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141.
This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies. 相似文献
142.
F. Molenkamp 《国际地质力学数值与分析法杂志》1991,15(3):147-168
To increase the insight into the phenomenon of liquefaction a theoretical study has been performed of material instability for undrained behaviour. Material instability concerns the instability of an equilibrium state of an infinite homogeneous solid for both uniform deformation and shear-band generation. In this paper shear-band generation is considered. In a companion paper the case of uniform deformation is elaborated and combined with the current results. In this paper it is shown that, for a contractant material, shear-band generation is accelerated by decreasing the drainage. 相似文献
143.
The axisymmetric elastic response of circular footings and anchor plates in a linearly non-homogeneous elastic soil is analysed. It is assumed that footings/anchors are flexible and subjected to axisymmetric vertical loads. The response of the footing/anchor is modelled by using the classical Poisson–Kirchhoff thin plate theory. A variational technique is used to analyse the interaction problem. A representation for the contact stress is established by using a fundamental solution corresponding to a unit vertical pressure acting over an annular region in the interior of the non-homogeneous soil. The fundamental solution can be derived by using rigorous analytical procedures. The influence of the footing flexibility and the degree of soil non-homogeneity on the displacements, bending moments and contact stresses of a surface footing is examined over a wide range of governing parameters. In the case of anchor plates the influence of depth of embedment, degree of soil non-homogeneity and anchor flexibility on the anchor displacement is investigated. 相似文献
144.
Richard T. Jones Jim D. Marshall Stephen F. Crowley Alan Bedford Nigel Richardson Jan Bloemendal Frank Oldfield 《第四纪科学杂志》2002,17(4):329-340
A lacustrine carbonate sequence from Hawes Water, Lancashire, UK, has been studied using stable isotopic, lithological, pollen and mineral magnetic analysis. The data reveal four abrupt climatic oscillations in the Late‐glacial Interstadial leading up to the onset of the Loch Lomond Stadial. The data also point to climatic warming relatively early within the stadial, ca. 12 500 GRIP yr, prior to the onset of the Holocene. The oxygen isotope record is taken as a signature of climate forcing against which the response of the lake‐system can be monitored. By adopting this approach it is revealed that the response of the biological system to the rapid climatic oscillations is non‐linear and primarily a function of the antecedent conditions. A significant end‐Devensian isotopic excursion (A) is matched by only minor changes in the cold‐adapted floras and faunas. During the warmer interstadial, the response of the biological ecosystem (events B–D) is clearly influenced by thresholds: major changes in the catchment vegetation associated with relatively minor oscillations in the isotopic signature. The stratigraphical patterns reveal significant lag effects between the onset of climate deterioration and resulting changes in vegetation. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
145.
Summary
Silica-undersaturated phlogopite schists from the Cackleberry Metamorphics, Arunta Inlier, central Australia, preserve relatively
low-temperature sapphirine-bearing parageneses that developed during low-pressure upper amphibolite facies metamorphism. Peak
metamorphic phlogopite–cordierite–sapphirine assemblages are interpreted to have formed during the same event recorded in
nearby metapelites, at c.3 kbar and 650–700 °C. Initial cooling of the terrain resulted in the breakdown of sapphirine to corundum–chlorite–phlogopite
and corundum–spinel–chlorite assemblages. Further retrogression at greenschist facies conditions resulted in the replacement
of sapphirine by diaspore–chlorite intergrowths. The reaction textures are consistent with a near-isobaric heating-cooling
path at low-pressure, and provide evidence for the stability of sapphirine at c.700 °C at low pressures in rocks of an appropriate Mg- and Fe3+-rich bulk composition.
Received August 15, 2001 accepted December 27, 2001 相似文献
146.
147.
148.
Jonathan S. Price 《水文研究》1994,8(2):167-177
Over an oceanic peatland, the concentration of Na in fog averaged 38.1 mgl?1 compared with 1.8 mgl?1 in rain, resulting in a significant flux of mineral elements to the surface. Between 16 May and 20 June 1990 the average mass flux of Na to the bog surface by fog, rain, and dry deposition was 21.9, 10.4 and 7.0 mg m?2 d?1. There was little long-term storage of Na within the peatland system, where Na losses measured in stream runoff averaged 34.8 mg m2 d?1, and deep groundwater losses 4 mg m?2 d?1. Calcium and Mg were preferentially retained in the organic soil, whereas K was relatively mobile. Potassium tended to become concentrated in the unsaturated zone. Stream runoff had a consistently higher pH than groundwater, corresponding to higher Ca and Mg concentrations, which may have been from mineral sources in the headwater ponds. Otherwise, the stream water chemistry was closely related to groundwater in the upper layers of the peat deposit. 相似文献
149.
Micro- and non-crystalline opals, chalcedony and flint show diffuse small angle neutron scattering (SANS). Precious opals give rise to two additional intensity maxima at very small scattering angles which are due to Bragg reflections from the closest packed non-crystalline silica spheres. A small angle texture diagram reveals that the closest packing is faulty. Synthetic non-crystalline opals yield much less intense small angle scattering due to lower contrast between silica spheres and interstitial cement or particles; in this case intensity maxima were not observed. The outer part of the scattering curves of opal-CT and microcrystalline quartz deviates from Porod's law. The specific surface of natural non-crystalline opals ranges from 0.006 to 0.018 nm–1. In microcrystalline opals, the specific surface is about 10 times larger than in non-crystalline opals. 相似文献
150.