岩浆结晶与成矿作用模拟

本文回顾了８０年代以来国际上关于岩浆结晶及成矿作用过程的计算机模拟这一领域的研究进展,主要包括镁铁质干岩浆体系、长英质湿岩浆体系的岩浆结晶作用模拟,以及有关的岩浆矿床成矿作用、岩浆热液成矿作用的模拟。基于对这一领域研究现状和发展趋势的分析,笔者首次提出了模拟岩石学的概念。预测在今后５～１０年内,模拟岩石学将得到突飞猛进的发展,并将对现代岩石成因理论、实验岩石学与矿物学、实验地球化学、矿床成因理论和矿产预测及勘察理论产生重要影响。     

Effects of temporal scales and space mismatches on the TRMM 3B42 v7 precipitation product in a remote mountainous area

The accurate measurement of precipitation is essential to understanding regional hydrological processes and hydrological cycling. Quantification of precipitation over remote regions such as the Tibetan Plateau is highly unreliable because of the scarcity of rain gauges. The objective of this study is to evaluate the performance of the satellite precipitation product of tropical rainfall measuring mission (TRMM) 3B42 v7 at daily, weekly, monthly, and seasonal scales. Comparison between TRMM grid precipitation and point‐based rain gauge precipitation was conducted using nearest neighbour and bilinear weighted interpolation methods. The results showed that the TRMM product could not capture daily precipitation well due to some rainfall events being missed at short time scales but provided reasonably good precipitation data at weekly, monthly, and seasonal scales. TRMM tended to underestimate the precipitation of small rainfall events (less than 1 mm/day), while it overestimated the precipitation of large rainfall events (greater than 20 mm/day). Consequently, TRMM showed better performance in the summer monsoon season than in the winter season. Through comparison, it was also found that the bilinear weighted interpolation method performs better than the nearest neighbour method in TRMM precipitation extraction.     

川滇地区地震活动单键群分析

利用单键群（即ＳＬＣ）分析方法,通过有关ＳＬＣ特征参量的时间滑移分析,结合１９７０年以来的区域地震活动和构造环境,分析了川滇西部地区的地震活动。较之７０年代和８０年代,９０年代的地震活动在总体上是处于中等强度的活动水平。文章认为,ＳＬＣ方法考虑了地震事件的时空关联性,可以用来分析地震活动趋势,是研究地震活动性的有用工具。     

Polycyclic aromatic hydrocarbon concentrations in urban soils representing different land use categories in Shanghai

An extensive soil survey was carried out in Shanghai to investigate the spatial distribution and possible sources of polycyclic aromatic hydrocarbons (PAHs) in urban soils. Soil samples were collected from highways, iron-smelting plants, steel-smelting plants, shipbuilding yards, coking plants, power plants, chemical plants, urban parks, university campuses and residential areas and were analyzed for 16 PAHs by gas chromatography with mass detection. High PAH concentrations were found in all locations investigated, with mean values of soil total PAH concentrations in the range 3,279–38,868 μg/kg DM, and the PAH concentrations were significantly influenced by soil organic matter content. Soil PAH profiles in all districts were dominated by PAHs with 4–6 rings. Principal components analysis and diagnostic ratios of PAHs indicate that they were mainly derived from coal combustion and petroleum but in soils from highways the PAHs were derived largely from vehicle exhaust emissions. The high concentrations of PAHs found indicate that many urban soils in Shanghai represent a potential hazard to public health.     

Formation of chlorite rims and the impact of pore-lining chlorite on reservoir quality: a case study from Shiqianfeng sandstones in upper Permian of Dongpu Depression,Bohai Bay Basin,eastern China

The source material, precursor and formation processes of chlorite rims, and impact of pore-lining chlorite on reservoir quality of the Shiqianfeng sandstones, Dongpu Depression, Bohai Bay Basin, China, are studied using an integrated approach, including core observation, point-count analysis of thin-sections, scanning electron microscopy, electron microprobe analysis and cathode luminescence. The petrographic analysis shows that chlorite rims consist of grain-coating chlorite, poorly crystalline pore-lining chlorite and euhedral-crystallised pore-lining chlorite. The chemical composition shows that pore-lining chlorite is mainly Fe-rich with an average of 0.785 for Fe/(Fe+Mg) ratio. Petrographic analysis shows a large amount of volcanic dust (3.0～16.0 vol%, average of 7.93 vol%) in Shiqianfeng sandstones, which determines the formation of poorly crystalline pore-lining chlorite. Transformation of volcanic dust to smectite rims started with shallow burial depth at an early diagenetic stage, followed by in situ alteration of the smectite rims to poorly crystalline chlorite rims. Euhedral-crystallised chlorite mainly develops in sandstones with high porosity, high permeability and open flow systems. Pore-lining chlorite can inhibit quartz overgrowth but cannot effectively prevent pore-filling of authigenic quartz, carbonate and kaolinite cements, and therefore cannot prevent porosity destruction. However, the occurrence of pore-lining chlorite is a barometer of good reservoir quality and intense hydrodynamic conditions.     

