PMN J0525−3343: soft X-ray spectral flattening in a blazar at z = 4.4

We report optical, radio and X-ray observations of a new distant blazar, PMN J0525−3343, at a redshift of 4.4. The X-ray spectrum measured from ASCA and BeppoSAX flattens below a few keV, in a manner similar to the spectra of two other z >4 blazars, GB 1428+4217 ( z =4.72) reported by Boller et al. and RX J1028.6−0844 ( z =4.28) reported by Yuan et al. The spectrum is well fitted by a power-law continuum which either is absorbed or breaks at a few keV. An intrinsic column density corresponding to 2×10²³ H‐atoms cm⁻² at solar abundance is required by the absorption model. This is however a million times greater than the neutral hydrogen, or dust, column density implied by the optical spectrum, which covers the rest-frame ultraviolet emission of the blazar nucleus. We discuss the problems raised and suggest that, unless there is intrinsic flattening in the spectral distribution of the particles/seed photons producing X-rays via inverse Compton scattering, the most plausible solution is a warm absorber close to the active nucleus.     

Modeling aluminum-silicon chemistries and application to Australian acidic playa lakes as analogues for Mars

Recent Mars missions have stimulated considerable thinking about the surficial geochemical evolution of Mars. Among the major relevant findings are the presence in Meridiani Planum sediments of the mineral jarosite (a ferric sulfate salt) and related minerals that require formation from an acid-salt brine and oxidizing environment. Similar mineralogies have been observed in acidic saline lake sediments in Western Australia (WA), and these lakes have been proposed as analogues for acidic sedimentary environments on Mars. The prior version of the equilibrium chemical thermodynamic FREZCHEM model lacked Al and Si chemistries that are needed to appropriately model acidic aqueous geochemistries on Earth and Mars. The objectives of this work were to (1) add Al and Si chemistries to the FREZCHEM model, (2) extend these chemistries to low temperatures (<0 °C), if possible, and (3) use the reformulated model to investigate parallels in the mineral precipitation behavior of acidic Australian lakes and hypothetical Martian brines.FREZCHEM is an equilibrium chemical thermodynamic model parameterized for concentrated electrolyte solutions using the Pitzer approach for the temperature range from <−70 to 25 °C and the pressure range from 1 to 1000 bars. Aluminum chloride and sulfate mineral parameterizations were based on experimental data. Aluminum hydroxide and silicon mineral parameterizations were based on Gibbs free energy and enthalpy data. New aluminum and silicon parameterizations added 12 new aluminum/silicon minerals to this Na-K-Mg-Ca-Fe(II)-Fe(III)-Al-H-Cl-Br-SO₄-NO₃-OH-HCO₃-CO₃-CO₂-O₂-CH₄-Si-H₂O system that now contain 95 solid phases.There were similarities, differences, and uncertainties between Australian acidic, saline playa lakes and waters that likely led to the Burns formation salt accumulations on Mars. Both systems are similar in that they are dominated by (1) acidic, saline ground waters and sediments, (2) Ca and/or Mg sulfates, and (3) iron precipitates such as jarosite and hematite. Differences include: (1) the dominance of NaCl in many WA lakes, versus the dominance of Fe-Mg-Ca-SO₄ in Meridiani Planum, (2) excessively low K⁺ concentrations in Meridiani Planum due to jarosite precipitation, (3) higher acid production in the presence of high iron concentrations in Meridiani Planum, and probably lower rates of acid neutralization and hence, higher acidities on Mars owing to colder temperatures, and (4) lateral salt patterns in WA lakes. The WA playa lakes display significant lateral variations in mineralogy and water chemistry over short distances, reflecting the interaction of acid ground waters with neutral to alkaline lake waters derived from ponded surface runoff. Meridiani Planum observations indicate that such lateral variations are much less pronounced, pointing to the dominant influence of ground water chemistry, vertical ground water movements, and aeolian processes on the Martian surface mineralogy.     

Dynamic implication of biomass energy consumption on economic growth in Sub-Saharan Africa: evidence from panel data analysis

The present article examines the dynamic linkages between biomass energy consumption, capital stock, human capital and economic growth across selected Sub-Saharan African countries based on dynamic heterogeneous panels of a mean group (MG) and pooled mean group (PMG) techniques. The finding based on PMG as the preferred method reveals that biomass energy consumption, capital stock and human capital are statistically significant, which means aforementioned variables have positive significant impact on economic growth in the countries studied. When an alternative panel estimation techniques of panel cointegration, dynamic OLS (DOLS) and fully modified OLS (FMOLS) are applied, the result based on panel cointegration technique reveals that biomass energy consumption, capital stock, human capital and economic growth are cointegrated as null hypothesis of most statistics are rejected at 1 % level of significance. The finding based on FMOLS shows that biomass energy consumption, capital stock and human capital positively influences economic growth at 1 % level and same result is obtained from panel OLS. The result based on DOLS however reveals that biomass energy consumption and capital stock are significant at 1 % on economic growth while human capital is insignificant. Considering its positive effect on economic growth with little or no environmental degradation when compared with fossil fuel uses, consumption of biomass energy is more preferable in these countries therefore is the best option to adopt by the policy makers of Sub-Saharan African countries.     

Zur Kenntnis der Kalkinkrustation und Kalkkorrosion im Seelitoral

Ohne Zusammenfassung     

Relating the reproductive toxicity of five ingested metals in calanoid copepods with sulfur affinity

The sublethal toxicity of dietary Ag, Cd, Hg, Mn, and Zn to marine copepods, measured as depressed egg production, was evaluated as a function of ambient metal concentrations and metal concentrations in copepod tissues. All metals were toxic following 4-h feedings on metal-contaminated phytoplankton food, but there was a four order of magnitude difference between the inhibitory concentration in copepod tissues of the most toxic (2.4 nmol g(-1) dry wt. for Hg) and least toxic (13.4 micromol g(-1) dry wt. for Mn) metals. Metal concentrations in copepods that elicited a toxic response were about 3 times higher than background concentrations for Ag and 9 times higher for Hg, about 2 times higher for Cd, two orders of magnitude higher for Mn, and only 5% higher for Zn. Copepods exposed to lower concentrations of Zn for longer periods (1 week), resulting in tissue Zn concentrations similar to those in the short-term exposures, were not affected, suggesting that copepods were capable of adjusting to slowly increasing Zn by sequestration of this metal. Toxic metal concentrations in copepod tissues were directly proportional (r2 = 0.85) to the affinity of the metals for sulfur, as indicated by the solubility products of the metal sulfides. This relationship, together with protein analysis of eggs, published recently, suggests that metals affect egg production by binding to enzymes involved with vitellogenesis.     

Über die Variabilität zweier mariner Oscillatorien aus der Sektion «Margaritiferae»

Aquatic Sciences - Es wurde die Variabilität der Dimensionen zweier mariner Oscillatorien aus der Adria (Rovinj, Istrien) verglichen und ihre taxonomische Zugehörigkeit diskutiert. Die...     

Entwurf zu einem ökologischen System der Blaualgen

Zusammenfassung es wird vorgeschlagen, die heutige Blaualgensystematik durch ein ?kologisches System zu erg?nzen, welches die ?kologisch bedingte Variabilit?t der Formen systematisch berücksichtigt, so dass die Grenzen der ?kologisch unbeeinflussten Einheiten der reinen Taxonomie klarer werden. Dafür wird das Benennungssytem von JAAG als günstigstes betrachtet.