What was the Volatile Composition of the Planetesimals that Formed the Earth?

Is there an asteroid type or meteorite class that best exemplifies the materials that went into the Earth? Carbonaceous chondrites were once the objects of choice, and in the minds of many this choice is still valid. However, the origin of primitive chondritic meteorites is unclear. At the extremes they could either be fragments of very small parent bodies that never became hot enough to undergo geochemical modification other than mild lithification, or remnants of the uppermost layers of a body that had undergone a significant degree of internal differentiation, while the top layers remained cool due to radiative heat loss or loss of volatiles to space. This latter case is problematic if one considers these objects as precursors to the Earth since the timescale for the evolution of such a small body could be longer than the timescale for the accretion of the Earth. Large-scale circulation of materials in the primitive solar nebula could greatly increase the diversity of materials near 1 AU while also making the entire inner solar system both more homogeneous and much wetter than previously expected. The total mass of the nebula is an important, but poorly constrained factor controlling the growth of planetesimals. There is also a selection effect that dominates our sampling of the planetesimals that may have existed 4.5 billion years ago; namely, small fragile bodies are more likely to be lost from the system or ground down by collisions between small bodies, yet these are precisely those that may have dominated the population from which the Earth accreted. The composition of these aggregates could have played a very important role in the early chemical evolution of the Earth. In particular, the Earth may have been much wetter and richer in hydrocarbons and other reducing materials than previously suspected.     

Mining Sand on the Continental Shelf of the Atlantic and Gulf Coasts of the U.S.

Essentially all marine mining along the East and Gulf coasts of the U.S. is for sand used in beach nourishment projects. The current minimal commercial production of sand and aggregate may increase as conventional, on-shore sources become exhausted or are lost to competing land use. Studies published in the late 1990s document a history of nearly 900 individual episodes of beach nourishment having a total cost in excess of $2 × 10⁹ with several hundred million cubic meters of sand placed along over 645 km (400 mi) of shoreline. As exemplified by studies in Florida, prospecting for sand for use in beach nourishment can begin before site specific needs are identified. A full prospecting starts with assimilation of pertinent literature, local knowledge, and an understanding of the geologic and geomorphic settings in which suitable deposits of sand or aggregate occur. High-resolution seismic profiling follows to outline the three dimensional extent of the sand bodies. Finally, vibratory cores are collected to verify the interpretation of the seismic data and to provide samples for geotechnical, especially granulometric, analyses. The actual method of production often is determined by the local availability of different dredge types. Because the mining of marine sands disturbs meaningful areas of the sea floor, environmental concerns must be considered. While it generally is assumed that dredged areas will be left barren, it is possible to assess the likely rate of recolonization. The disruption of bottom habitat also can affect feeding and spawning areas for fishes and other organisms. Alteration in local currents and wave transformation processes need to be modeled and their consequences assessed.     

Persistence of a Groundwater Contaminant Plume after Hydraulic Source Containment at a Chlorinated‐Solvent Contaminated Site

The objective of this study was to characterize the behavior of a groundwater contaminant (trichloroethene, TCE) plume after implementation of a source‐containment operation at a site in Arizona. The plume resides in a quasi‐three‐layer system comprising a sand/gravel unit bounded on the top and bottom by relatively thick silty clayey layers. The system was monitored for 60 months beginning at start‐up in 2007 to measure the change in contaminant concentrations within the plume, the change in plume area, the mass of the contaminant removed, and the integrated contaminant mass discharge (CMD). The concentrations of TCE in groundwater pumped from the plume extraction wells have declined significantly over the course of operation, as have concentrations for groundwater sampled from 40 monitoring wells located within the plume. The total CMD associated with operation of the plume extraction wells peaked at 0.23 kg/d, decreased significantly within 1 year, and thereafter began an asymptotic decline to a current value of approximately 0.03 kg/d. Despite an 87% reduction in contaminant mass and a comparable 87% reduction in CMD for the plume, the spatial area encompassed by the plume has decreased by only approximately 50%. This is much less than would be anticipated based on ideal flushing and mass‐removal behavior. Simulations produced with a simplified three‐dimensional (3D) numerical model matched reasonably well to the measured data. The results of the study suggest that permeability heterogeneity, back diffusion, hydraulic factors associated with the specific well field system, and residual discharge from the source zone are all contributing to the observed persistence of the plume, as well as the asymptotic behavior currently observed for mass removal and for the reduction in CMD.     

