Effects of biochar, cow bone, and eggshell on Pb availability to maize in contaminated soil irrigated with saline water

Toxicity of heavy metals adversely affects environment and human health. Organic materials derived from natural matters or wastes have been applied to soils to reduce the mobility of contaminants such as heavy metals. However, the application of cow bone powder (CB), biochar (BC), and eggshell powder (ES) is rarely investigated for the reduction of Pb bioavailability in soils irrigated with saline water. The objective of this study was to assess the effectiveness of CB, BC, and ES additions as immobilizing substances on Pb bioavailability in shooting range soil irrigated with deionized and saline water. Each additive of CB, BC, and ES at 5 % (w/w) was mixed with soils and then the deionized and saline water were irrigated for 21 days. With deionized water irrigation, the soils treated with CB, BC, and ES exhibited higher pH when compared with saline water irrigation. With saline water irrigation, the electrical conductivity, water-soluble anions, and cations were significantly increased in soils treated with CB, BC, and ES. The water-soluble Pb in soils treated with CB, BC, and ES was significantly decreased with saline water irrigation. On the other hand, the water-soluble Pb in soil treated with CB was increased with deionized water irrigation. Only BC with saline water irrigation decreased the Pb concentration in maize shoots.     

Strategically Locating Wildlife Crossing Structures for Florida Panthers Using Maximal Covering Approaches

Crossing structures are an effective method for mitigating habitat fragmentation and reducing wildlife‐vehicle collisions, although high construction costs limit the number that can be implemented in practice. Therefore, optimizing the placement of crossing structures in road networks is suggested as a strategic conservation planning method. This research explores two approaches for using the maximal covering location problem (MCLP) to determine optimal sites to install new wildlife crossing structures. The first approach is based on records of traffic mortality, while the second uses animal tracking data for the species of interest. The objective of the first is to cover the maximum number of collision sites, given a specified number of proposed structures to build, while the second covers as many animal tracking locations as possible under a similar scenario. These two approaches were used to locate potential wildlife crossing structures for endangered Florida panthers (Puma concolor coryi) in Collier, Lee, and Hendry Counties, Florida, a population whose survival is threatened by excessive traffic mortality. Historical traffic mortality records and an extensive radio‐tracking dataset were used in the analyses. Although the two approaches largely select different sites for crossing structures, both models highlight key locations in the landscape where these structures can remedy traffic mortality and habitat fragmentation. These applications demonstrate how the MCLP can serve as a useful conservation planning tool when traffic mortality or animal tracking data are available to researchers.     

Flows within the Ekman layer during spin-up of a thermally stratified fluid

Abstract

Finite-difference numerical solutions were obtained to present the flow and temperature field details within the transient Ekman layer during spin-up of a thermally stratified fluid in a cylinder. This complements the earlier studies on stratified spin-up which examined the flows in the interior core region. As the stratification increases, the following changes in the flow field are noticeable. The radial velocity in the Ekman layer decreases in magnitude. The azimuthal flows adjust smoothly from the interior region to the endwall boundary, and the Ekman layer in the azimuthal flow field fades. Vertical motions are inhibited, resulting in a weakened Ekman pumping. The axial vorticity field behaves similarly to the azimuthal flows. The temperature deviation from the equilibrium profile decreases, and the heat transfer flux from the endwall to the fluid decreases. The thickness of the thermal layer is larger than the velocity layer thickness. Illustrative comparisons of the relative sizes of the terms in the governing equations are conducted in order to assess the stratification effect in the adjustment process of the fluid.     

Electric charge and magnetic flux on rotating black holes in a force-free magnetosphere

The electric charge on rotating black holes is calculated to be ∼ BJ in the force-free configuration of Ghosh, with a horizon flux of ∼ BM ². This charge is gravitationally weak for B ∼10¹⁵ G , so that the Kerr metric applies. Being similar to the electric charge of a magnetar, both electric charge and magnetic flux should be, in sign and order of magnitude, continuous during stellar collapse into a black hole. Extraction of the rotational energy from newly formed black holes may proceed by interaction with the magnetic field.     

Effect of doubling the ensemble size on the performance of ensemble prediction in the warm season using MOGREPS implemented at the KMA

Using the Met Office Global and Regional Ensemble Prediction System (MOGREPS) implemented at the Korea Meteorological Administration (KMA), the effect of doubling the ensemble size on the performance of ensemble prediction in the warm season was evaluated. Because a finite ensemble size causes sampling error in the full forecast probability distribution function (PDF), ensemble size is closely related to the efficiency of the ensemble prediction system. Prediction capability according to doubling the ensemble size was evaluated by increasing the number of ensembles from 24 to 48 in MOGREPS implemented at the KMA. The initial analysis perturbations generated by the Ensemble Transform Kalman Filter (ETKF) were integrated for 10 days from 22 May to 23 June 2009. Several statistical verification scores were used to measure the accuracy, reliability, and resolution of ensemble probabilistic forecasts for 24 and 48 ensemble member forecasts. Even though the results were not significant, the accuracy of ensemble prediction improved slightly as ensemble size increased, especially for longer forecast times in the Northern Hemisphere. While increasing the number of ensemble members resulted in a slight improvement in resolution as forecast time increased, inconsistent results were obtained for the scores assessing the reliability of ensemble prediction. The overall performance of ensemble prediction in terms of accuracy, resolution, and reliability increased slightly with ensemble size, especially for longer forecast times.     

