70年来中国化学海洋学研究的主要进展

我国的海洋化学工作者通过70年来,特别是近30年来的化学海洋学研究,实现了我国与世界先进水平进入同步发展的快车道,其显著的特点是:(1)化学海洋学研究从元素地球化学分布系统转向了以揭示深层次海洋生物地球化学过程为核心的研究;(2)化学海洋学研究实现了多领域、多视点的综合交叉研究;(3)更加关注了人为影响与自然变化共同作用下的海洋生态环境变化研究,对近海和海岸带而言,更加注重从海陆统筹一体化角度探析化学物质的分布迁移特征。本文从生源要素的海洋生物地球化学过程、微/痕量元素与同位素的海洋化学研究、生物过程作用下的化学海洋学过程等角度,重点总结归纳和分析了30年来我国海洋化学研究的重要进展和发展状况,以期对化学海洋学的进一步研究提供借鉴和启迪。     

春季季风间期赤道东印度洋浮游植物光合生理特征

Phytoplankton physiologies are dynamic and have sensitive responses to the ambient environment. In this paper,we examine photosynthetic physiologies of phytoplankton communities with Phyto-PAM in the eastern equatorial Indian Ocean during the spring inter-monsoon. Environmental parameters were measured to investigate the coupling between phytoplankton photosynthetic physiologies and their habitats. During the cruise, the water column was highly stratified. The mixed layer extended to about 75 m and was characterized by high temperature(28°C) and low nutrient level. The F_v/F_m values and chlorophyll a(Chl a) concentrations were lower at the surface, as consequences of nutrient depletion and photo-inhibition. Subsurface Chl a maximum(SCM) occurred between 75 and 100 m, and had the highest F_v/F_m values. The formation of SCM was a balance between nutrient availability and light limitation. The SCM may contribute significantly to pelagic food web and primary production in the water column. Phytoplankton in different layers encountered different light, trophic and hydrographic dynamics and evolved distinct photosynthetic characteristics. Despite of co-limitation of nutrient limitation and photo-inhibition, phytoplankton in the surface layer showed their acclimation to high irradiance, had lower light utilization efficiencies(α: 0.061±0.032) and could exploit a wide range of light irradiance. Whereas, phytoplankton in the SCM layers presented the highest light utilization efficiencies(α:0.146±0.48), which guaranteed higher photosynthetic capacities under low light level. These results provide insights into phytoplankton photo-adaption strategies in this less explored region.     

浙江朱家尖岛东沙海滩对热带风暴“娜基莉”的响应及风暴后的恢复

海滩对风暴的响应及风暴后海滩的恢复过程一直以来都是国内外海滩研究的热点。本文通过对浙江舟山市朱家尖岛东沙海滩地形地貌的现场调查,对比分析了热带风暴"娜基莉"影响下东沙海滩剖面的蚀积变化,探讨了海滩在热带风暴发生后的恢复情况。结果表明,在"娜基莉"影响期间,因风暴浪为向岸浪,东沙海滩几乎遭受全线侵蚀,12个剖面单宽侵蚀总量为73.46 m3/m,其中海滩直线段较两个遮蔽段侵蚀显著。由于海滩在风暴前进方向的左侧,且"娜基莉"距东沙较远,使得东沙海滩普遍侵蚀但强度较小。东沙海滩在热带风暴后的恢复过程中,不同部位的地貌调整和冲淤变化不同,下岬角遮蔽段基本趋于稳定,直线段和上岬角遮蔽段在恢复过程中因受海滩季节性调整的影响呈现持续侵蚀。     

底栖有孔虫(Florilus decors)壳体微量元素/钙比值的LA-ICP-MS原位微区分析方法及应用——以长江口外海域为例

深海沉积物中有孔虫壳体的微量元素、同位素测试技术已较为成熟,而河口近海沉积物中有孔虫壳体元素微区测试却鲜有报道。本文报道了一种利用激光剥蚀电感耦合等离子体质谱（LA-ICP-MS）分析法测试取自长江口外沉积物中的有孔虫壳体元素/钙比值的技术,研究了氦气载气流量、能量密度、束斑大小、激光剥蚀频率等参数对测试结果的影响,优化了活体有孔虫原位分析方法。应用确定的测试条件对2016年7月取自长江口外的底栖有孔虫优美花朵虫样品（Florilus decors）进行测试,发现Mg、Sr等元素/钙比值在壳体不同位置上无显著差异,而Mn的数据较为离散,可能与有孔虫生长过程中经历的水环境及其变化有关。     

Global Statistical Assessment and Cross-Calibration with Jason-2 for Reprocessed HY-2 A Altimeter Data

HY-2 A (Haiyang-2 A) satellite was launched on August 16, 2011 and radar altimeter is one of its main payloads. We reprocessed two years of HY-2 A altimeter sensor geophysical dataset records (SGDR) data. This paper presents the main results in terms of reprocessed HY-2 A altimeter data quality: verification of data availability and validity, monitoring several relevant altimeter parameters, and assessment of the HY-2 A altimeter system performances. A cross-calibration analysis of reprocessed HY-2 A altimeter data with Jason-2 was conducted. The reprocessed HY-2 A altimeter data show good quality and have a low level of noise with respect to Jason-2. The same geophysical correction methods were used to calculate the sea surface height (SSH) for the two missions. The mean standard deviations of the crossover differences for HY-2 A and Jason-2 are 5.24 cm and 5.34 cm, respectively. The mean standard deviation of the crossover differences between HY-2 A and Jason-2 is 5.37 cm. These show that HY-2 A can provide SSH measurements at almost the same level of accuracy as Jason-2. The relative SSH bias between HY-2 A and Jason-2 due to the Ultra Stable Oscillator (USO) drift is obviously observed, and it can affect the calculation of mean sea level and should be further studied and corrected.     