On recording sea surface elevation with accelerometer buoys: lessons from ITOP (2010)

Measurements of significant wave height are made routinely throughout the world’s oceans, but a record of the sea surface elevation (η) is rarely kept. This is mostly due to memory limitations on data, but also, it is thought that buoy measurements of sea surface elevation are not as accurate as wave gauges mounted on stationary platforms. Accurate records of η which contain rogue waves (defined here as an individual wave at least twice the significant wave height) are of great interest to scientists and engineers. Using field data, procedures for tilt correcting and double integrating accelerometer data to produce a consistent record of η are given in this study. The data in this study are from experimental buoys deployed in the recent Impact of Typhoons on the Ocean in the Pacific (ITOP) field experiment which occurred in 2010. The statistics from the ITOP buoys is under that predicted by Rayleigh theory, but matches the distributions of Boccotti and others (Tayfun and Fedele) (Ocean Eng 34:1631-1649, 2007). Rogue waves were recorded throughout the experiment under various sea state conditions. Recommendations, as a result of lessons learned during ITOP, are made for the routine recording of η which may not add significantly to the existing data burden. The hope is that we might one day collect a worldwide database of rogue waves from the existing buoy network, which would progress our understanding of the rogue wave phenomenon and make work at sea safer.     

Simulating the diurnal cycle of rainfall in global climate models: resolution versus parameterization

The effects of horizontal resolution and the treatment of convection on simulation of the diurnal cycle of precipitation during boreal summer are analyzed in several innovative weather and climate model integrations. The simulations include: season-long integrations of the Non-hydrostatic Icosahedral Atmospheric Model (NICAM) with explicit clouds and convection; year-long integrations of the operational Integrated Forecast System (IFS) from the European Centre for Medium-range Weather Forecasts at three resolutions (125, 39 and 16 km); seasonal simulations of the same model at 10 km resolution; and seasonal simulations of the National Center for Atmospheric Research (NCAR) low-resolution climate model with and without an embedded two-dimensional cloud-resolving model in each grid box. NICAM with explicit convection simulates best the phase of the diurnal cycle, as well as many regional features such as rainfall triggered by advancing sea breezes or high topography. However, NICAM greatly overestimates mean rainfall and the magnitude of the diurnal cycle. Introduction of an embedded cloud model within the NCAR model significantly improves global statistics of the seasonal mean and diurnal cycle of rainfall, as well as many regional features. However, errors often remain larger than for the other higher-resolution models. Increasing resolution alone has little impact on the timing of daily rainfall in IFS with parameterized convection, yet the amplitude of the diurnal cycle does improve along with the representation of mean rainfall. Variations during the day in atmospheric prognostic fields appear quite similar among models, suggesting that the distinctive treatments of model physics account for the differences in representing the diurnal cycle of precipitation.     

Compositions of four unusual CM or CM-related Antarctic chondrites

To identify chemical group affinities and infer the occurrence of thermal metamorphism or aqueous alteration in their histories, we quantified 43 trace elements in the CM or CM-related Antarctic carbonaceous chondrites EET 96010, LAP 02277, MET 01070, and WIS 91600. We also analyzed LAP 02206, a CV chondrite, to add to our comparison database. We present whole-rock oxygen isotope data for LAP 02206, LAP 02277, and MET 01070 to complement our trace element results. With these data, we confirm the CV classification of LAP 02206 and CM or CM-like classification for the other four chondrites in this study. On the basis of moderately volatile element content, our results show that EET 96010 experienced open-system heating, while any heating LAP 02277 and MET 01070 may have experienced was in a chemically closed-system. WIS 91600, on a trace element basis, appears to be CM-like material. Our analyses support the idea that CM material has experienced a wide variety of post-accretionary processing.     