Ternary forecast of heavy snowfall in the Honam area,Korea

The objective of this study is to improve the statistical modeling for the ternary forecast of heavy snowfall in the Honam area in Korea. The ternary forecast of heavy snowfall consists of one of three values, 0 for less than 50 mm, 1 for an advisory (50–150 mm), and 2 for a warning (more than 150 mm). For our study, the observed daily snow amounts and the numerical model outputs for 45 synoptic factors at 17 stations in the Honam area during 5 years (2001 to 2005) are used as observations and potential pre...     

Relative contributions of sulfate- and iron(III) reduction to organic matter mineralization and process controls in contrasting habitats of the Georgia saltmarsh

The objectives of this study were to partition out the predominant anaerobic respiration pathways coupled to C oxidation and to further elucidate the controls of anaerobic C respiration in three major saltmarsh habitats at Skidaway Island, GA; the short form of Spartina alterniflora (SS), the tall form of S. alterniflora (TS), and unvegetated, bioturbated creekbank (CB). Geochemical analysis of pore water and solid phase constituents revealed that the SS site experienced highly reducing conditions with two orders of magnitude higher pore water sulfide inventories (1.884 mmol m⁻²) than TS (0.003 mmol m⁻²) and CB (0.005 mmol m⁻²), respectively. Conversely, reactive Fe(III) inventories at TS (2208 mmol m⁻²) and CB (2881 mmol m⁻²) were up to 7–9 times higher than at SS (338 mmol m⁻²). Incubations and intact core experiments indicated that reduction accounted for 95% (SS), 37% (TS) and 66% (CB) of total anaerobic respiration. There was no detectable Fe(III) reduction at SS, while Fe(III) reduction accounted for up to 70% of C oxidation in the 3–6 cm depth interval at TS and 0–3 cm depth of CB, and on average, approximately 55% of C oxidation over two-thirds of marsh surface area. Laboratory manipulations provided further evidence for the importance of Fe(III) reduction as the accumulation rates of fermentation products were high when Fe(III) reduction was inhibited by removing the Fe(III) minerals from highly bioturbated CB sediments with higher Fe(III) mineral contents. Anaerobic C oxidation, - and Fe(III)-reduction rates appeared to be highest at the TS site during active plant growth in summer. Overall results suggest that bioturbation by macrofauna is the overriding factor in modulating the pathway of C mineralization in the saltmarsh, whereas availability of organic substrates from plants is a key factor in controlling the C oxidation rate.     

TBT toxicity on the marine microalga Nannochloropsis oculata

Commercial antifouling formulations containing TBT are the major source of organotin contamination in coastal waters. In view of the persisting TBT residues (13 ng Sn l⁻¹) in the coastal waters of South Korea, an attempt has been made to evaluate the growth response and biochemical composition of laboratory-cultured Nannochloropsis oculata to TBT toxicity. It is evident that the persisting concentration level of TBT is high enough to cause adverse effect on the microalgal species. The EC₅₀ (24 h) was found to be at 0.89 nM level of TBT for this marine eustigmatophyte N. oculata. Photosynthetic pigment content was significantly affected. At elevated TBT concentrations of 1.0 nM, especially pronounced changes in biochemical composition was found. TBT tolerance of N. oculata and its growth as well as biochemical responses are discussed.     

The effect of land cover change on duration and severity of high and low flows

Land cover has been increasingly recognized as an important factor affecting hydrologic processes at the basin and regional level. Therefore, improved understanding of how land cover change affects hydrologic systems is needed for better management of water resources. The objective of this study is to investigate the effects of land cover change on the duration and severity of high and low flows by using the Soil Water Assessment Tool model, Bayesian model averaging and copulas. Two basins dominated by different land cover in the Ohio River basin are used as study area in this study. Two historic land covers from the 1950s and 1990s are considered as input to the Soil Water Assessment Tool model, thereby investigating the hydrologic high and low flow response of different land cover conditions of these two basins. The relationships between the duration and severity of both low and high flow are defined by applying the copula method; changes in the frequency of the duration and severity are investigated. The results show that land cover changes affect both the duration and severity of both high and low flows. An increase in forest area leads to a decrease in the duration and severity during both high and low flows, but its impact is highest during extreme flows. The results also show that the land cover changes have had significant influences on changes in the joint return periods of duration and severity of low and high flows. While this study sheds light on the role of land cover change on severity and duration of high and low flow conditions, more studies using various land cover conditions and climate types are required in order to draw more reliable conclusions in the future. Copyright © 2016 John Wiley & Sons, Ltd.     

SHRIMP U–Pb ages of detrital zircons from the Early Cretaceous Nakdong Formation,South East Korea: Timing of initiation of the Gyeongsang Basin and its provenance

To constrain the depositional age of the lowermost Nakdong Formation in the Early Cretaceous Gyeongsang Basin, SHRIMP U–Pb age determination was carried out on zircon separates. The U–Pb compositions of detrital zircons from the Nakdong Formation yield a wide range of ages from the Archean to the Cretaceous but show a marked contrast in age distribution according to the geographical locations within the basin. The provenance of the southern Nakdong Formation is dominantly the surrounding Yeongnam Massif, which is composed of Paleoproterozoic metamorphic rocks and Triassic to Jurassic plutonic rocks, whereas the central to northern Nakdong Formation records significant sediment derivation from the Okcheon Metamorphic Belt, which is distributed to the northwest, in addition to the contribution from the Yeongnam Massif. It is suggested that the maximum depositional age of the Nakdong Formation is ca 127 Ma, based on its youngest detrital zircon age population. The onset of its deposition at 127 Ma coincided with the tectonic inversion in East Asia from a compressional to an extensional geodynamic setting, probably due to the contemporaneous change in the drift direction of the Izanagi Plate and its subsequent oblique subduction.