Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

Mapping hourly dynamics of urban population using trajectories reconstructed from mobile phone records

Understanding the spatiotemporal dynamics of urban population is crucial for addressing a wide range of urban planning and management issues. Aggregated geospatial big data have been widely used to quantitatively estimate population distribution at fine spatial scales over a given time period. However, it is still a challenge to estimate population density at a fine temporal resolution over a large geographical space, mainly due to the temporal asynchrony of population movement and the challenges to acquiring a complete individual movement record. In this article, we propose a method to estimate hourly population density by examining the time‐series individual trajectories, which were reconstructed from call detail records using BP neural networks. We first used BP neural networks to predict the positions of mobile phone users at an hourly interval and then estimated the hourly population density using log‐linear regression at the cell tower level. The estimated population density is linearly correlated with population census data at the sub‐district level. Trajectory clustering results show five distinct diurnal dynamic patterns of population movement in the study area, revealing spatially explicit characteristics of the diurnal commuting flows, though the driving forces of the flows need further investigation.     

西藏当雄九子拉地区石炭系诺错组中震积岩的发现及意义

西藏当雄九子拉地区石炭系诺错组地层序列中,首次发现了一套非正常沉积的粉砂岩和灰岩的组合.岩系中可识别出非正常的沉积构造,即微同沉积断裂、火焰状构造、同生变形构造及振动液化泄水构造等,这一软沉积变形构造具震积岩的识别标志特征,代表灾变事件震积的地质记录.在剖面结构上大致显示为7个单元的震积序列,自下而上由下伏弱震层(A)—液化脉(B)—震褶岩(C)—震裂岩(D)—阶梯状微断层(E)—火焰状构造(F)—上覆未震层(G)的渐变过程及震积作用逐渐减弱的趋势呈不同形式的组合出现,有ABG、ACDG、AEG、ABCG和ABFG等组合.本研究分析认为晚古生代诺错组早期存在一个强烈的构造活动时期,结合震积岩的分布及区域地质背景研究表明,九子拉北侧一带可能为近东西向同生断裂带,该断裂带的强烈构造活动是本区诺错组震积作用的直接诱发因素.从而佐证了九子拉地区正处于构造转换阶段.本研究对分析晚古生代的构造演化、沉积盆地类型奠定了基础,同时保存完好的震积事件地层记录对推断古断裂、古环境也具有较大意义.     

四川盆地喜马拉雅期张扭性断裂构造特征及形成机制

前人对四川盆地盆缘冲断带及川中高-磨地区断裂系统进行了系统性研究,但对于盆地其他区块断裂发育特征、形成演化及应力背景的认识尚不充分.发现了梓潼-成都-威远-华蓥山-广安地区震旦系-下三叠统地层中发育的一套区域性张扭性断裂,主要自震旦系及以下地层向上延伸切穿二叠系地层,多为高陡、小断距正断层,部分形成负花状构造.根据该断裂系统的剖面产状、纵向穿层特征及盆地范围内体现出的分异性,推断该断裂系统形成于喜马拉雅期.物理模拟实验研究发现该断裂体系应发育于扭张性应力环境中,该断裂体系的发育指示了四川盆地内部新生代存在南西-北东向张应力,可能与四川盆地新生代发生的逆时针旋转有关.      

The Extra-Area Effect in 71 Cloud Seeding Operations during Winters of 2008–14 over Jiangxi Province,East China

Effects of weather modification operations on precipitation in target areas have been widely reported, but little is specifically known about the downwind (extra-area) effects in China. We estimated the extra-area effect of an operational winter (November-February) aircraft cloud-seeding project in northern Jiangxi Province in eastern China by using a revised historical target/control regression analysis method based on the precipitation data in winter. The results showed that the overall seasonal average rainfall at the downwind stations increased by 21.67%(p=0.0013). This enhancement effect was detected as far as 120 km away from the target area. Physical testing was used to compare the cloud characteristics before and after seeding on 29 November 2014. A posteriori analysis with respect to the characteristics of cloud units derived from operational weather radar data in Jiangxi was performed by tracking cloud units. Radar features in the target unit were enhanced relative to the control unit for more than two hours after the operational cloud seeding, which is indicative of the extra-area seeding effect. The findings could be used to help relieve water shortages in China.     

油气包裹体在油气地质研究中的应用--概念、分类、形成机制及研究意义

油气包裹体己成为油气成藏研究的有力工具,在划分油气运移充注期次、确定油气藏的形成时间、反映油气的成熟度及来源等方面均有重要的应用价值。近年来,利用油气包裹体及其共生的盐水溶液包裹体估算油气藏形成时的pVT条件是油气包裹体研究中的一个新热点,它为更准确地计算油气藏形成的温度一压力条件提供了一种独立的、更准确的技术手段。研究表明,包裹体岩相学和流体体系的热力学研究仍将是今后的发展重点。油气包裹体的pVT模拟技术尚处于初始阶段,两种软件（VTFlinc和FIT）的准确性和精确性虽有待进一步提高,但已经成为今后一个重要的发展方向。     

综合评价方法在水质评价应用中的比较研究

以黄河某取水口监测点19981999年的水质为评价对象,利用灰色关联分析法、模糊综合评价法和物元分析法分别进行了综合评价,结果表明,模糊综合评价和物元分析法的评价结果一致,"中心化"灰色关联法评价结果与上述两方法的评价结果一致.     

珠一坳陷始新世文昌组沉积期构造转换对源‒汇体系的控制

珠江口盆地珠一坳陷在中始新世裂陷期文昌组沉积早、晚期之间存在明显的构造转换,该构造事件对古近系源?汇体系的形成和演变有重大影响.基于研究区地震、钻井、测井等资料的综合分析,本文认为构造转换控制了裂陷期源?汇体系的盆山地貌、物源供给、搬运方向及沉积样式等基本要素,并影响深层古近系储层条件.而且在构造转换的制约下,研究区发...     

Purification and Characterization of a Novel Hydrolase That Can Specifically Degrade the Polysaccharide Isolated from Green Seaweed Ulva prolifera

The extracellular polysaccharide hydrolase-producing strain EP-1 was isolated from seawater and identified as Paenibacillus pabuli. Furthermore, a homogeneous extracellular polysaccharide hydrolase from Paenibacillus pabuli EP-1 was purified by combining ion-exchange chromatography and size exclusion chromatography with a purification fold of 90.69 and recovery of 16.23%. Characterization of the purified polysaccharide hydrolase revealed a molecular mass of 38 k Da and optimum activity at 45℃ and pH 6.0. The polysaccharide hydrolase maintained its stability within a wide range of pH(3.0–12.0) and thermal stability when the temperature was below 50℃. The presence of Hg²⁺, Fe²⁺, Mn²⁺, Co²⁺ and SDS notably decreased hydrolase activity, and organic solvents such as formaldehyde, acetone, DMF and acetonitrile completely inhibited hydrolase activity. The purified hydrolase had no activity on agar, carrageenan, gellan gum, sodium alginate, or starch, but effectively hydrolyzed the polysaccharide from Ulva prolifera. The Km and Vmax values of this hydrolase were 43.84 mg m L^-1 and 4.33 mg m L^-1 min^-1, respectively. The sequence analysis with quantitative time-of-flight mass spectrometry indicated that the hydrolase was an endoglucanase.