Petrogenesis of basalt–trachyte lavas from Olmoti Crater, Tanzania

Olmoti Crater is part of the Plio-Pleistocene Ngorongoro Volcanic Highland (NVH) in northern Tanzania to the south of Gregory Rift. The Gregory Rift is part of the eastern branch of the East African Rift System (EARS) that stretches some 4000 km from the Read Sea and Gulf of Aden in the north to the Zambezi River in Mozambique. Here, we (1) characterize the chemistry and mineral compositions of lavas from Olmoti Crater, (2) determine the age and duration of Olmoti volcanic activity through ⁴⁰Ar/³⁹Ar dating of Olmoti Crater wall lavas and (3) determine the genesis of Olmoti lavas and the relationship to other NVH and EARS volcanics and (4) their correlation with volcanics in the Olduvai and Laetoli stratigraphic sequences.Olmoti lavas collected from the lower part of the exposed crater wall section (OLS) range from basalt to trachyandesite whereas the upper part of the section (OUS) is trachytic. Petrography and major and trace element data reflect a very low degree partial melt origin for the Olmoti lavas, presumably of peridotite, followed by extensive fractionation. The ⁸⁷Sr/⁸⁶Sr data overlap whereas Nd and Pb isotope data are distinct between OLS and OUS samples. Interpretation of the isotope data suggests mixing of enriched mantle (EM I) with high-μ-like reservoirs, consistent with the model of Bell and Blenkinsop [Bell, K., Blenkinsop, J., 1987. Nd and Sr isotopic compositions of East African carbonatites: implications for mantle heterogeneity. Geology 5, 99–102] for East African carbonatite lavas. The isotope ratios are within the range of values defined by Oceanic Island Basalt (OIB) globally and moderate normalized Tb/Yb ratios (2.3–1.6) in these lavas suggest melting in the lithospheric mantle consistent with other studies in the region.⁴⁰Ar/³⁹Ar incremental-heating analyses of matrix and anorthoclase separates from Olmoti OLS and OUS lavas indicate that volcanic activity was short in duration, lasting 200 kyr from 2.01 ± 0.03 Ma to 1.80 ± 0.01 Ma. The age of Olmoti activity overlaps with ages reported for Ngorongoro Caldera, implying contemporaneous activity of multiple NVH volcanic centers during part of the eruption interval.Olmoti is considered the source for the bulk of interbedded volcanics and volcaniclastic deposits that comprise much of the upper Bed I section of nearby Olduvai Gorge, and part of the Laetoli sequence, both known for their well preserved fossils and archaeological remains. Age and chemical data reported here are compatible with those derived from tephra and lava interbedded in Bed I at Olduvai Gorge and from the Olpiro Beds at Laetoli.     

A refractory Ca-SiO-H2-O2 vapor condensation experiment with implications for calciosilica dust transforming to silicate and carbonate minerals

Condensates produced in a laboratory condensation experiment of a refractory Ca-SiO-H₂-O₂ vapor define four specific and predictable deep metastable eutectic calciosilica compositions. The condensed nanograins are amorphous solids, including those with the stoichiometric CaSiO₃ pyroxene composition. In evolving dust-condensing astronomical environments they will be highly suitable precursors for thermally supported, dust-aging reactions whereby the condensates form more complex refractory silicates, e.g., diopside and wollastonite, and calcite and dolomite carbonates. This kinetically controlled condensation experiment shows how the aging of amorphous refractory condensates could produce the same minerals that are thought to require high-temperature equilibrium condensation. We submit that evidence for this thermal annealing of dust will be the astronomical detection of silica (amorphous or crystalline) that is the common, predicted, by-product of most of these reactions.     

