Determination of Selenium Concentrations in NIST SRM 610, 612, 614 and Geological Glass Reference Materials Using the Electron Probe, LA-ICP-MS and SHRIMP II

A combination of EMPA, sensitive high resolution ion microprobe (SHRIMP II) and/or LA-ICP-MS techniques was used to measure the concentration of selenium (Se) in NIST SRM 610, 612, 614 and a range of reference materials. Our new compiled value for the concentration of Se in NIST SRM 610 is 112 ± 2 μg g⁻¹. The concentration of Se in NIST SRM 612, using NIST SRM 610 for calibration, determined using LA-ICP-MS (confirmed using SHRIMP II) was 15.2 ± 0.2 μg g⁻¹. The concentration of Se in NIST SRM 614, using LA-ICP-MS was 0.394 ± 0.012 μg g⁻¹. LA-ICP-MS determination of Se in synthetic geological glasses BCR-2G, BIR-1G, TB-1G and the MPI-DING glasses showed a range in concentrations from 0.062 to 0.168 μg g⁻¹. Selenium in the natural glass, VG2, was 0.204 ± 0.028 μg g⁻¹.     

Accelerated sediment delivery to continental margins during post-orogenic rebound of mountain ranges

Changes in sediment flux to continental margins are commonly interpreted in terms of tectonic growth of topography or climatic change. Here, we show that variations in sediment yield from orogenic systems, previously considered as resulting from climate change, drainage reorganisation or mantle processes can be explained by intrinsic mechanisms of mountain belt/foreland basin systems naturally evolving during post-orogenic decay. Numerical modelling indicates an increase of sediment flux leaving the orogenic system synchronous with the cessation of deposition in the foreland basin and the transition from late syn- to post-orogenesis. Experiments highlight the importance of lithospheric flexure that causes the post-orogenic isostatic rebound of the foreland basin. Erosion of the rebounding foreland basin combined with continued sediment flux from the thrust wedge drives an acceleration in sediment outflux towards continental margins. Sediment budget records in natural settings such as the Northern Pyrenees or Western European Alps also indicate accelerated post-orogenic sediment delivery to the Bay of Biscay and Rhône Delta respectively. These intrinsic processes that determine sediment yield to continental margins must be accounted for prior to consideration of additional external tectonic or climatic controls.