on the permeability heterogeneity. This provides a means to decide length scales for placement of in-well control devices in steam injectors in SAGD.     

The trace element compositions of S-type granites: evidence for disequilibrium melting and accessory phase entrainment in the source

Within individual plutons, the trace element concentrations in S-type granites generally increase with maficity (total iron and magnesium content and expressed as atomic Fe + Mg in this study); the degree of variability in trace element concentration also expands markedly with the same parameter. The strongly peraluminous, high-level S-type granites of the Peninsular Pluton (Cape Granite Suite, South Africa) are the product of biotite incongruent melting of a metasedimentary source near the base of the crust. Leucogranites within the suite represent close to pure melts from the anatectic source and more mafic varieties represent mixtures of melt and peritectic garnet and ilmenite. Trace elements such as Rb, Ba, Sr and Eu, that are concentrated in reactant minerals in the melting process, show considerable scatter within the granites. This is interpreted to reflect compositional variation in the source. In contrast, elements such as LREE, Zr and Hf, which are concentrated within refractory accessory phases (zircon and monazite), show well-defined negative correlations with increasing SiO₂ and increase linearly with increasing maficity. This is interpreted to reflect coupled co-entrainment of accessory minerals and peritectic phases to the melt: leucocratic rocks cannot have evolved from the more mafic compositions in the suite by a process of fractional crystallisation because in this case they would have inherited the zircon-saturated character of this hypothetical earlier magma. Trace element behaviour of granites from the Peninsular Pluton has been modelled via both equilibrium and disequilibrium trace element melting. In the disequilibrium case, melts are modelled as leaving the source with variable proportions of entrained peritectic phases and accessory minerals, but before the melt has dissolved any accessory minerals. Thus, the trace element signature of the melt is largely inherited from the reactants in the melting reaction, with no contribution from zircon and monazite dissolution. In the equilibrium case, melt leaves the source with entrained crystals, after reaching zircon and monazite saturation. A significant proportion of the rocks of the Peninsular Pluton have trace element concentrations below those predicted by zircon and monazite saturation. In the case of the most leucocratic rocks all compositions are zircon undersaturated; whilst the majority of the most mafic compositions are zircon oversaturated. However, in both cases, zircon is commonly xenocrystic. Thus, the leucocratic rocks represent close to pure melts, which escaped their sources rapidly enough that some very closely match the trace element disequilibrium melting model applied in this study. Zircon dissolution rates allow the residency time for the melt in the source to be conservatively estimated at less than 500 years.     

Occurrence of gorgosterol in diatoms of the genus Delphineis

The presence of the C₃₀ sterol gorgosterol (22,23-methylene-23,24-dimethylcholest-5-en-3ß-ol) and its analogues in some marine and freshwater environments is generally associated with invertebrate animals or dinoflagellates since there have been no reports of them in other microalgal classes. Here we show that two unialgal cultures of different species of the marine diatom Delphineis contain gorgosterol in addition to sterols more commonly found in diatoms. Our findings suggest that some reports of gorgosterol in seawater and marine sediments may well have an origin, at least in part, from diatoms.