Characterization of complex fluvial systems using remote sensing of spatial and temporal water level variations in the Amazon,Congo, and Brahmaputra Rivers

The Surface Water and Ocean Topography (SWOT) satellite mission will provide global, space‐based estimates of water elevation, its temporal change, and its spatial slope in fluvial environments, as well as across lakes, reservoirs, wetlands, and floodplains. This paper illustrates the utility of existing remote sensing measurements of water temporal changes and spatial slope to characterize two complex fluvial environments. First, repeat‐pass interferometric SAR measurements from the Japanese Earth Resources Satellite are used to compare and contrast floodplain processes in the Amazon and Congo River basins. Measurements of temporal water level changes over the two areas reveal clearly different hydraulic processes at work. The Amazon is highly interconnected by floodplain channels, resulting in complex flow patterns. In contrast, the Congo does not show similar floodplain channels and the flow patterns are not well defined and have diffuse boundaries. During inundation, the Amazon floodplain often shows sharp hydraulic changes across floodplain channels. The Congo, however, does not show similar sharp changes during either infilling or evacuation. Second, Shuttle Radar Topography Mission measurements of water elevation are used to derive water slope over the braided Brahmaputra river system. In combination with in situ bathymetry measurements, water elevation and slope allow one to calculate discharge estimates within 2.3% accuracy. These two studies illustrate the utility of satellite‐based measurements of water elevation for characterizing complex fluvial environments, and highlight the potential of SWOT measurements for fluvial hydrology. Copyright © 2010 John Wiley & Sons, Ltd.     

Determination of Partition Coefficients for Selected PAHs between Water and Dissolved Organic Matter

The fate and transport of highly hydrophobic chemicals are affected by the partitioning between water and dissolved organic carbon. Large variation in the partition coefficient (K_DOCw) is often found, due to the selection of model organic matter or potential experimental artifacts. To investigate the roles of the type of organic matter on the partitioning of highly hydrophobic compounds, the partition coefficients of eight selected polycyclic aromatic hydrocarbons (PAHs), with 3–6 aromatic rings, were determined using a passive dosing/extraction method between water and model dissolved organic matter (humic acid, fulvic acid, sodium dodecyl sulfate micelle (SDS), and 2‐hydroxypropyl‐β‐cyclodextrin). Although the K_DOCw values for 3–4 ring PAHs in this study were close to those reported in the literature, experimental K_DOCw values between Aldrich humic acid (AHA) and water were higher than values reported in the literature for 5–6 ring PAHs. The K_DOCw values were highest for AHA, followed by SDS and Suwannee river fulvic acid (SFA). The slopes of the linear regression between log K_DOCw and log K_ow were 1.23 (± 0.13), 0.82 (± 0.09), and 0.59 (± 0.13) for AHA, SDS, and SFA, respectively. The differences in the K_DOCw values between AHA and the other organic matter (SDS, SFA, and CD) increased with increasing hydrophobicity of the PAHs, showing that the sorption of highly hydrophobic chemicals to the humic acid fraction may be important in the presence of mixed organic matter.     

海陆风环流的计算方法

给出海陆风环流的计算方法,得到了计算方程,该方程为一个复偏微分方程,可用松弛迭代法数值求解。利用该方程,对珠江口及香港地区的海陆风环流作了高分辨率的计算,结果表明用该方法计算得到的海陆风环流是可信的,其与实际观测及Mass模式的计算结果十分吻合。     

The Air-Sea Exchange of CO2 in the East Sea (Japan Sea)

During CREAMS expeditions, fCO₂ for surface waters was measured continuously along the cruise tracks. The fCO₂ in surface waters in summer varied in the range 320–440 μatm, showing moderate supersaturation with respect to atmospheric CO₂. In winter, however, fCO₂ showed under-saturation of CO₂ in most of the area, while varying in a much wider range from 180 to 520 μatm. Some very high fCO₂ values observed in the northern East Sea (Japan Sea) appeared to be associated with the intensive convection system developed in the area. A gas-exchange model was developed for describing the annual variation of fCO₂ and for estimating the annual flux of CO₂ at the air-sea interface. The model incorporated annual variations in SST, the thickness of the mixed layer, gas exchange associated with wind velocity, biological activity and atmospheric concentration of CO₂. The model shows that the East Sea releases CO₂ into the atmosphere from June to September, and absorbs CO₂ during the rest of the year, from October through May. The net annual CO₂ flux at the air-sea interface was estimated to be 0.032 (±0.012) Gt-C per year from the atmosphere into the East Sea. Water column chemistry shows penetration of CO₂ into the whole water column, supporting a short turnover time for deep waters in the East Sea. This revised version was published online in August 2006 with corrections to the Cover Date.     