Stratigraphic analysis of the northern polar layered deposits of Mars: Implications for recent climate history

We examine the stratigraphy of the polar layered deposits (PLD) within the north polar cap of Mars to assess its layer continuity, correlations, cyclicity and structure and implications for the recent climate record. PLD sequences characterized using Fourier analysis and curve shape matching algorithms show that layers correlate throughout the upper part of the PLD. We tested for cyclicity and found that the uppermost ∼300 m contain a dominant wavelength layer packet of ∼30 m, interpreted to be a climate signal related to the 51 kyr precession cycle. Directly below this region we document a section of polar layered deposits ∼100 m thick without a dominant periodic signal; this is interpreted to represent a phase of low net accumulation and lag deposits formed during the last ice age, about 0.5-2 Ma ago. We further analyzed layer structure by combining these results with three-dimensional determinations of layer orientation (strike and dip) to assess the internal stratigraphy of the PLD and its implications for polar history. We show that individual layers within the PLD stratigraphy are not horizontal (no dip) but rather show broad variation in elevation with distance. Correlations suggest that the layer strikes and dips broadly follow present cap surface topography. Local variations in layer orientations in the vicinity of the troughs suggest that (1) trough structures were present at the time of layer accumulation and (2) dips may have been influenced by ice flow and/or static ice accumulation in the presence of preexisting troughs. This new information favors models in which the troughs are long-term structures of the PLD rather than (1) recently eroded into the PLD, or (2) very active and laterally migrating around the PLD. Our results strongly support the hypothesis that significant volumes of polar volatiles are mobilized and transported equator-ward during periods of increased obliquity. Our results predict that the upper ∼300 m of the north polar PLD accumulated in the last 500 ka, yielding net accumulation rates of ∼0.06 cm/yr. The presence and albedo of the no periodic signal zone suggest that polar net accumulation rates are very low and that dust rich lag deposits form during periods of sustained high obliquity. Layer sequences in the south polar and equatorial regions are examined and compared to those in the north; rhythmic sequences are observed in both regions but no direct correlations to the dominant signals of the north polar deposits have yet been found. These new techniques and observations provide a paradigm for further analysis of recent polar history (the upper kilometer of the record) and a basis for extending assessments to the lower part of the polar deposits and to other cyclic deposits in the geological record of Mars.     

Formation and evolution of Lakshmi Planum, Venus: Assessment of models using observations from geological mapping

Detailed geological analysis of the Lakshmi Planum region of western Ishtar Terra results in the establishment of the sequence of major events during the formation and evolution of western Ishtar Terra, an important and somewhat unique area on Venus characterized by a raised volcanic plateau surrounded by distinctive folded mountain belts, such as Maxwell Montes. These mapping results and the stratigraphic and structural relationships provide a basis for addressing the complicated problem of Lakshmi Planum formation and for testing the suite of models previously proposed to explain this structure. We review and classify previous models of formation for western Ishtar Terra into “downwelling” models (generally involving convergence and underthrusting) and “upwelling” models (generally involving plume-like upwelling and divergence). The interpreted nature of units and the sequence of events derived from geological mapping are in contrast to the predictions of the divergent models. The major contradictions are as follows: (1) The very likely presence of an ancient (craton-like) tessera massif in the core of Lakshmi, which is inconsistent with the model of formation of Lakshmi due to rise and collapse of a mantle diapir; (2) The absence of rift zones in the interior of Lakshmi that are predicted by the divergent models; (3) The apparent migration of volcanic activity toward the center of Lakshmi, whereas divergent models predict the opposite trend; (4) The abrupt cessation of ridges of the mountain ranges at the edge of Lakshmi Planum and propagation of these ridges over hundreds of kilometers outside Lakshmi; the divergent models predict the opposite progression in the development of major contractional features. In contrast, convergent models of formation and evolution of Lakshmi Planum appear to be more consistent with the observations and explain this structure by collision and underthrusting/subduction of lower-lying plains with the elevated and rigid block of tessera. These models are capable of explaining formation of the major features of western Ishtar (for example, the mountain belts), the sequences of events, and principal volcanic and tectonic trends during the evolution of Lakshmi. To explain the pronounced north-south asymmetry of Lakshmi these models need to consider the likelihood that the major focal points of collision are at the north and north-west margins of the plateau. We note that pure downwelling models, however, face three important difficulties: (1) The possibly unrealistically long time span that appears to be required to produce the major features of Lakshmi; (2) The strong north-south asymmetry of the Planum; the pure downwelling models predict the formation of a more symmetrical structure; and (3) The absence of radial contractional structures (arches and ridges) in the interior of Lakshmi that would represent the predictions of the downwelling models.