Comparative assessment of nitrogen fixation rate by 15N2 tracer assays in the South China Sea

Nitrogen fixation is one of the most important sources of new nitrogen in the ocean and thus profoundly affects the nitrogen and carbon biogeochemical processes. The distribution, controlling factors, and flux of N₂ fixation in the global ocean remain uncertain, partly because of the lack of methodological uniformity. The 15N₂ tracer assay (the original bubble method → the 15N₂-enriched seawater method → the modified bubble method) is the mainstream method for field measurements of N₂ fixation rates (NFRs), among which the original bubble method is the most frequently used. However, accumulating evidence has suggested an underestimation of NFRs when using this method. To improve the availability of previous data, we compared NFRs measured by three 15N₂ tracer assays in the South China Sea. Our results indicate that the relationship between NFRs measured by the original bubble method and the 15N₂-enriched seawater method varies obviously with area and season, which may be influenced by incubation time, diazotrophic composition, and environmental factors. In comparison, the relationship between NFRs measured by the original bubble method and the modified bubble method is more stable, indicating that the N₂ fixation rates based on the original bubble methods may be underestimated by approximately 50%. Based on this result, we revised the flux of N₂ fixation in the South China Sea to 40 mmol/(m2·a). Our results improve the availability and comparability of literature NFR data in the South China Sea. The comparison of the 15N₂ tracer assay for NFRs measurements on a larger scale is urgently necessary over the global ocean for a more robust understanding of the role of N₂ fixation in the marine nitrogen cycle.     

南黄海沉积物中活性铁氧化物对有机碳的保存作用

土壤和沉积物中活性铁对有机质的吸附对有机质具有长期稳定和保存作用,从而在地质时间尺度上缓冲大气CO₂浓度。本文利用连二亚硫酸钠还原性溶解提取活性铁氧化物（FeR）及与之结合的有机碳（Fe-OC）,定量研究了南黄海沉积物中FeR与OC之间的结合方式以及FeR对OC的保存作用,讨论了深度增加对二者相互作用的影响。结果表明,南黄海沉积物中Fe-OC占沉积物总有机碳的份数（f_Fe-OC）为（13.2±7.47）%,即活性铁对OC的年吸附量为0.72 Mt,占全球边缘海沉积物TOC年埋藏通量的0.44%。Fe-OC的平均OC:Fe为4.50±2.61,表明共沉淀作用对有机质的保存起重要作用,且其比值随海源有机质含量增加而增加。Fe-OC稳定碳同位素（δ13C_Fe-OC）结果表明,FeR优先保存活性有机质,但这种选择性随OC:Fe增大而减弱。随深度增加,f_Fe-OC和δ13C_Fe-OC均未表现出显著变化,这与该海域沉积物中有机质活性较低、铁还原作用较弱有关。     

Study on the negative bias temperature instability effect under dynamic stress

This paper studies negative bias temperature instability (NBTI) under alternant and alternating current (AC) stress. Under alternant stress, the degradation smaller than that of single negative stress is obtained. The smaller degradation is resulted from the recovery of positive stress. There are two reasons for the recovery. One is the passivation of H dangling bonds, and another is the detrapping of charges trapped in the oxide. Under different frequencies of AC stress, the parameters all show regular degradation, and also smaller than that of the direct current stress. The higher the frequency is, the smaller the degradation becomes. As the negative stress time is too small under higher frequency, the deeper defects are hard to be filled in. Therefore, the detrapping of oxide charges is easy to occur under positive bias and the degradation is smaller with higher frequency.     

Impact of multiple satellite ocean color samplings in a day on assessing phytoplankton dynamics

Ocean-color imagers on conventional polar-orbiting satellites have a revisit time of ??2 days for most regions, which is further reduced if the area is frequently cloudy. The Geostationary Ocean Color Imager (GOCI), the first ocean-color imager on a geostationary satellite, provides measurements 8 times a day, thus significantly improving the frequency of measurements for studies of ocean environments. Here, we use results derived from GOCI measurements over Taihu Lake to demonstrate that the extra sampling can be used to improve the accuracy of statistically averaged longer-term (daily) measurements. Additionally, using numerical simulations, we demonstrate that the coupling of diurnal variations of both biomass and photosynthetic available radiation can improve the accuracy of daily primary production estimates. These results echo that higher sampling frequency can improve our estimates of longer-term dynamics of biogeochemical processes and highlights the value of ocean color measurements from geostationary satellites.     

Automated multi-scale classification of the terrain units of the Jiaxie Guyots and their mineral resource characteristics

Given the advances in satellite altimetry and multibeam bathymetry, benthic terrain classification based on digital bathymetric models (DBMs) has been widely used for the mapping of benthic topographies. For instance, cobalt-rich crusts (CRCs) are important mineral resources found on seamounts and guyots in the western Pacific Ocean. Thick, plate-like CRCs are known to form on the summit and slopes of seamounts at the 1 000–3 000 m depth, while the relationship between seamount topography and spatial distribution of CRCs remains unclear. The benthic terrain classification of seamounts can solve this problem, thereby, facilitating the rapid exploration of seamount CRCs. Our study used an EM122 multibeam echosounder to retrieve high-resolution bathymetry data in the CRCs contract license area of China, i.e., the Jiaxie Guyots in 2015 and 2016. Based on the DBM construted by bathymetirc data, broad- and fine-scale bathymetric position indices were utilized for quantitative classification of the terrain units of the Jiaxie Guyots on multiple scales. The classification revealed four first-order terrain units (e.g., flat, crest, slope, and depression) and eleven second-order terrain units (e.g., local crests, depressions on crests, gentle slopes, crests on slopes, and local depressions, etc.). Furthermore, the classification of the terrain and geological analysis indicated that the Weijia Guyot has a large flat summit, with local crests at the southern summit, whereas most of the guyot flanks were covered by gentle slopes. “Radial” mountain ridges have developed on the eastern side, while large-scale gravitational landslides have developed on the western and southern flanks. Additionally, landslide masses can be observed at the bottom of these slopes. The coverage of local crests on the seamount is ~1 000 km2, and the local crests on the peak and flanks of the guyots may be the areas where thick and continuous plate-like CRCs are likely to occur.