Characterization of a TCE DNAPL Zone in Alluvium by Partitioning Tracers

Partitioning interwell tracer tests (PITT) were used ID determine the spatial distribution and volume of residual trichloroethene (TCE) present in alluvium beneath the Portsmouth Gaseous Diffusion Plain in southern Ohio. Its first use at this site was in support of the design of a surfactant flood to remove the residual DNAPL (dense nonaqueous phase liquids) from the alluvial aquifer. The second application assessed the performance of the surfactant flood. The average DNAPL saturation in the first PITT was 0.1 to 0.2% in a swept pore volume of 4500 gallons (17.000 L). A second PITT was undertaken following the surfactant flood and yielded an average residual saturation of 0.06% in a swept pore volume of 3400 gallons (13.000 L), the reduction in pore volume being due to the confinement of the tracers to the lower sand and gravel unit of the alluvium. The design, operation, and analysis of the two PM Is provided strong evidence of a buried channel that controls the spatial distribution of the residual TCI: DNAPL in the basal sand and gravel aquifer and must be considered in the eventual full remediation of this aquifer.     

Does heavy oil pollution induce bacterial diseases in Japanese flounder Paralichthys olivaceus?

As basic research for the effect of heavy oil on the fish immune system, in this study, the number of leukocyte was counted in Japanese flounder Paralichthys olivaceus, after exposure to heavy oil at a concentration of 30 g/8 L for 3 days. To compare the numbers of bacteria in the skin mucus between oil-exposed and control fish, viable bacteria were enumerated by counting colony forming unit (CFU). Compared with 5.79 ± 1.88 × 10⁷ leukocytes/mL in the controls, the exposed fish demonstrated higher counts, averaging 1.45 ± 0.45 × 10⁸ cells/mL. The bacterial numbers of control fish were 4.27 ± 3.68 × 10⁴ CFU/g, whereas they were 4.58 ± 1.63 × 10⁵ CFU/g in the exposed fish. The results suggest that immune suppression of the fish occurred due to heavy oil stressor, and bacteria could invade in the mucus, resulting in the increasing leukocyte number to prevent infectious disease.     

Toxicogenomic analysis of immune system-related genes in Japanese flounder (Paralichthys olivaceus) exposed to heavy oil

Heavy oil contamination is one of the most important environmental issues. Toxicities of polycyclic aromatic hydrocarbons (PAHs), including immune toxicities, are well characterized, however, the immune toxic effects of heavy oil, as a complex mixture of PAHs, have not been investigated. In the present study, we selected Japanese flounder (Paralichthys olivaceus) as a model organism, and observed alteration of immune function by the exposure to heavy oil. To analyze the expression profiles of immune system-related genes, we selected 309 cDNAs from our flounder EST library, and spotted them on a glass slide. Using this cDNA array, alteration of gene expression profiles was analyzed in the kidneys of flounders exposed to heavy oil. Six Japanese flounders (mean body weight: 197 g) were acclimated to laboratory conditions at 19–20 °C. Three fish were exposed to heavy oil C (bunker C) at a concentration of 3.8 g/L for 3 days, and the others were kept in seawater without heavy oil and used as the control. After the exposure period, the fish were transferred into control seawater and maintained for 4 days, and then they were dissected and their kidneys were removed. Total RNA was extracted from the kidney samples to use in gene expression analyses. The microarray detected alteration of immune system-related genes in the kidneys of heavy oil-exposed flounders, including down-regulation of immunoglobulin light chain, CD45, major histocompatibility complex class II antigens and macrophage colony-stimulating factor precursor, and up-regulation of interleukin-8 and lysozyme. These results suggest that pathogen resistance may be weakened in heavy oil-exposed fish, causing a subsequent bacterial infection, and then proinflammatory genes may be induced as a defensive response against the infection. Additionally, we found candidate genes for use as biomarkers of heavy oil exposure, such as N-myc downstream regulated gene 1 and heat shock cognate 71 kDa proteins.     

