大九湖泥炭沼泽源铁有机配合物的络合稳定性及其生态环境意义

为了研究泥炭沼泽源铁有机配合物的络合稳定性,利用pH电位滴定法和荧光淬灭滴定法测定了大九湖泥炭沼泽中不同分子量段的DOM和Fe2+、Fe3+的络合稳定常数.pH电位滴定法结果（4.0~6.1）和荧光淬灭滴定法（1.5~4.1）差异较大,这与高pH条件下OH被脱质子化及Fe2+的氧化有关.相对而言,pH滴定法更适用于探究不同分子量段DOM与铁的络合稳定性,荧光淬灭法不改变样品酸碱条件,更适于研究不同价态铁与DOM的络合稳定性.研究结果表明:DOM与Fe3+的络合稳定常数大于Fe2+,低分子量段（< 3 kDa）的DOM与Fe2+、Fe3+的络合稳定常数更大.泥炭沼泽源铁有机配合物具有较好的络合稳定性,分子量相对较小的DOM与铁的络合能力更强.即便Fe2+氧化为Fe3+,仍能与DOM络合并保持较强的稳定性,这有利于陆源溶解性铁向水生态系统的输出.沼泽源铁有机配合物的络合稳定性还会影响铁的生物可利用性.      

基于Sentinel-1和DEM数据的南岭高植被覆盖区地形线性特征提取方法

在南岭高海拔山脉、植被茂密等地区开展地质调查难度大,人员和物资难以进入,因此需提前根据该区域的地形线性特征合理设计野外调查路线;此外地形线性特征可为区域构造运动信息的认知提供辅助知识.遥感技术以其宏观性、多尺度、多层次的特点成为地质研究和地质勘查的重要手段,然而在高植被覆盖区,常见的光学影像难以穿透植被,而微波雷达遥感则因为较好的植被穿透性,使得其应用成为可能.因此,提出了一种基于雷达卫星Sentinel-1和数字高程模型（digital elevation model,DEM）数据的地形线性特征提取方法.该方法首先利用似然比边缘检测算法提取Sentinel-1影像中的边缘特征,然后对DEM进行线性特征增强以生成山体阴影影像,再利用Canny边缘检测算子提取DEM数据中的山脊线与山谷线等主要线性特征,以DEM提取出的特征线为中心建立缓冲区并与雷达影像的提取结果做相交处理,将得到的线性特征利用道格拉斯-普克算法进行局部直线拟合,最后得到研究区的地形线性特征.结果表明,该方法综合考虑了雷达影像的微观细节信息和DEM数据的宏观趋势信息,在保留主要线性地形特征的同时剔除了伪边缘和噪声点,提取效果较好.      

东天山云海铜镍矿地球化学特征及成因分析

云海铜镍矿位于觉罗塔格构造带西段,成矿岩体为多期次侵入的杂岩体,岩体分异演化充分,镁铁质和超镁铁质岩石均有发育,主要岩石类型为角闪辉石岩、橄榄苏长岩、辉长岩、闪长岩。主量元素化学组成表明,该杂岩体属拉斑玄武岩系列,岩石具同源演化特征,显示高铁、高镁、低钛、低铝特征,富集大离子亲石元素Rb,Ba,亏损Nb,Ta,轻稀土富集。岩浆源区有部分熔融而交代的岩石圈地幔,岩浆在上升过程中受到地壳物质混染,发生橄榄石、斜方辉石、斜长石的分离结晶。岩体形成于早二叠世,为构造活动和地幔柱双重作用下的产物。     

青藏高原东北缘祁连山三叠系砂岩碎屑锆石U-Pb定年及其物源分析

三叠系沉积物广泛覆盖青藏高原东北缘,其中松潘—甘孜地区三叠系的沉积物得到了较系统的研究,但是青藏高原北缘的祁连山三叠系盆地的研究却较为缺乏。为了丰富相关研究和揭示区域构造演化的特点,通过古水流方向统计、砂岩中碎屑矿物统计和碎屑锆石U-Pb测年等方法对祁连山三叠纪盆地物源进行系统研究。结果表明,祁连山三叠系盆地的古流向主要有南东向、正南向、南西向,物源来自岩浆弧和大规模褶皱造山作用的混合区。祁连山三叠系砂岩中的碎屑锆石的年龄谱主要峰值集中在250~290 Ma、360~460 Ma、1 600~2 000 Ma和2 200~2 600 Ma这4个年龄段。通过对比分析华北板块、华南板块中和秦祁昆中央造山带中岩浆锆石年龄谱特征可知:1 600~2 000 Ma和2 200~2 600 Ma年龄段的锆石来自华北板块,360~460 Ma年龄段的锆石来自北祁连造山带,250~290 Ma年龄段的锆石来自东昆仑的火山岛弧。此外,600~1 000 Ma年龄段锆石很少,这些锆石来自扬子板块,表明在三叠纪扬子克拉通和华北克拉通发生碰撞形成了秦岭造山带,阻断了来自扬子克拉通的物源。     

土工试验规范变更对膨胀计算和判定的影响

对土工试验方法标准的新旧规范中无荷膨胀率和有荷膨胀率的变化内容进行对比分析,发现两者的计算公式发生显著变化,新规范的计算结果与旧规范相比,膨胀率明显变大,膨胀量随之增大,这将对工程勘察、设计、施工等产生明显影响。以某工程为例,新规范计算后地层总膨胀量由旧规范的16.7 mm变为51.8 mm,增加了2倍左右,地基土的胀缩等级由Ⅰ级变为Ⅱ级,地基基础设计等级由丙级变为乙级,地基处理措施和施工方案随之也发生改变。因此,工程技术人员对此应综合考虑,严谨对待。     

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.     

Numerical characterization of slope rock mass through considerations of hydraulic and mechanical properties

Landslides - In this paper, the slope rock mass is numerically characterized by considering hydraulic and mechanical properties using two distinct element models. The flow rate and permeability are...     

Failure mechanisms and dynamics of the Shanzao rockslide in Yongjia County,China on 10 August 2019

Landslides - At about 04:00 on 10 August 2019, the heavy rainfall carried by Typhoon Lekima induced a catastrophic rockslide in Shanzao Village, Yongjia County, China. The heavy rainfall triggered...     

Movement process analysis of the high-speed long-runout Shuicheng landslide over 3-D complex terrain using a depth-averaged numerical model

Landslides - Flow-like landslide is one of the most catastrophic types of natural hazards due to its high velocity and long travel distance. In 2019, a large catastrophic landslide was triggered by...     

A three-dimensional large-deformation random finite-element study of landslide runout considering spatially varying soil

Landslides - Landslide is a uniquely dynamic large-deformation process that can present serious threat to human lives and infrastructures. The natural soil properties often exhibit inherent spatial...