Instantaneous Shorelines as an Intermediate for Island Shoreline Mapping based on Aerial/Satellite Stereo Images

Island shoreline mapping based on field measurements by collecting visually discernible features is costly and even unrealistic to be implemented in practice because of the nonuniqueness, fuzziness, and ambiguity of shoreline features. The MHHW (the mean higher high water) shoreline, i.e., the intersection of the coastal profile with the MHHW, is recommended to be chosen as a significant shoreline indicator of an island. An approach for mapping the MHHW shoreline using the aerial/satellite stereo images is proposed. In the proposed procedure, first, the height difference between the instantaneous shoreline and the MHHW shoreline is calculated by the ocean tide model; then the orthometric/normal height of the instantaneous shoreline is determined from the stereo images; last, the instantaneous shoreline is used as an intermediate for determination of the height of the MHHW shoreline. The proposed procedure is applied to the MiaoZiHu Island located in the East China Sea. Preliminary experimental result shows that in ideal cases, the horizontal positional accuracy of the extracted shoreline can reach 0.2 m from aerial images of 0.1 m resolution.     

波浪作用下粉土海床中的孔压响应试验研究

海床在波浪作用下是否稳定对海底工程的安全至关重要,海床的稳定性与土体中的孔压响应密切相关。水槽模拟试验表明:在波浪的作用下,黄河三角洲粉土海床中将产生振荡孔隙水压力和累积孔隙水压力。振荡孔隙水压力大小与土层深度、波高和粘粒含量有关,其振幅(能量)在土层中随深度的增加呈指数衰减,且粘粒含量越高衰减越快;加载波高越大,能量衰减越快。而累积孔压响应模式表现为在波浪作用最初的一段时间内,孔隙水压力快速上升,然后逐渐减小而趋于稳定,其大小和速率也与波高、粘粒含量、土层埋深有关,粘粒含量越高,孔压累积速度越低。     

重力活塞取样器取样技术研究

现代海洋沉积物柱状取样技术是一套综合性的高新技术系统,它一般应该包括：优良的取样器具,方便灵活的取样操作设备,高精度的定位导航仪器和高分辨率的地形、地貌、地层探测系统等四个方面。我国和先进国家相比,取样操作设备方面差距最大,应该成为我国今后取样技术研究和发展的重点     

中国降水季节内振荡的气候特征分析

利用谐波分析、功率谱分析的方法,对全国730个站点自1951～2000年逐日降水资料进行气候平均分析,研究全国降水季节内振荡的分布特征.研究结果表明,中国大部分地区的降水主要以季节变化为主,而在长江中下游流域主要以季节内振荡为主.气候平均下降水的准双周振荡和Madden and Julian Oscillation(简称MJO)的振幅都在4月份开始加强,在11月份开始减弱,而MJO全年表现都很显著,准双周振荡主要在夏季显著;MJO主要分布在36°N以南的长江中下游地区,准双周振荡主要分布在115°E以西的内陆.     

6种鱼类肌肉组织肌苷酸的检测分析

采用高效液相色谱技术,在国内首次测定了条纹斑竹鲨(Chilocsyllium plagiosum)、大黄鱼(Pseudosci-aena crocea)、鳜(Siniperca chuatsi)、青石斑鱼(Epinephelus awoara)、牙鲆(Paralichthys olivaceus)和乌塘鳢(Bostrichthys sinensis)等6种鱼类新鲜和冻存肌肉组织中肌苷酸含量。结果表明:(1)不同鱼类肌肉组织中肌苷酸质量比不同,牙鲆新鲜肌肉组织中肌苷酸质量比最高,为4.214 mg/g,其余5种鱼类为2.365~3.634 mg/g。(2)10 d冻存试验中,经-70℃超低温冻存,6种鱼类冻存肌肉组织中肌苷酸质量比均高于新鲜肌肉组织,大黄鱼肌肉组织冻存1 d肌苷酸质量比达最大值,鳜肌肉组织冻存10 d肌苷酸质量比呈上升态势未出现最大值,其余5种鱼类肌肉组织肌苷酸质量比均在冻存第5天达到最大值。长时间的冻存将会降低食用鱼肉中肌苷酸质量比,导致鲜味下降,但经1周左右短时间的冻存后可明显提高鱼肉中肌苷酸质量比,增加鲜味,提高食用价值。