Does pore water velocity affect the reaction rates of adsorptive solute transport in soils? Demonstration with pore-scale modelling

Modelling adsorptive solute transport in soils needs a number of parameters to describe its reaction kinetics and the values of these parameters are usually determined from batch and displacement experiments. Some experimental results reveal that when describing the adsorption as first-order kinetics, its associated reaction rates are not constants but vary with pore water velocity. Explanation of this varies but an independent verification of each explanation is difficult because simultaneously measuring the spatiotemporal distributions of dissolved and adsorbed solutes in soils is formidable. Pore-scale modelling could play an important role to address this gap and has received increased attention over the past few years. This paper investigated the transport of adsorptive solute in a simple porous medium using pore-scale modelling. Fluid flow through the void space of the medium was assumed to be laminar and in saturated condition, and solute transport consisted of advection and molecular diffusion; the sorption and desorption occurring at the fluid–solid interface were modelled as linear first-order kinetics. Based on the simulated spatiotemporal distribution of dissolved and adsorbed solutes at pore scale, volumetric-average reaction kinetics at macroscopic scale and its associated reactive parameters were measured. Both homogeneous adsorption where the reaction rates at microscopic scale are constant, and heterogeneous adsorption where the reaction rates vary from site to site, were investigated. The results indicate that, in contrast to previously thought, the macroscopic reaction rates directly measured from the pore-scale simulations do not change with pore velocity under both homogeneous and heterogeneous adsorptions. In particular, we found that for the homogeneous adsorption, the macroscopic adsorption remains first-order kinetic and can be described by constant reaction rates, regardless of flow rate; whilst for the heterogeneous adsorption, the macroscopic adsorption kinetics continues not to be affected by flow rate but is no longer first-order kinetics that can be described by constant reaction rates. We discuss how these findings could help explain some contrary literature reports over the dependence of reaction rates on pore water velocity.     

Toxicity identification in metal plating effluent: implications in establishing effluent discharge limits using bioassays in Korea

Because of complexity and diversity of toxicants in effluent, chemical analysis alone gives very limited information on identifying toxic chemicals to test organisms. Toxicity identification evaluation (TIE) techniques have been widely used to identify toxicants in various samples including industrial wastewater as well as natural waters. In response to new regulation for effluent discharge in Korea, which will be effective from 2011, a necessity of studies emerges that investigates toxicity levels in industrial effluents. This work was a preliminary study examining toxicity levels in effluent from one metal plating factory using Daphnia magna (48 h immobility) and identifying toxicity-causing substances. Toxicity tests showed variability on different sampling occasions and the results of TIE methods indicated that both organic compounds and metals contributed to the observed toxicity in metal plating effluent. Further studies are necessary to help reduce effluent toxicity especially from direct dischargers, who will have to comply with the new regulation.     

Sloped multi‐roller isolation devices for seismic protection of equipment and facilities

The rolling motion of mutually orthogonal rollers respectively sandwiched between two bearing plates in which one or both have V‐shaped sloping surfaces makes the sloped rolling‐type isolation device have an excellent in‐plane seismic isolation performance. In this study, the sloped rolling type isolation device in which a single roller moves between two V‐shaped sloping surfaces along each principle horizontal direction is refined by incorporating multi‐roller, built‐in damping, and pounding prevention mechanisms. The associated dynamic behavior is further clarified, and a simplified twin‐flag hysteretic model, which can be easily applied in most commercial computational tools is then proposed. Seismic simulation tests on the refined isolation devices (i.e. the sloped multi‐roller isolation devices) with different design parameters such as sloping angles of bearing plates and built‐in damping capabilities, together with a raised floor system by employing the sloped multi‐roller isolation devices, were conducted. Not only is the efficiency of the sloped multi‐roller isolation devices in seismically protecting the important objects, but also the practicability and accuracy of the proposed simplified numerical model in predicting the seismic responses of the sloped multi‐roller isolation devices is experimentally verified. Copyright © 2014 John Wiley & Sons, Ltd.